4.7 Article

Structural and magnetic properties of CoFe2O4 nanopowders, prepared using a modified Pechini method

Journal

CERAMICS INTERNATIONAL
Volume 44, Issue 1, Pages 530-536

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2017.09.207

Keywords

Nanoparticles; Cobalt ferrite; Sol-gel; Citric acids; Alcohols

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Cobalt ferrite nanopowders were synthesized by means of the sol-gel method, using citric acid as a chelating agent, and various alcohols as gelling agent: ethanol (ET), ethylene glycol (EG), polyvinyl alcohol (PVA), 1,3 propanediol (PD) and a mixture of PVA and EG. The simultaneous TG/DTA analysis revealed different thermal behaviours of the synthesized gels, depending on the gelling agent. The powders obtained at 500 degrees C and annealed at 700 degrees C and 1000 degrees C contain a single CoFe2O4 phase. Scanning electron microscopy (SEM) revealed the influence of the gelling agent on the morphology of cobalt ferrite particles. The coercivity and the saturation magnetization of the powders obtained at 500 degrees C showed a strong dependence on the crystallite size, determined by the nature of the gelling agent.

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