Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 2, Pages 164-167Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08792f
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Funding
- NSFC [21232004, 21472071, 21602087]
- PAPD of Jiangsu Higher Education Institutions
- JSNU [YQ2015003]
- NSF of Jiangsu Province [BK20151163, BK20160212]
- Qing Lan Project of Jiangsu Education Committee
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The first thiazolium salt-catalyzed C-C triple bond cleavage of benzene-linked allene-ynes has been established. The reaction pathway involves [2+2] cycloaddition and ring-opening of in situ generated cyclobutenes with H2O under mild and convenient conditions, and provides practical access to substituted 1-naphthols with potentially valuable applications.
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