Article
Chemistry, Physical
Gongyue Huang, Luca Porcarelli, Yan Liang, Maria Forsyth, Haijin Zhu
Summary: The study found that the composite with TFSI anion exhibited the best ion conductivity, while a synergistic effect was observed for the composite with both TFSI and OTf mixed anion, resulting in significantly enhanced ionic conductivity reaching 1.47 mS/cm. This work demonstrates the potential of using a combination of TFSI and OTf anions as an effective strategy for improving ionic conductivity in proton-exchange membranes.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Alex Spiess, Philipp Brandt, Alexa Schmitz, Christoph Janiak
Summary: Water sorption characteristics of six pure hydrophilic ionic liquids were investigated, revealing a steady and high water uptake with a small hysteresis between absorption and desorption. These findings provide valuable insights into the water sorption behavior of ionic liquids.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Multidisciplinary
Xian Suo, Zhenzhen Yang, Yuqing Fu, Chi-Linh Do-Thanh, Dmitry Maltsev, Huimin Luo, Shannon M. Mahurin, De-en Jiang, Huabin Xing, Sheng Dai
Summary: Metal-ion-amino-based ionic liquids were utilized to fine-tune the energy regulation of CO2 chemisorption, demonstrating efficient and controllable CO2 release with reduced energy input and minimal sacrifice on CO2 uptake capacity, offering new prospects for energy-efficient carbon capture technologies.
Article
Chemistry, Inorganic & Nuclear
Kalpana Chintakrinda, Nagaraju Narayanam, Guang-Hui Chen, Fei Wang, Jian Zhang, Lei Zhang
Summary: We report the discovery of inorganic toroidal and capsule titanium oxysulfate clusters through ionothermal synthesis. The ratio between geometrically different anions (tetrahedral SO(4)(2-) vs. pseudo-tetrahedral PO(3)(3-)) shows an interesting influence on the formation of cluster structure.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Kohei Miyazaki, Atsushi Mizawa, Yuta Ito, Fumihiro Sagane, Takeshi Abe
Summary: In this study, the formation kinetics of graphite intercalation compounds (GICs) were investigated, and it was found that the activation energy of interfacial anion transfer resistance is correlated with the viscosity of the ionic liquid electrolytes. This relationship provides important insights for the construction of dual-ion batteries with high capacity and high rate capability.
Article
Chemistry, Physical
Faiz Warsi, Md Rabiul Islam, Mohammad Osama, Maroof Ali, Mohd Arham Khan
Summary: The interactions between cationic ionic liquids/surfactants and anionic dye were investigated. The critical micelle concentration, spectroscopic changes, and binding constants were studied to understand the interaction behavior.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
M. Rothe, G. Quintard, M. Kronseder, P. Bauduin, T. Zemb, W. Kunz
Summary: This study investigates the microstructure of H[C8E5c] and its metal salts using X-ray scattering methods, which shows the existence of spherical micelles in diluted aqueous solutions and the interdigitation of head groups at high concentrations. The study also reveals the arrangement of metal cations between the micelles, which could be responsible for the unique properties of these systems.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Polymer Science
Fan Yang, Meng Zhao, Darren Smith, Peggy Cebe, Sam Lucisano, Thomas Allston, Thomas W. Smith
Summary: This study describes the synthesis, polymerization, and ion exchange of 1-butyl-2,3-dimethyl-4-vinylimidazolium triflate to produce a series of 1-butyl-2,3-dimethyl-4-vinylimidazolium polymers. Regardless of the anion's nature, substitution at the 2-position of the imidazolium moiety significantly increases the distance between the anion and cation.
Article
Chemistry, Physical
Malgorzata Pajak, Katarzyna Hubkowska, Andrzej Czerwinski
Summary: The mixtures of selected protic and aprotic ionic liquids with their parent superacids were used as electrolytes for hydrogen electrosorption in thin Pd films. The properties of these mixtures were characterized using electrochemical and physicochemical methods, demonstrating their potential use as electrolytes in hydride/protonic systems.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Chemistry, Physical
Apurba Ray, Bilge Saruhan
Summary: This article discusses the demand for high-performance, lightweight, and low-cost electronic devices, which has prompted research into advanced electrochemical energy storage devices and technologies. The focus is on ionic liquids as electrolytes in Li-ion batteries and supercapacitors, highlighting their potential, advantages, and challenges.
Article
Polymer Science
Ann Jastram, Tobias Lindner, Christian Luebbert, Gabriele Sadowski, Udo Kragl
Summary: This study focused on hydrogels synthesized by radical polymerization of imidazolium-based ionic liquids. The swelling and diffusion behavior of these hydrogels were investigated, showing strong swelling in water and ethanol with transport mechanisms deviating from Fickian-type behavior.
Article
Engineering, Environmental
Honghong Wang, Shangqing Chen, Yanan Dong, Jingjing Sun, Junfeng Wang, Yi Nie
Summary: The adsorption of metal ions from the cellulose spinning process-generated [Emim]Dep solution was studied using modified molecular sieves. The smaller size of 1.6 mm showed superior removal kinetic and selectivity for metal ions. Batch adsorption experiments showed high removal ratios for K+, Ca2+, Mg2+, Cu2+ and Zn2+, and the loss ratio of [Emim]Dep was below 0.7%. Fixed-bed adsorption experiments confirmed the long-term separation performance of metal ions from [Emim]Dep aqueous solution.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Engineering, Environmental
Yumeng Song, Qiqi Wei, Taotao Lu, Jiuyan Chen, Weifeng Chen, Wei Qi, Shanhu Liu, Zhichong Qi, Yanmei Zhou
Summary: The study found that the influence of imidazolium-based ionic liquids on the transport of TiO2 nanoparticles depended on the species, alkyl chain length, and counteranions. The inhibitory effects were mainly controlled by the hydrophobicity of the ILs and electrostatic repulsion between nanoparticles and porous media. Additionally, the inhibitory role of ILs was more pronounced under acidic conditions compared to alkaline conditions.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Chemistry, Physical
Zhangyi Xiong, Peijing Guo, Yushan Yang, Shaoyu Yuan, Ningzhao Shang, Chun Wang, Yufan Zhang, Huan Wang, Yongjun Gao
Summary: The DIB-SCHD device cleverly integrates the advantages of both a dual-ion battery and a supercapacitor, delivering exceptional electrochemical performance. With a state-of-the-art electrode and electrolyte design, it achieves high mass capacitance, specific energy, and specific power. The synergistic energy storage mechanism involving ion intercalation/deintercalation and adsorption/desorption processes promotes reaction kinetics and boosts overall performance.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
K. L. Andrew Chan, Anton S. Shalygin, Oleg N. Martyanov, Tom Welton, Sergei G. Kazarian
Summary: High throughput macro ATR-FTIR spectroscopic imaging was used for in situ characterization of 14 ionic liquids under controlled environments. The study found that the structure of the cation and anion in the ionic liquids significantly influenced the absorption of toluene and water, providing valuable insights for the application of ionic liquids.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Environmental
Yinghao Xue, Wei Teng, Yanyan Chen, Qian Ma, Xiaoqian Chen, Yu Sun, Jianwei Fan, Yuping Qiu, Rongbing Fu
Summary: This study developed a novel adsorbent, MnxLa1-x@HTCC, which can effectively remove multiple heavy metals simultaneously and exhibit superior adsorption capacity under different conditions. Additionally, the study indicates the potential of Mn-La carbon composites as a promising adsorbent in groundwater remediation.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Sicong Lei, Chengyi Hong, Zhiqiang Dong, Jichen Zhang, Xiaoxian Zhang, Ling Zhu, Yuping Qiu
Summary: The study investigates the mechanism of Pb(II)-mediated precipitation transformation to enhance the removal of Cr(VI) oxyanion on biogenic hydroxyapatite (BHAp). The process is time-dependent, involving rapid crystal precipitation in the initial stages and subsequent accumulation of precipitates over several hours. This method provides a potential approach for the successive removal of Pb(II) and Cr(VI).
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Yang Peng, Dan Zhang, Yuping Qiu, Zhina Xiao, Yusi Ji, Wenyang Li, Yiji Xia, Yichuan Wang, Hongwei Guo
Summary: Using high-throughput infrared imaging and 2-D clinostat treatment, we demonstrate that apical hook formation can occur without gravity-induced root bending. This formation begins with de novo growth asymmetry at the apical part, which is largely independent of auxin biosynthesis, transport, and signaling. Additionally, functional cortical microtubule array is essential for the enlargement of hook curvature.
JOURNAL OF INTEGRATIVE PLANT BIOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Ji Xuan, Huabin Xu, Hui Li, Desheng Chen, Yuping Qiu, Xi Chen, Mei Shao, Xianming Xia
Summary: This study aimed to explore the specific mechanism of extracellular vesicles from bone marrow mesenchymal stem cells (BMSCs) in liver fibrosis. The results showed that extracellular vesicles enriched with miR-148a-5p attenuated hepatic fibrosis by targeting Smad4.
MOLECULAR BIOTECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Yu-Ping Qiu, Qing Shi, Wei-Zhen Wang, Su-Hong Xia, Hao Dai, Hui Yin, Zhi-Qing Yang, Ping Wang
Summary: Supported alloy catalysts are important in heterogeneous catalytic processes, but the synthesis of supported alloy nanoparticles with consistent composition and size distribution is challenging. In this paper, a simple and effective method for preparing highly dispersed, homogeneously alloyed bimetallic nanoparticles on oxide supports is reported. The method involves the solid solution of metal cations in the oxide and the electrostatic adsorption of a secondary metal species onto the oxide surface, followed by reductive annealing to induce metal exsolution and homogeneous alloying on the oxide surface. The applicability and generality of this method are demonstrated using different oxides and base-noble metal pairs.
Article
Environmental Sciences
Chengyi Hong, Zhiqiang Dong, Jichen Zhang, Ling Zhu, Lei Che, Fuzhi Mao, Yuping Qiu
Summary: A novel biochar composite ABF-4 has been developed in this study, which shows excellent adsorption performance for both cationic Pb(II)/Cd(II) and anionic As(III). The adsorption capacity of ABF-4 is significantly higher than that of pure biochar, and is enhanced by increasing the surface area and micropores.
Article
Environmental Sciences
Qian Ma, Wei Teng, Yu Sun, Yanyan Chen, Yinghao Xue, Xiaoqian Chen, Chuning Zhang, Hua Zhang, Jianwei Fan, Yuping Qiu, Rongbing Fu
Summary: The core-shell structured nanoscale zero-valent iron encapsulated with mesoporous hydrated silica was prepared for efficient removal of heavy metals. The material exhibited high adsorption capacity for Pb(II), Cd (II), and As(V) at pH 5.0.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Oncology
Zeyu Ji, Yuping Qiu, Qingchun Cai, Chunfang Xu
Summary: This study revealed that LINC00922 promotes the progression of gastric cancer through the miR-204-5p/HMGA2 axis, suggesting potential diagnostic and therapeutic options for GC.
WORLD JOURNAL OF SURGICAL ONCOLOGY
(2022)
Article
Chemistry, Physical
Muhua Chen, Weizhen Wang, Yuping Qiu, He Wen, Guangyao Li, Zhiqing Yang, Ping Wang
Summary: This study experimentally identified the active sites in HCHO oxidation over TiO2-supported Pt catalysts and revealed the cooperative mechanism involved.
Article
Engineering, Environmental
Wenhui Han, Yuanzhang Hou, Ying Yu, Zhibo Lu, Yuping Qiu
Summary: This study found that fibrous PET can promote the transportation of NPs in saturated porous media, while filmy PET can inhibit it. The addition of fibrous PET increases porosity, while the addition of filmy PET decreases porosity.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Biochemistry & Molecular Biology
Wei Huang, Nan Hu, Zhina Xiao, Yuping Qiu, Yan Yang, Jie Yang, Xin Mao, Yichuan Wang, Zhengguo Li, Hongwei Guo
Summary: Ethylene plays a critical role in tomato fruit growth and ripening by modulating auxin biosynthesis/signaling and activating fruit development-related genes.
Article
Engineering, Environmental
Yuanzhang Hou, Changjian Luo, Yange Wang, Yijin Zhao, Yuping Qiu
Summary: This study investigates the colloidal interaction and cotransport of nanoplastics, submicroplastics, and microplastics in seawater and saturated natural sea sands. The results demonstrate the dominant role of unstable nanoplastics in the cotransport process.
Article
Chemistry, Applied
Xianfa Rao, Yitao Lou, Jianjun Zhao, Jun Chen, Yuping Qiu, Tingting Wu, Shengwen Zhong, Hua Wang, Lijue Wu
Summary: Polyacrylonitrile carbon nano-fibers, prepared through electrospinning and high temperature carbonization, exhibit a disordered and porous nanoscale-morphology with larger specific surface area and more active sites. The porous microstructure facilitates fast lithium ion transport, resulting in superior performance as anode materials for lithium ion batteries in terms of higher capacity, better rate capability, and cycle life.
JOURNAL OF POROUS MATERIALS
(2023)
Article
Chemistry, Physical
Deng -Hui Xuan, Yu -Ping Qiu, Ping Wang
Summary: By mechanically milling aluminum powder with activated charcoal, the reactivity of aluminum with alkaline solution can be significantly improved. This method is cost-effective and yields a high hydrogen generation rate, making it promising for mobile and portable applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Engineering, Environmental
Ling Zhu, Chengyi Hong, Jichen Zhang, Yuping Qiu
Summary: This study reports a high concentration of trivalent chromium in alkaline soils, which challenges the conventional wisdom that trivalent chromium forms insoluble species and has low mobility in soils. The results show that organic matter content and soil texture are critical factors driving the migration of submicron colloids in soils.
JOURNAL OF HAZARDOUS MATERIALS
(2023)