4.5 Article

A thermodynamic description of data for pure Pb from 0 K using the expanded Einstein model for the solid and the two state model for the liquid phase

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.calphad.2017.12.008

Keywords

Lead; Two state model for liquid phase; Thermodynamic assessment; Extended Einstein model

Funding

  1. Ministry of Education and Science of the Russian Federation of Increase Competitiveness Program of NUST MISIS [K2-2016-013, N211]
  2. Austrian Science Fund (FWF) [N211] Funding Source: Austrian Science Fund (FWF)

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Thermodynamic data for the crystalline and liquid phases of pure lead were critically assessed. A thermodynamic description was obtained using an extended Einstein model for the crystalline phase and a two state model for the liquid phase. The assessment was carried out through careful analysis of the experimental data published in the scientific literature. Additional measurements using enthalpy drop were also carried out in the present work to remove ambiguities in published experimental data.

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