Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 11, Pages 1303-1306Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc08553b
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Funding
- National Natural Science Foundation of China [21702013, 21602119, U1504208]
- Fundamental Research Funds from the Central Universities in Beijing University of Chemical Technology [buctrc201721, PYCC1707]
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Organosulfides are a common class of structure units in bioactive molecules and functional materials motivating continuous developments of efficient synthetic methods. Herein, we report an electrophilic aryne-activated ring opening protocol of one or two heteroatom containing saturated sulfur heterocycles. This three-component transformation proceeds under mild reaction conditions and displays exceptional generality of nucleophiles (C, O, S, N, and F centered nucleophiles), giving structurally diverse thioethers in good yields.
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