Article
Engineering, Chemical
Yishuang Wang, Na Li, Mingqiang Chen, Defang Liang, Chang Li, Quan Liu, Zhonglian Yang, Jun Wang
Summary: In this study, the efficient conversion and utilization of glycerol steam reforming were achieved by optimizing the catalyst structure and preparation method. The appropriate Ca additive and hydrothermal synthesis method improved the catalyst reducibility and CO2 adsorption capacity. The Ni-6Ca/ATP-hs catalyst exhibited the highest glycerol conversion and H-2 yield, as well as excellent anti-sintering and coke resistance.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Mingqiang Chen, Jiaxin Hu, Yishuang Wang, Chunsheng Wang, Zhiyuan Tang, Chang Li, Defang Liang, Wen Cheng, Zhonglian Yang, Han Zhang
Summary: Steam reforming of acetic acid over Ti-modified Ni/Attapulgite catalysts showed promising hydrogen production efficiency, attributed to the synergistic effects among Ti species, Ni active metal, and Attapulgite support, as well as the optimized precipitation sequence determining the surface properties of the catalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Weijun Qiao, Shuqian Yang, Lei Zhang, Yuan Tian, Honghao Wang, Caishun Zhang, Zhixian Gao
Summary: Different divalent metals were used to prepare Cu-Ce/M-Al catalysts for hydrogen production from methanol steam reforming, with Ce-Cu/Zn-Al catalyst showing the best performance. The dispersion, reduction temperature, and oxygen vacancies on the surface played key roles in determining the catalytic performance of the catalysts. At optimal conditions, the methanol conversion reached 100% and the H-2 production rate was 779.7 STP cm(3) kg(-1) s(-1).
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Physical
Xu Qingli, Zhang Zhengdong, Huang Kai, Xin Shanzhi, Mao Chuang, Chen Chenge, Yang Huan, Yue Yang, Yan Yongjie
Summary: A series of Mg-modified Ni/Attapulgite (ATP) catalysts were prepared for glycerol steam reforming, and the Ni/10MgO/ATP catalyst showed the best performance with high activity, hydrogen yield, and stability. The addition of Mg inhibited nickel sintering and carbon formation, enhancing the catalyst activity and longevity.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Energy & Fuels
Mingqiang Chen, Guowei Sun, Yishuang Wang, Defang Liang, Chang Li, Jun Wang, Quan Liu
Summary: The study focuses on improving the catalytic performance of methanol steam reforming (MSR) by supporting Cu-Zr components on AZ, which enhances the catalytic activity and promotes efficient hydrogen production.
Article
Energy & Fuels
Mingqiang Chen, Xiaoyang Feng, Yishuang Wang, Defang Liang, Chang Li, Zhonglian Yang, Jun Wang
Summary: In this study, attapulgite-based MCM-41 (AM) was synthesized using attapulgite as a silicon source, and AM-supported Ni/Ce/Zr catalysts were manufactured by sol-gel assisted impregnation method. It was found that the optimal Ce-Zr additives and calcination temperature could enhance the electronic interaction among Ni/Ce/Zr components, resulting in the highest ethanol conversion rate and stability of the catalyst. This study provides a new opportunity for the preparation of efficient and low-cost AM-supported Ni/Ce/Zr catalysts for ethanol steam reforming.
Article
Chemistry, Physical
Surendar Moogi, Lingaiah Nakka, S. Sai Prasad Potharaju, Ashfaq Ahmed, Abid Farooq, Sang-Chul Jung, Gwang Hoon Rhee, Young-Kwon Park
Summary: Different cobalt-based mixed oxide catalysts were synthesized and tested for hydrogen production from glycerol steam reforming, with the 5Cu20CM catalyst showing the best performance attributed to its small particle size, high dispersion, and large surface area.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Analytical
Yishuang Wang, Zhiheng Lu, Mingqiang Chen, Defang Liang, Jun Wang
Summary: Tar formation is a major challenge in biomass gasification, but catalytic steam reforming (CSR) can potentially convert tar into hydrogen. This study successfully prepared a series of NixFeyMn/ATP catalysts and applied them to CSR of toluene, a model tar compound. The addition of trace amounts of Fe and Mn improved the catalyst's stability and activity.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)
Article
Chemistry, Physical
D. H. D. Rocha, T. A. Z. de Souza, C. J. R. Coronado, J. L. Silveira, R. J. Silva
Summary: The study found that by recycling the residual gas with high concentration of water and CO2, the glycerol reforming capacity can be maximized while increasing the system's overall exergy efficiency. This process was evaluated in three different scenarios regarding reform gas processing from technical and environmental perspectives.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Kang Gao, Ommolbanin Alizadeh Sahraei, Maria C. Iliuta
Summary: The physicochemical properties of low-efficiency coal fly ash were significantly improved through simple acid/alkali treatments, enhancing the catalytic activity for glycerol steam reforming. Alkali-LPD proved more effective than acid-LPD in improving the surface area and elemental distribution of the fly ash.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
Article
Chemistry, Physical
M. Salome Macedo, Elka Kraleva, Heike Ehrich, M. A. Soria, Luis M. Madeira
Summary: A comparative study of Co-based catalysts supported on La2O3, AlZnOx and AlLaOx for glycerol steam reforming was conducted. The results showed that CoAlLaOx exhibited superior carbon resistance, while NiAlLaOx demonstrated good catalytic stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Multidisciplinary
Yunzhu Wang, Songshan Zhu, Sufang He, Jichang Lu, Jiangping Liu, Huihui Lu, Di Song, Yongming Luo
Summary: CeO2 nanosphere-supported nickel catalysts were directly reduced by H-2 without calcination, which enhanced the concentration of oxygen vacancies, improved the nickel dispersion and reduction, and resulted in superior catalytic performance for hydrogen production from glycerol steam reforming.
Article
Green & Sustainable Science & Technology
Chunsheng Wang, Yishuang Wang, Mingqiang Chen, Defang Liang, Wen Cheng, Chang Li, Zhonglian Yang, Jun Wang
Summary: Treatment with molten NaOH can enhance the surface area of SEP and improve its surface reactivity, leading to better catalytic performance in bio-glycerol steam reforming.
Article
Green & Sustainable Science & Technology
M. Salome Macedo, M. A. Soria, Luis M. Madeira
Summary: In recent years, glycerol steam reforming (GSR) has been a focus of interest for the production of green hydrogen, with researchers focusing on GSR thermodynamics, catalyst development, reaction kinetics and mechanisms, reactor models, and innovative reactor configurations.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2021)
Article
Chemistry, Physical
Shuangxia Yang, Yu Li, Lei Chen, Guiying Xu, Jianjun Hou, Laizhi Sun, Tianjin Li, Xinping Xie, Xiaolu Yi, Baofeng Zhao, Hongyu Si, Dongliang Hua
Summary: In this study, LDHs-derived Ni-Al nanosheet arrays (NiAl/NA) were synthesized via a one-step hydrothermal method and used in the steam-reforming of glycerol reaction for enhanced and stable hydrogen production. The catalysts were characterized using various techniques, and the results showed that smooth and cross-linked Ni-Al mixed metal oxide nanosheets grew on the Ni foam substrate. The NiAl/NA catalyst exhibited improved glycerol conversion, higher H-2 yield, and longer stability compared to traditional Ni-Al nanosheet powder, mainly due to its array structures providing improved reducibility and more exposed active sites.
Article
Thermodynamics
Chunsheng Wang, Yishuang Wang, Mingqiang Chen, Jiaxin Hu, Defang Liang, Zhiyuan Tang, Zhonglian Yang, Jun Wang, Han Zhang
Summary: The study revealed that in simulated bio-oil steam reforming experiments, the regenerability of Co/Al2O3 catalyst was not successful in restoring its activity, while the Co/SEP catalyst showed better regeneration performance, mainly due to the alleviation of Co sintering.
Article
Chemistry, Physical
Mingqiang Chen, Jiaxin Hu, Yishuang Wang, Chunsheng Wang, Zhiyuan Tang, Chang Li, Defang Liang, Wen Cheng, Zhonglian Yang, Han Zhang
Summary: Steam reforming of acetic acid over Ti-modified Ni/Attapulgite catalysts showed promising hydrogen production efficiency, attributed to the synergistic effects among Ti species, Ni active metal, and Attapulgite support, as well as the optimized precipitation sequence determining the surface properties of the catalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Review
Chemistry, Physical
Chunsheng Wang, Yishuang Wang, Mingqiang Chen, Defang Liang, Zhonglian Yang, Wen Cheng, Zhiyuan Tang, Jun Wang, Han Zhang
Summary: This review discusses recent advances in the development of efficient and stable catalysts for methane dry reforming, with a focus on novel materials, advanced characterizations, and improved reaction system compatibility. Crystalline oxide catalysts and new materials demonstrate superior reactivity and stability, while progress in advanced characterizations has led to the establishment of reaction mechanisms. Efforts are also being made to upgrade reaction systems for higher efficiency and milder conditions.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Mingqiang Chen, Defang Liang, Yishuang Wang, Chunsheng Wang, Zhiyuan Tang, Chang Li, Jiaxin Hu, Wen Cheng, Zhonglian Yang, Han Zhang, Jun Wang
Summary: Ethanol steam reforming (ESR) is a promising technology for hydrogen production, but efficient Ni-based catalysts are still a challenge. In this study, M-Ni/ Sepiolite catalysts were synthesized and characterized, showing that La, Mg, and Ca promoters enhance Ni-0 active sites. The Ca-Ni/SEP catalyst exhibited high carbon conversion and hydrogen yield due to small Ni particle size and strong metal-support interaction.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Environmental
Mingqiang Chen, Zhiyuan Tang, Yishuang Wang, Jingjing Shi, Chang Li, Zhonglian Yang, Jun Wang
Summary: Phosphorus-modified Mo/Sepiolite catalysts can regulate Kraft lignin conversion, reducing lignin oil yield and HHV while significantly increasing the productivity of phenolic compounds. The optimized distribution between Mo5+ sites and acid strength/type in 5P-Mo/SEP results in lignin oil with a higher HHV compared to Kraft lignin.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Energy & Fuels
Mingqiang Chen, Jingjing Shi, Yishuang Wang, Zhiyuan Tang, Zhonglian Yang, Jun Wang, Han Zhang
Summary: The highly efficient conversion of lignin to value-added liquid fuel or phenol monomers has attracted widespread attention. A W-Ni-Mo/SEP trimetallic catalyst was prepared for lignin catalytic depolymerization under supercritical ethanol, significantly improving the cycle stability and product selectivity compared to Mo/SEP. The catalyst formation increased oxygen vacancies, enhanced metal-support interaction, and reduced acid site content, leading to the production of lignin oil with higher HHV and increased selectivity to guaiacol and ethoxyphenol monomers.
Article
Chemistry, Physical
Wen Cheng, Yishuang Wang, Mingqiang Chen, Defang Liang, Chang Li, Zhonglian Yang, Jun Wang
Summary: In this study, nickel-based catalysts supported on modified attapulgite (ATP) were prepared and applied to the aqueous phase reforming of glycerol (APRG). The results showed that the acid/base treatment of ATP significantly improved the catalytic performance, resulting in higher glycerol conversion and hydrogen selectivity. The bimetallic NiFe/MA-E catalyst exhibited the best performance at low temperature. Catalyst deactivation was mainly caused by particle agglomeration and carbon deposition.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Green & Sustainable Science & Technology
Chunsheng Wang, Yishuang Wang, Mingqiang Chen, Defang Liang, Wen Cheng, Chang Li, Zhonglian Yang, Jun Wang
Summary: Treatment with molten NaOH can enhance the surface area of SEP and improve its surface reactivity, leading to better catalytic performance in bio-glycerol steam reforming.
Article
Engineering, Environmental
Mingqiang Chen, Jinhui Zhang, Yishuang Wang, Zhiyuan Tang, Jingjing Shi, Chunsheng Wang, Zhonglian Yang, Jun Wang, Han Zhang
Summary: In this study, Mo/SEP catalysts were prepared by an incipient-wetness impregnation method and it was found that calcination at 400 degrees Celsius exhibited optimal catalytic activity, resulting in the highest lignin oil yield.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Ming-Yi Chen, Ngoc Thanh Thuy Tran, Ahmed Abubakar Alao, Wen-Dung Hsu
Summary: This study demonstrates the significance of surface Pt atom arrangement for the efficiency of ORR in PEMFCs and reveals the correlation between Pt-Pt average distance and O2 dissociation barrier. Furthermore, the study discovers a robust correlation between the level of the catalyst's d-band center and O2 adsorption energy. High-entropy alloy substrates provide potential for controlling Pt arrangement and O2 dissociation barrier.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Eduardo C. Atayde Jr, Babasaheb M. Matsagar, Yu-Cheng Wang, Kevin C. -W. Wu
Summary: This study presents the first application of an acidic MOF, Sulfated MOF-808, in catalyzing the HAA reactions of furan oligomers for the production of biofuel precursors. The catalyst showed high yield, selectivity, and recyclability, making it versatile for different starting materials.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Maria do Carmo Rangel, Francieli Martins Mayer, Soraia Jesus de Oliveira, Sergio Gustavo Marchetti, Fabricio Luiz Faita, Doris Ruiz, Giovanni Saboia, Mariana Kieling Dagostini, Jonder Morais, Maria do Carmo Martins Alves
Summary: This study developed a new catalyst by investigating the effect of magnesium on the catalytic properties of hematite in ethylbenzene dehydrogenation. The catalyst showed important differences in activity, selectivity, and stability, making it a promising candidate for commercial applications.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yanjun Li, Qian Wang, Hui Tian, Mingyuan Zhu, Yuanyuan Liu
Summary: A novel strategy using microwave-assisted precipitation was proposed to prepare defective CsH3PMo11VO40 catalyst for the oxidation of methacrolein to methacrylic acid. Microwave treatment accelerates crystallization, increases vanadyl species content, and forms defective Keggin structures, thereby enhancing the oxidation capacity of the catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Rajeshwari Athavale, Sailee Gardi, Fatima Choudhary, Dayanand Patil, Nandkishor Chandan, Paresh More
Summary: In this study, a novel acidic ionic liquid catalyst was prepared and used for the synthesis of bis-indolyl methane derivatives. The catalyst exhibited short reaction times, easy purification, and reusability.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Masatomo Hattori, Takato Hattori, Masakuni Ozawa
Summary: Cu-added gamma-Al2O3 catalysts were prepared with varying Cu loadings and the effects of copper oxidation states on catalytic activity were investigated. The results showed that the addition of copper increased the catalyst activity, but excessive copper loading decreased catalytic activity. XRD and TEM analysis indicated the formation of a solid solution of copper oxide species on the surface of gamma-Al2O3. XAS and TPR data demonstrated variations in copper oxidation states among the catalysts.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liwei Fang, Shiyang Niu, Shengsen Wang, Yiqing Lu, Yuanhui Cheng
Summary: In this study, PtNi alloy on nitrogen-doped carbon and SnO2 dual-support was designed to modulate the metal-support interaction, resulting in improved catalytic activity and stability for oxygen reduction reaction. The SnO2/PtNi/NC catalyst exhibited a strongly coupled interface, enhanced electron transfer, and higher half-wave potential compared to PtNi/NC and commercial Pt/C.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Shohei Harada, Duanxing Li, Kenta Iyoki, Masaru Ogura
Summary: This study investigates the catalytic performance of a composite catalyst composed of ZnZrOX and H-zeolite for the hydrogenation of CO2. The deactivation of the composite catalyst is influenced by ion exchange of Zn2+ and/or coke, with their effects differing based on the zeolite structure. Separating the grains of the composite catalyst can prevent deactivation.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Laura Proano, Christopher W. Jones
Summary: In this study, NiGa alloy particles supported on CeO2, ZrO2, and ZrO2-CeO2 solid solutions were prepared and characterized. The nature of the support was found to have a significant influence on the catalyst's activity and selectivity, with the crystalline structure of ZrO2 having the greatest impact. Pure ZrO2 showed the highest methanol selectivity and CO2 conversion at high Zr:Ce ratios. In equimolar and Ce-rich conditions, basic sites and oxygen vacancies were found to be the key parameters affecting methanol production.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Liyan Zhang, Yinze Yang, Leilei Zhou, Fengyu Zhao, Haiyang Cheng
Summary: 1,6-Hexamethylenediamine was successfully synthesized via the reductive amination of 1,6-hexanediol using a Ru/PRL(x)-Al2O3 catalyst. The highly dispersed and anchored Ru species, formed by 1,10-phenanthroline (PRL), played a crucial role in the catalytic reaction. The formation of new acid-base pairs, electron deficient Ru species, and smaller nanoparticles contributed to the improved catalytic performances of the Ru/PRL-Al2O3 catalyst.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Anita Horvath, Miklos Nemeth, Andrea Beck, Gyorgy Safran, Valeria La Parola, Leonarda Francesca Liotta, Gregor Zerjav, Matevz Roskaric, Albin Pintar
Summary: This study investigates the catalytic and structural changes caused by the addition of 0.25 wt% indium in a 3% Ni/CeO2-Al2O3 catalyst prepared by impregnation method. The results show that the addition of indium can decrease the activity of the catalyst, but it improves its stability and reduces coking.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Ankush Kularkar, Vaibhav Vilas Khedekar, Sachin D. Chaudhari, Mudavath Ravi, Sadhana S. Rayalu, Penumaka Nagababu
Summary: Efficiently addressing the challenges of photocatalytic CO2 reduction to CH3OH is crucial. This study developed Zn-BTC MOF and its composites with CaIn2S4, achieving highly efficient and robust photocatalytic CO2 reduction to CH3OH under ambient conditions, using H2O2 as the hydrogen source. Among the composites, ZMCIS4 demonstrated excellent performance with a CH3OH evolution of 49100 μmol/g.cat and a quantum efficiency of approximately 78.41%. The enhanced performance was attributed to the production of nascent hydrogen atoms (H center dot) through the photo-splitting of H2O2 on the ZMCIS surface.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Dan Liu, Yudong Li, Chengyu Wang, Haiyue Yang, Rong Wang, Shujun Li, Xiaohui Yang
Summary: In this study, a self-supporting three-dimensional porous Co3O4 nanobelt array decorated on nickel foam (P-Co3O4 -NBA@NF) electrode with numerous active sites was successfully constructed for the oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-furan dicarboxylic acid (FDCA). The P-Co3O4 -NBA@NF electrode demonstrated high conversion efficiency, selectivity, and Faraday efficiency, as well as remarkable long-term stability. This research provides a promising electrocatalyst for biomass conversion.
APPLIED CATALYSIS A-GENERAL
(2024)
Article
Chemistry, Physical
Yimin Li, Enggah Kurniawan, Fumiya Sato, Takayoshi Hara, Yasuhiro Yamada, Satoshi Sato
Summary: In this study, several silica-alumina catalysts modified with Ag were examined for the dehydration of 1,3-butanediol to 1,3-butadiene. Among them, an amorphous silica-alumina catalyst (SAL-3) modified with Ag showed the highest improvement in catalytic activity and stability when operated in H2 flow. The generation of reversible acid sites was found to be the reason behind the enhanced activity and stability of this Ag/SAL-3 catalyst. The effects of various parameters on the catalytic activity of Ag/SAL-3, such as reaction temperature, contact time, Ag content, and carrier gas, were investigated.
APPLIED CATALYSIS A-GENERAL
(2024)