Journal
CHEMCATCHEM
Volume 10, Issue 9, Pages 2041-2045Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201701992
Keywords
alkynes; azides; click chemistry; copper; N-heterocyclic carbenes
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Funding
- EPSRC [EP/K030760/1]
- Imperial College London
- Royal Society [RG140579]
- EPSRC [EP/K030760/1] Funding Source: UKRI
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A series of well-defined copper(I) complexes bearing ring-expanded N-heterocyclic carbene (NHC) ligands has been applied to the azide-alkyne cycloaddition reaction. The obtained results notably showed that the six-membered NHC ligands outperform well-established five-membered ones. [CuI(Mes-6)] displayed a remarkable catalytic activity while respecting the strict criteria for click reactions.
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