4.7 Article

Two dimensional Z-scheme AgCl/Ag/CaTiO3 nano-heterojunctions for photocatalytic hydrogen production enhancement

Journal

APPLIED SURFACE SCIENCE
Volume 436, Issue -, Pages 519-526

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2017.12.065

Keywords

Z-scheme; Photocatalytic hydrogen production; Nano-heterojunction; Stability

Funding

  1. Natural Science Foundation of China [51672249, 51603187, 91122022]
  2. Zhejiang Provincial Natural Science Foundation of China [LQ17F040004, LY15E030011]

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The two dimensional(2D) Z-scheme AgCl/Ag/Ca/TiO3 nano-heterojunction is synthesized via simple preparation of hydrothermal-chemical co-deposition method. The results of SEM, EDS, elemental mapping, XRD, TEM, XPS and Raman shift imply that the AgCl/Ag nanoparticles have deposited on the surfaces of CaTiO3 nanosheets successfully. Compared with the unmodified samples, the photocatalytic activity of the as-prepared 2D AgCl/Ag/CaTiO3 nano-heterojunction exhibits a remarkable enhancement by the hydrogen production. Further, the photocatalytic process has been studied and the mechanism of the photocatalytic hydrogen production enhancement has been provided, which could be ascribed to the Z-scheme heterojunction and 2D lamellar structure of the CaTiO3. (C) 2017 Elsevier B.V. All rights reserved.

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