4.8 Article

Natural gas hydrate exploitation by CO2/H-2 continuous Injection-Production mode

Journal

APPLIED ENERGY
Volume 226, Issue -, Pages 10-21

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.apenergy.2018.05.098

Keywords

Hydrate; CO2/CH4 replacement; CO2/H-2 injection; CO2 sequestration; Continuous injection-production

Funding

  1. National Natural Science Foundation of China [21636009, 51576209, 51676207]
  2. National Key Research and Development Program of China [2016YFC0304003, 2017YFC0307302]

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CO2 replacement is considered as a promising method for the simultaneous development of natural gas hydrate and CO2 sequestration. The addition of small molecular gases, such as N-2 and H-2, into the injected gas can increase the gas recovery ratio and prevent CO2 liquefaction. Based on previous studies, this work presents methane hydrate exploitation using the CO2/H-2 continuous injection-production mode. The mechanism combines gas sweep with CH4/CO2 replacement. A series of experiments were carried out to optimize the injected gas composition and flow rate, which have a significant effect on the rate of CH4 hydrate decomposition, amount of CO2 sequestration, and cost. The compositions of the injected gases had little effect on the recovery rate when a relatively higher flow rate was employed. A balance between CH4 production and CO2 sequestration was established when the CO2 mole fraction was slightly < 74%, and the temperature of the reservoir did not decline throughout the whole process. The injection rate affected both the displacement efficiency and the production cost. Moreover, through these experiments, we discovered a more economically feasible and productive measure for regulating the injection rate.

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