Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 13, Pages 3192-3198Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201705328
Keywords
chemosensor; hexavalent chromium; luminescence; metal-organic-framework; water
Categories
Funding
- NSFC [21371102, 21531005, 21673120, 21771113]
- NSF of Tianjin [16JCZDJC36900, 15JCZDJC38800]
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A new luminescent Zn-II-MOF with 1D triangular channels along the b axis, namely NUM-5, has been successfully assembled and well characterized, which features good stability, especially in aqueous solution. Interestingly, this compound exhibits a fast, sensitive and selective luminescence quenching response towards Cr-VI (Cr2O72-/CrO42-) in aqueous solution. The detection limits towards Cr2O72- and CrO42- ions are estimated to be 0.7 and 0.3 ppm, respectively, which are among the lowest detection limits reported for the MOF-based fluorescent probes that can simultaneously detect Cr2O72- and CrO42- in aqueous environment. The possible detection mechanism has been discussed in detail. Moreover, it can be easily regenerated after detection experiments, indicative of excellent recyclability. All these results suggest NUM-5 to be a highly selective and recyclable luminescent sensing material for the quantitative detection of Cr-VI anions in aqueous solution.
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