4.7 Article

Poly(vinylidene fluoride) composites with carbon nanotubes decorated with metal nanoparticles

Journal

COMPOSITES PART B-ENGINEERING
Volume 142, Issue -, Pages 1-8

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2017.12.047

Keywords

Piezoelectric polymers; PVDF; Carbon nanotubes; Smart materials; Electrical properties

Funding

  1. Portuguese Foundation for Science and Technology (FCT) [UID/FIS/04650/2013]
  2. FEDER funds through the COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) [POCI-01-0145-FEDER-006941]
  3. EMaDeS - Energy, Materials and Sustainable Development [Centro-01-0145-FEDER-000017]
  4. Portugal Program (PT), within the Regional Operational Program of the Center (CENTRO)
  5. European Union through the European Regional Development Fund (ERDF)
  6. FCT [SFRH/BD/98219/2013]
  7. Spanish Ministry of Economy and Competitiveness (MINECO) (FEDER) [MAT2016-76039-C4-3-R]
  8. Basque Government Industry Department under the ELKARTEK Program

Ask authors/readers for more resources

Polymer composites based on poly(vinylidene fluoride) (PVDF) filled with carbon nanotubes (CNT) decorated with metal nanoparticles (NP) of cobalt, nickel, platinum and palladium have been produced. The CNT nano fillers decorated with metal NP were synthesized by a modified wet impregnation method and their structural, morphological and thermal properties were evaluated. The metal NP ranging from 2 to 10 nm were found well dispersed on the CNT structure. The structural, optical, thermal and electrical properties of the metal/CNT/PVDF composite films demonstrate that the inclusion of the nanofillers leads to the nucleation of the gamma-PVDF phase (up to 90%) and enhance the thermal properties (higher melting point) of the polymer. The nanofillers also proved to be suitability to tailor the optical properties of the polymer composite films and lead to an increase in the d.c. electrical conductivity (up to 10(-13)S/cm). Thus, the reported metal/CNT nanofillers are suitable to tune PVDF polymer properties towards specific applications.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Biomedical

Enhanced neuronal differentiation by dynamic piezoelectric stimulation

Tiffany S. Pinho, Deolinda Silva, Jorge Cibrao Ribeiro, Ana Marote, Rui Lima, Salete J. Batista, Rita Melo, Clarisse Ribeiro, Cristiana B. Cunha, Irina S. Moreira, Senentxu Lanceros-Mendez, Antonio J. Salgado

Summary: This study focuses on the application of poled and coated PVDF films for neural differentiation and found that these films can induce neuronal differentiation under mechanical stimulation, which is further enhanced with a pre-coating step of poly-d-lysine and laminin.

JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A (2023)

Review Chemistry, Multidisciplinary

Silk Fibroin as Sustainable Advanced Material: Material Properties and Characteristics, Processing, and Applications

Ander Reizabal, Carlos M. Costa, Leyre Perez-Alvarez, Jose L. Vilas-Vilela, S. Lanceros-Mendez

Summary: In this review, the molecular structure, original properties, available modifications, and processing methods of silk fibroin are presented, providing a wide overview for custom structural and functional variations.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Polymer Science

Influence of polymer matrix on the luminescence of phosphor based printable electroluminescent materials and devices

R. Policia, D. M. Correia, N. Perinka, C. R. Tubio, S. Lanceros-Mendez

Summary: This study develops printable electroluminescent materials and devices based on different polymer matrixes. Incorporating different contents of zinc sulfide co-doped with copper particles into various polymer matrixes, the influence of the polymer matrix on the functional performance of the materials is evaluated. The printability of the materials is demonstrated and SEBS shows the highest luminance values in functional devices.

POLYMER (2023)

Article Chemistry, Applied

Degradation and mineralization of electroactive poly (3-hydroxybutyrate-co-3-hydroxyvalerate) electrospun fibers for bone tissue engineering

Teresa Marques-Almeida, Senentxu Lanceros-Mendez, Clarisse Ribeiro

Summary: Biocompatible and electroactive polymers are required for tissue engineering applications to produce active scaffolds. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) meets these requirements and its processing and properties were investigated in this study. The developed PHBV fibers showed bioactivity by mineralizing carbonated hydroxyapatite and partially degrading after 60 days in contact with simulated body fluid, indicating their suitability for bone tissue engineering.

REACTIVE & FUNCTIONAL POLYMERS (2023)

Article Chemistry, Physical

Sustainable metal-organic framework co-engineered glass fiber separators for safer and longer cycle life of Li-S batteries

Srikanth Ponnada, Mubashir Mansoor, Navid Aslfattahi, Nilgun Baydogan, Susmita Naskar, Rakesh K. Sharma, Maryam Sadat Kiai

Summary: To address the issues of Li dendrite growth and polysulfide movement in Li-S batteries, researchers have developed Cu or Fe-coated ultrathin MOF nanosheets on a glass fiber separator. The Cu or Fe atoms facilitate Li ion movement while preventing polysulfide migration through Lewis acid-base interaction. The Cu/MOF and Fe/MOF separators exhibit excellent long-term cycling stability, with low-capacity decay and high capacity retention after 400 cycles, demonstrating their potential for practical applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Ceramics

Long-lasting ceramic composites for surface dielectric barrier discharge plasma actuators

K. O. Shvydyuk, F. F. Rodrigues, J. Nunes-Pereira, J. C. Pascoa, S. Lanceros-Mendez, A. P. Silva

Summary: The developed research investigates cost-effective MgO-Al2O3, MgO-CaZrO3 perovskite, and thermally stable YSZ ceramic composites for DBD plasma actuators in aerospace applications. The study focuses on their implementation for flow control and ice mitigation. Results show that MgO-Al2O3 achieves higher induced velocities and lower heat dissipation, making it the best candidate for active flow control mechanisms. YSZ, on the other hand, exhibits high power consumption and is suitable for ice mitigation. This extensive research highlights the promising potential of these ceramics as breakthrough materials for DBD plasma actuators.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY (2023)

Article Materials Science, Multidisciplinary

Graphene Based Printable Conductive Wax for Low-Power Thermal Actuation in Microfluidic Paper-Based Analytical Devices

Ricardo Brito-Pereira, Clarisse Ribeiro, Pedro Costa, Vitor Correia, Vanessa F. Cardoso, Senentxu Lanceros-Mendez

Summary: The study proposes multifunctional hydrophobic composites with conductive graphene nanoplatelets (GNPs) integrated into the wax matrix to achieve a dual role of barrier and heater. With post-thermal curing, wax prints with mechanical stability and adequate impregnation can achieve controlled temperatures ranging from room temperature to approximately 107 degrees Celsius in just 10 seconds. This technology has great potential to meet the increasing demand for versatile and effective microfluidic paper-based analytical devices (mu PADs).

ADVANCED MATERIALS TECHNOLOGIES (2023)

Review Chemistry, Multidisciplinary

Smart and Multifunctional Materials Based on Electroactive Poly(vinylidene fluoride): Recent Advances and Opportunities in Sensors, Actuators, Energy, Environmental, and Biomedical Applications

Carlos M. Costa, Vanessa F. Cardoso, Pedro Martins, Daniela M. Correia, Renato Goncalves, Pedro Costa, Vitor Correia, Clarisse Ribeiro, Margarida M. Fernandes, Pedro M. Martins, Senentxu Lanceros-Mendez

Summary: This article reviews the latest advances and applications of poly(vinylidene fluoride) (PVDF) and its derivatives, highlighting the characteristics of PVDF materials, especially their outstanding electroactive properties, and their application in areas such as sensors and energy harvesting.

CHEMICAL REVIEWS (2023)

Article Chemistry, Multidisciplinary

α-Methylbenzylamine Functionalized Crown-Ether-Appended Calix[4]arene Phase Transfer Catalyst for Enantioselective Henry Reaction

Apoorva Malik, Pragati R. Sharma, Rakesh K. Sharma

Summary: In this letter, a highly selective crown-ether-appended calix[4]arene derived phase transfer catalyst was designed and applied for asymmetric nitroaldol reaction, leading to the desired adducts with high yields and good enantioselectivities.

CHEMISTRY-A EUROPEAN JOURNAL (2023)

Article Materials Science, Composites

Printable piezoresistive polymer composites for self-sensing medical catheter device applications

E. Pimentela, P. Costa, C. R. Tubio, J. L. Vilaca, C. M. Costa, S. Lanceros-Mendez, D. Miranda

Summary: Flexible sensor devices are in high demand for new and improved health treatments, particularly for neurogenic bladder dysfunction. Polymer composites based on different matrices (CMC, SEBS, and PVA) and varying concentrations of multiwalled carbon nanotubes (CNT) have been developed for catheter medical device application. These composites demonstrate excellent electrical and mechanical properties, with high conductivity and piezoresistive response.

COMPOSITES SCIENCE AND TECHNOLOGY (2023)

Correction Materials Science, Biomaterials

Electroactive functional microenvironments from bioactive polymers: A new strategy to address cancer (vol 137, 212849, 2022)

S. Ribeiro, M. Soares, B. Hermenegildo, V. Correia, A. Garcia Diez, S. Lanceros-Mendez, C. Ribeiro

BIOMATERIALS ADVANCES (2023)

Article Chemistry, Multidisciplinary

3D Printed Robotic Hand with Piezoresistive Touch Capability

Goncalo Fonseca, Joao Nunes-Pereira, Abilio P. Silva

Summary: This study presents a low-cost sensory glove system that enhances the functionality of a 3D-printed mechanical hand prosthesis by enabling touch detection, localization, and force measurement. The mechanical hand model was produced using 3D printing, allowing for quick and affordable production with the ability to replace individual parts easily. A complementary sensory mimicry add-on system was constructed and instrumented with piezoresistive sensors attached to the glove's palm, enabling the localization and quantification of forces exerted on the glove. This system has shown promising results and could serve as a platform for the development of a more complex and multifunctional system in the future.

APPLIED SCIENCES-BASEL (2023)

Article Materials Science, Multidisciplinary

Photocurable Hybrid Materials with High Magnetodielectric Coupling

Cristian Mendes-Felipe, Rui Carvalho, Pedro Martins, Oleksandr Igorovych Ivankov, Ivan Bobrikov, Viktor Petrenko, Jose Maria Porro, Marco Sangermano, Senentxu Lanceros-Mendez

Summary: Magnetodielectric materials, which allow magnetic control of dielectric response, are highly interesting for IoT-related devices. Photocurable polymers combined with magnetic nanoparticles offer a sustainable and efficient approach for their development. Photocurable magnetic hybrid materials based on PUA and various magnetic micro- and nanoparticles have been developed, with investigations on their physicochemical properties, electrical conductivity, and magnetic properties. By optimizing the filler type and content, composites with high magnetodielectric coefficients have been obtained, making them important for the fabrication of magnetodielectric devices in the digital transition context.

ACS APPLIED POLYMER MATERIALS (2023)

Article Materials Science, Multidisciplinary

Environmentally Friendlier Printable Conductive and Piezoresistive Sensing Materials Compatible with Conformable Electronics

Miguel Franco, Azadeh Motealleh, Carlos M. Costa, Nikola Perinka, Clarisse Ribeiro, Carmen R. Tubio, Sonia AlexandraCorreia Carabineiro, Pedro Costa, Senentxu Lanceros-Mendez

Summary: Flexible and conformable conductive composites using different polymers and graphene oxide have been developed for printable solutions with functional properties. The materials have low resistance and support bending deformations, making them suitable for sustainable and functional printable electronics.

ACS APPLIED POLYMER MATERIALS (2023)

Review Materials Science, Ceramics

Review of Ceramic Composites in Aeronautics and Aerospace: A Multifunctional Approach for TPS, TBC and DBD Applications

Kateryna O. Shvydyuk, Joao Nunes-Pereira, Frederico F. Rodrigues, Abilio P. Silva

Summary: The pursuit of improved performance in the aeronautical and aerospace industries has led to research and development of advanced ceramics. These ceramics have the unique ability to fulfill various application requirements, such as thermomechanical, thermoelectric, and electromechanical properties, ensuring reliability, durability, and extended lifespan of critical structures or systems. In the aeronautical and aerospace fields, engineered ceramic appliances serve three main purposes: thermal protection systems, thermal protection barriers, and dielectric barrier discharge plasma actuators. This research provides a comprehensive discussion and review of these applications and explores the concept of multifunctional advanced ceramics for future engineering needs and perspectives.

CERAMICS-SWITZERLAND (2023)

Article Engineering, Multidisciplinary

The relationship between the impact position interference and CAI strength of composite sandwich structures under double impacts

Keyu Zhu, Xitao Zheng, Jing Peng, Jiaming Sun, Ruilin Huang, Leilei Yan

Summary: This paper discusses the influence of multiple impacts on the compression strength of honeycomb sandwich structures with composite face sheets. It is found that the size of the impactor affects the turning point of the compression strength. Additionally, high impact energy leads to damage in the bottom face sheet and reduces the overall compression strength.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Effect of carbonation on the corrosion behavior of steel rebar embedded in magnesium phosphate cement

Danqian Wang, Yanfei Yue, Jueshi Qian

Summary: Magnesium Potassium Phosphate Cement (MKPC) as a binder for steel rebars shows improved corrosion resistance when subjected to carbonation, due to the increase in pH and the formation of a more protective oxide film.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Mechanical properties and failure mechanisms of all-CFRP corrugated sandwich truncated cone

Zhibin Li, Wenyu Wang, Pengcheng Xue, Xingyu Wei, Jian Xiong

Summary: This work proposes a design approach and manufacturing method for carbon fiber reinforced plastic (CFRP) corrugated sandwich truncated cones (CSTC) to improve their anti-debonding ability and ensure reliability. The study establishes theoretical models for CSTCs' stiffness and failure modes, which are verified through experiments and finite element analysis (FEA). The research reveals the effect of geometric parameters on failure modes and performs an optimal design for CSTC structures. The findings have significant implications for the design and application of lightweight CSTCs in constructions, such as launch vehicle adapters.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Asymmetric wettability fibrous membranes: Preparation and biologic applications

Mingyu Zhang, Lei Chu, Jiahua Chen, Fuxun Qi, Xiaoyan Li, Xinliang Chen, Deng-Guang Yu

Summary: This review summarizes the different structures and construction methods of fibrous membranes with asymmetric wettability. It also reviews the biological applications of these membranes and suggests future challenges.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Effect of fibre concentration on the mechanical properties of welded reinforced polypropylene

E. Mofakhami, L. Gervat, B. Fayolle, G. Miquelard-Garnier, C. Ovalle, L. Laiarinandrasana

Summary: This study investigates the effects of fibre concentration on the mechanical response of welded glass-fibre-reinforced polypropylene (GF-PP). Experimental observations reveal a significant reduction in weld ratio, up to 60%, indicating a decreased strength compared to the bulk material. Increasing fibre content in the welded material results in a decrease in stress at break and strain at the maximum stress. The use of DIC technique and X-ray microtomography further confirms the localized strain amplification in the welded zone due to the significant increase in fibre density.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Interlaminar shear strength of Carbon/PEEK thermoplastic composite laminate: Effects of in-situ consolidation by automated fiber placement and autoclave re-consolidation

Emad Pourahmadi, Farjad Shadmehri, Rajamohan Ganesan

Summary: This research compares the mechanical properties of laminates manufactured using automated fiber placement and conventional autoclave curing methods. The results show that laminates manufactured using automated fiber placement have a lower interlaminar shear strength compared to laminates reconsolidated using autoclave curing. A finite element simulation method is proposed to quantitatively analyze these differences.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Bolted joint method for composite materials using a novel fiber/metal patch as hole reinforcement-Improving both static and fatigue properties

Johnny Jakobsen, Benny Endelt, Fahimeh Shakibapour

Summary: This study proposes a new bolted/pinned joining method for composite applications, which improves load transfer by introducing a patch-type reinforcement. Experimental results demonstrate significant improvements in both static and fatigue load conditions compared to existing methods. Finite element simulations highlight the advantage of this method, as it creates a more efficient load-transferring mechanism through different stress distributions.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Novel multi-crack damage approach for pultruded fiber-polymer web-flange junctions

Gisele G. Cintra, Janine D. Vieira, Daniel C. T. Cardoso, Thomas Keller

Summary: This paper proposes a novel approach to assess multi-crack behavior in layered fiber-polymer composites. The generated Compliance and R-curves provide useful insights into understanding the multiple delamination process and allow for separate evaluation of strain energy release rate (SERR) for each crack. The developed cohesive zone model successfully simulates the failure process zone of three parallel cracks, showing good agreement between the numerical model and experimental results.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Uncovering the hidden structure: A study on the feasibility of induction thermography for fiber orientation analysis in CFRP composites using 2D-FFT

Renil Thomas Kidangan, Sreedhar Unnikrishnakurup, C. Krishnamurthy, Krishnan Balasubramaniam

Summary: The induction heating process can accurately identify fiber orientation and stacking order, making it a valuable tool for large-area inspection and quality control in manufacturing fiber-reinforced composites.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Morphological characteristics of spray dried cellulose nanofibers produced using various wood pulp feedstocks and their effects on polypropylene composite properties

Sungjun Hwang, Yousoo Han, Douglas J. Gardner

Summary: Bleached Kraft pulp, unbleached Kraft pulp, and old corrugated cardboard pulp are suitable for producing cellulose nanofibril suspensions. Spray drying is a fast, simple, cost-effective, and scalable drying method. Spray-dried cellulose nanofibrils can be used as reinforcing materials in polypropylene matrices. The particle size of cellulose nanofibrils affects the material properties.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Four-dimensional printing of continuous glass fiber-reinforced thermoplastics

Mehdi Mahdavi, Abbas Zolfaghari

Summary: This study aims to improve the recovery forces of shape memory polymers (SMPs) through material extrusion additive manufacturing. By using glass fiber (GF) as reinforcement and manufacturing multi-layer composite specimens, it was found that PLA with 6.62% GF exhibited the best recovery force, which was further optimized through annealing heat treatment.

COMPOSITES PART B-ENGINEERING (2024)

Review Engineering, Multidisciplinary

Flame retardancy and fire mechanical properties for natural fiber/polymer composite: A review

Xiang Ao, Antonio Vazquez-Lopez, Davide Mocerino, Carlos Gonzalez, De-Yi Wang

Summary: The vulnerability of natural fibers to heat and fire poses a significant challenge for their substitution of traditional fiber reinforcements in composite materials. Natural fiber/polymer composites (NFCs) are regarded as potential candidates for engineering applications due to their environmental friendliness and low-impact sourcing. Thus, appropriate approaches need to be implemented to enhance the fire safety of NFCs. This review summarizes and discusses the latest understanding of flammability and thermal properties of natural fibers, with a special focus on their interaction with polymer matrix in fire behavior. Additionally, the latest developments in flame-retardant approaches for NFCs are reviewed, covering both flame retardancy and fire structural integrity. Finally, future prospects and perspectives on fire safety of NFCs are proposed, providing insights into further advancements of NFCs.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Construction of an epoxidized, phosphorus-based poly(styrene butadiene styrene) and its application in high-performance epoxy resin

Cheng Wang, Siqi Huo, Guofeng Ye, Bingtao Wang, Zhenghong Guo, Qi Zhang, Pingan Song, Hao Wang, Zhitian Liu

Summary: The demand for multifunctional, transparent epoxy resin with superior dielectric, mechanical, and fire-safety performances is increasing in modern industries. Researchers have developed an epoxidized, phosphaphenanthrene-containing poly(styrene butadiene styrene) (ESD) for advanced fire-safe epoxy resin, which maintains high transparency and improves UV-blocking property. The addition of 10 wt% ESD results in improved mechanical properties, decreased dielectric constant and loss, and outperformance compared to other fire-safe epoxy resins. This research provides an effective method for developing multifunctional flame-retardant epoxy resin.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Inner superhydrophobic materials based on waste fly ash: Microstructural morphology of microetching effects

Bo Pang, Heping Zheng, Zuquan Jin, Dongshuai Hou, Yunsheng Zhang, Xiaoyun Song, Yanan Sun, Zhiyong Liu, Wei She, Lin Yang, Mengyuan Li

Summary: This study develops an internal superhydrophobic material (ISM) using waste denitrification fly ash, which maintains stable hydrophobicity under harsh conditions of use and does not rely on expensive fluor-based surface modifications. The synthesized ISM has excellent matrix strength, strong waterproof properties, and retains superhydrophobicity even at damaged or friction interfaces.

COMPOSITES PART B-ENGINEERING (2024)

Article Engineering, Multidisciplinary

Directional eddy current probe configuration for in-line detection of out-of-plane wrinkles

Meirbek Mussatayev, Qiuji Yi, Mark Fitzgerald, Vincent K. Maes, Paul Wilcox, Robert Hughes

Summary: Real-time monitoring of carbon fibre composites during Automated Fibre Placement (AFP) manufacturing remains a challenge for non-destructive evaluation (NDE) techniques. This study designed a directional eddy-current (EC) probe to evaluate the detectability of out-of-plane wrinkles. Experimental evaluations and finite element modeling were conducted to better understand the relationship between eddy-current density and defect detection. The findings suggest that the probe configuration with an asymmetric driver coil and differential pickup coils shows the best capability for wrinkle detection.

COMPOSITES PART B-ENGINEERING (2024)