Journal
CHEMICAL ENGINEERING SCIENCE
Volume 191, Issue -, Pages 253-261Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2018.06.070
Keywords
Methane hydrate; Flow assurance; Asphaltene; Metal surface; Molecular dynamics simulation
Categories
Funding
- Fundamental Research Project of Shenzhen, China [JCYJ20160513103756736]
- Shenzhen Peacock Plan Research Grant [KQJSCX20170330151956264]
- Economy, Trade and Information Commission of Shenzhen Municipality [HYCYPT20140507010002]
- Development and Reform Commission of Shenzhen Municipality [DCF-2018-64]
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Microsecond molecular dynamics simulations were performed to investigate the methane hydrate formation on smooth and rough metal surface covered with water, light oil, and heavy oil with asphaltenes, respectively. The growth and crystallization of methane hydrates were characterized by the four-body order parameter and the face-saturated incomplete cage analysis. Results highlighted the priority for hydrate growth inside the groove of rough metal surface, from which the hydrate grew upwards to the outside of the groove and then to the water-gas interface. It clearly demonstrated the inhibition effects of light oil on the methane hydrate growth, which was further enhanced by adding asphaltenes. The inhibition mechanisms were elaborated during different stages of hydrate growth by gaining insights into the four-body order parameters at different locations of metal surface. To our knowledge, this was the first molecular-level study on the methane hydrate evolution on metal surface with heavy oil. It provided theoretical supports for evaluating the priority sites for the hydrate formation on pipe wall with concave and convex surfaces that might result from metal corrosion, change of pipe diameter or depositions of solid particles during the multi-phase transportation. (C) 2018 Elsevier Ltd. All rights reserved.
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