Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 7, Pages 790-793Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08387d
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Funding
- National Science Foundation [CHE1566213]
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Oxo-vanadium complexes are found to catalyze the redox dis-proportionation of benzylic and allylic alcohols, which results in co-production of carbonyl products and reductively coupled hydrocarbon dimers. Preliminary experimental and computational findings suggest the intervention of reduced V-alkoxide species, which undergo facile C-O bond homolysis to produce carbon free radicals, precursors to the hydrocarbon dimers.
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