4.7 Article

Task-specific design of a hierarchical porous aromatic framework as an ultrastable platform for large-sized catalytic active site binding

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 13, Pages 1603-1606

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc09767k

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Funding

  1. National Basic Research Program of China (973 Program) [2014CB931804]
  2. National Natural Science Foundation of China (NSFC Project) [21302061, 21531003]

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An amine-tagged hierarchical porous aromatic framework PAF70-NH2 with ultra-stability and narrowly distributed mesopores was synthesized. PAF70-NH2 has high potential for covalently immobilizing a relatively large-sized catalyst inside its pores. Thiswork gave a perfect example of using PAF70-NH2 as a platform for completely recyclable heterogeneous organocatalysis.

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