Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes

A synthetic polymer system with repeatable chemical recyclability

(2018) Jian-Bo Zhu et al.   SCIENCE

Highly Robust Yttrium Bis(phenolate) Ether Catalysts for Excellent Isoselective Ring-Opening Polymerization of Racemic Lactide

(2017) Tie-Qi Xu et al.   MACROMOLECULES

Aluminium salalens vs. salans: “Initiator Design” for the isoselective polymerisation of rac-lactide

(2016) Paul McKeown et al.   CHEMICAL COMMUNICATIONS

The Halogen Bond

(2016) Gabriella Cavallo et al.   CHEMICAL REVIEWS

Highly Stereocontrolled Ring-Opening Polymerization of Racemic Alkyl β-Malolactonates Mediated by Yttrium [Amino-alkoxy-bis(phenolate)] Complexes

(2016) Cédric G. Jaffredo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc Complexes of Sequential Tetradentate Monoanionic Ligands in the Isoselective Polymerization of rac -Lactide

(2016) Tomer Rosen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Halogen Bonding in Supramolecular Chemistry

(2015) Lydia C. Gilday et al.   CHEMICAL REVIEWS

Beyond Stereoselectivity, Switchable Catalysis: Some of the Last Frontier Challenges in Ring-Opening Polymerization of Cyclic Esters

(2015) Sophie M. Guillaume et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Investigations of the Stereoselective Rare Earth Metal-Mediated Ring-Opening Polymerization of β-Butyrolactone

(2015) Peter T. Altenbuchner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone

(2015) Miao Hong et al.   Nature Chemistry

Rare-Earth Complexes Supported by Tripodal Tetradentate Bis(phenolate) Ligands: A Privileged Class of Catalysts for Ring-Opening Polymerization of Cyclic Esters

(2015) Jean-François Carpentier   ORGANOMETALLICS

Metal influence on the iso- and hetero-selectivity of complexes of bipyrrolidine derived salan ligands for the polymerisation of rac-lactide

(2015) Matthew D. Jones et al.   Chemical Science

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

(2015) D. C. Aluthge et al.   Chemical Science

From Syndiotactic Homopolymers to Chemically Tunable Alternating Copolymers: Highly Active Yttrium Complexes for Stereoselective Ring-Opening Polymerization of β-Malolactonates

(2014) Cédric G. Jaffredo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Size Influence in Iso-Selective Lactide Polymerization

(2014) Clare Bakewell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide

(2014) Matthew D. Jones et al.   CHEMICAL COMMUNICATIONS

Isoselective ring-opening polymerization of rac-lactide initiated by achiral heteroscorpionate zwitterionic zinc complexes

(2014) Zehuai Mou et al.   CHEMICAL COMMUNICATIONS

PMLABe Diol Synthesized by Ring-Opening Polymerization of Racemic Benzyl β-Malolactonate Initiated by Rare-Earth Trisborohydride Complexes: An Experimental and DFT Study

(2014) Cédric G. Jaffredo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gradient Isotactic Multiblock Polylactides from Aluminum Complexes of Chiral Salalen Ligands

(2014) Alessia Pilone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discrete O-Lactate and β-Alkoxybutyrate Aluminum Pyridine–Bis(naphtholate) Complexes: Models for Mechanistic Investigations in the Ring-Opening Polymerization of Lactides and β-Lactones

(2014) Joice S. Klitzke et al.   ORGANOMETALLICS

Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

(2014) Srinivas Abbina et al.   ACS Macro Letters

Highly diastereoselective synthesis of chiral aminophenolate zinc complexes and isoselective polymerization of rac-lactide

(2013) Haobing Wang et al.   CHEMICAL COMMUNICATIONS

Structurally well-defined group 4 metal complexes as initiators for the ring-opening polymerization of lactide monomers

(2013) Andreas Sauer et al.   DALTON TRANSACTIONS

Poly(hydroxyalkanoate) Block or Random Copolymers of β-Butyrolactone and Benzyl β-Malolactone: A Matter of Catalytic Tuning

(2013) Cédric G. Jaffredo et al.   MACROMOLECULES

Yttrium– and Aluminum–Bis(phenolate)pyridine Complexes: Catalysts and Model Compounds of the Intermediates for the Stereoselective Ring-Opening Polymerization of Racemic Lactide and β-Butyrolactone

(2013) Joice S. Klitzke et al.   ORGANOMETALLICS

A highly active and site selective indium catalyst for lactide polymerization

(2012) Dinesh C. Aluthge et al.   CHEMICAL COMMUNICATIONS

Yttrium Phosphasalen Initiators for rac-Lactide Polymerization: Excellent Rates and High Iso-Selectivities

(2012) Clare Bakewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Yttrium catalysts for syndioselective β-butyrolactone polymerization: on the origin of ligand-induced stereoselectivity

(2012) Jian Fang et al.   Polymer Chemistry

Exploring Electronic versus Steric Effects in Stereoselective Ring-Opening Polymerization of Lactide and β-Butyrolactone with Amino-alkoxy-bis(phenolate)-Yttrium Complexes

(2011) Miloud Bouyahyi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Single site catalysts for stereoselective ring-opening polymerization of lactides

(2010) Pieter Jelle Dijkstra et al.   Polymer Chemistry

Stereocontrolled ring-opening polymerisation of lactide

(2009) Matthew J. Stanford et al.   CHEMICAL SOCIETY REVIEWS

Stereocontrolled ring-opening polymerization of cyclic esters: synthesis of new polyester microstructures

(2009) Christophe M. Thomas   CHEMICAL SOCIETY REVIEWS

Syndiotactic-Enriched Poly(3-hydroxybutyrate)s via Stereoselective Ring-Opening Polymerization of Racemic β-Butyrolactone with Discrete Yttrium Catalysts

(2009) Noureddine Ajellal et al.   MACROMOLECULES

C3-Symmetric Lanthanide Tris(alkoxide) Complexes Formed by Preferential Complexation and Their Stereoselective Polymerization ofrac-Lactide

(2008) Polly L. Arnold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION