Journal
CHEMICAL SOCIETY REVIEWS
Volume 47, Issue 11, Pages 3861-3898Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cs00065k
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Funding
- Soochow University [Q410900714]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201708]
- Fund for Scientific Research-Flanders (FWO)
- University of Leuven (KU Leuven)
- Ministry of Education and Science of the Russian Federation [02.a03.0008]
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This focused review aims to summarize recent developments in the processes involving additions of secondary propargylamines to various heteroallenes and subsequent transition metal-catalyzed or electrophile-mediated cyclizations. The utility of this convenient and tunable strategy spans from the carbon dioxide fixation and target-oriented synthesis of complex natural and biologically active products to the generation of extended synthetic libraries of diverse oxygen-, nitrogen-and sulfur-containing heterocycles. For comparative purposes, the analogous transformations of propargylic alcohols are also highlighted in this account.
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