4.7 Article

Bright NUV mechanofluorescence from a terpyridine-based pure organic crystal

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 1, Pages 94-97

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08064f

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Funding

  1. National Natural Science Foundation of China [51673105, 51573081, 51473084]
  2. Open Project of the State Key Laboratory of Supramolecular Structure and Materials of Jilin University [SKLSSM-201728]

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A bright NUV mechanofluorescent terpyridine-based material with a piezoelectric space group was obtained. The single crystal analysis and quantum chemical calculations indicated the existence of enhanced intermolecular and intramolecular interactions and intersystem crossing, but which did not facilitate the room temperature phosphorescence.

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