4.7 Article

The chaotropic effect as an orthogonal assembly motif for multi-responsive dodecaborate-cucurbituril supramolecular networks

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 17, Pages 2098-2101

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08078f

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Funding

  1. Fundamental Research Funds for the Central Universities [2042016HF1054]
  2. Wuhan University Experiment Technology Project Funding [WHU-2016-SYJS-06]
  3. DFG [NA-686/8]
  4. China Scholarship Council [201406275086]

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In aqueous solution, host-guest complexation is frequently driven by the hydrophobic effect, which also constitutes a popular approach in the design of supramolecular assemblies. Herein, we report an orthogonal assembly motif, the chaotropic effect, which exploits the tendency of chaotropic anions to associate with hydrophobic surfaces.

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