Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 24, Issue 43, Pages 10906-10933Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201801866
Keywords
asymmetric catalysis; Mukaiyama; organocatalysis; silyl-reagents; synthetic methods
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Funding
- Spanish Government (MINECO/FEDER) [CTQ2015-64561-R]
- UAM
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Organocatalysis is a growing area that is benefiting from advances in many fields. Its implementation has begun in areas such as supramolecular chemistry, organic chemistry and natural product synthesis. While a considerable number of important publications in the field of organocatalytic Mukaiyama-type additions have been reported, they are yet to be fully covered in a review. Therefore, we would like to highlight the applications of various kinds of organocatalysts in Mukaiyama-type reactions, while also including the vinylogous Mukaiyama variation. Herein we describe and discuss the development and current state of the art of the organocatalytic Mukaiyama reaction, vinylogous Mukaiyama and related reactions.
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