Journal
CHEMISTRY-AN ASIAN JOURNAL
Volume 13, Issue 17, Pages 2378-2381Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201800341
Keywords
1; 1-spirobiindane; aminalization; chiral BrOnsted acid; disulfonic acid; disulfonimide
Categories
Funding
- JSPS KAKENHI [JP15H05802, 15H05810, JP17K15417]
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [15H05810] Funding Source: KAKEN
Ask authors/readers for more resources
1,1-Spirobiindane-7,7-disulfonic acid (SPISA) and 1,1-spirobiindane-7,7-disulfonimide were synthesized from 1,1-spirobiindane-7,7-diol (SPINOL) in 4 steps using a Pd-catalyzed Newman-Kwart rearrangement as a key step. These new catalysts possessing a rigid spirocyclic backbone were evaluated in a catalytic asymmetric aminalization reaction, and SPISA/iPr(2)NEt exhibited high enantioselectivity, demonstrating the utility of SPISA as a chiral BrOnsted acid catalyst.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available