Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 46, Pages 5835-5838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01732h
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Funding
- Ministry of Science and Technology of the People's Republic of China [2016YFA0602900]
- National Natural Science Foundation of China [21572071, 21420102003]
- Guangdong Natural Science Foundation [2017A030313054]
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A novel four-component coupling reaction of carbon dioxide, amines, cyclic ethers and 3-triflyloxybenzynes has been developed for the first time, providing an efficient method for the synthesis of a series of functionalized carbamate derivatives in moderate to high yields. The process proceeds under mild, transition metal-free and fluoride-free conditions, leading to the formation of two new C-O bonds, one new C-N bond and one C-H bond in a single step.
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