Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 7, Pages 759-762Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08408k
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Funding
- MoES, New Delhi [09-DS/03/2014 PC-IV]
- CSIR
- UGC
- CDRI Communication [9606]
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An anti-carbonickelative cyclization via reversible alkenylnickel E/Z isomerization of 2-azido phenyl propargyl alcohols with aryl boronic acids is achieved using Ni(acac)(2) as the catalyst to access 2,3-diaryl quinolines. It represents a rare example of trapping the vinyl metal intermediate with a nitrogen center, a non-carbon center electrophile.
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