Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 35, Pages 4410-4412Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc01005f
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Funding
- National Natural Science Foundation of China [21673255, 21533011]
- National Key Research and Development Program of China [2017YFA0403003]
- Chinese Academy of Sciences [QYZDY-SSW-SLH013]
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The synthesis of dimethyl carbonate (DMC) from CO2 and methanol is a very interesting reaction, but is thermodynamically limited. In this work, CaC2 was used to consume the water produced in the reaction to shift the reaction equilibrium, and C2H2 was produced at the same time. This is the first work on the combination of driving a thermodynamically unfavorable reaction and producing C2H2 using CaC2.
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