4.7 Article

Engineering nanoporous organic frameworks to stabilize naked Au clusters: a charge modulation approach

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 40, Pages 5058-5061

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc02966k

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Funding

  1. Division of Chemical Science, Geoscience, and Bioscience, Office of Basic Energy Sciences, US Department of Energy
  2. National Natural Science Foundation of China [21062013]
  3. Natural Science Foundation of Jiangxi Province [2011ZBAB203013]

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A simple charge modulation approach has been developed to stabilize naked Au clusters on a nanoporous conjugated organic network. Through engineering pore walls with regulated charges, the controllable growth of Au nanoclusters has been realized. The resulting supported catalyst exhibits excellent performance in the aerobic oxidation of alcohols.

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