Bis(perchlorocatecholato)silane-A Neutral Silicon Lewis Super Acid

The Lewis superacid Al[N(C6F5)2]3 and its higher homolog Ga[N(C6F5)2]3 – structural features, theoretical investigation and reactions of a metal amide with higher fluoride ion affinity than SbF5

(2018) J. F. Kögel et al.   Chemical Science

Efficient DLPNO–CCSD(T)-Based Estimation of Formation Enthalpies for C-, H-, O-, and N-Containing Closed-Shell Compounds Validated Against Critically Evaluated Experimental Data

(2017) Eugene Paulechka et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Synthesis of Functional Bis(pentafluoroethyl)silanes (C2 F5 )2 SiX2 , with X=H, F, Cl, Br, OPh, and O2 CCF3

(2016) Nico Schwarze et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Neutral Silicon/Phosphorus Frustrated Lewis Pair

(2015) Benedikt Waerder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elusive Silane-Alane Complex [SiH⋅⋅⋅Al]: Isolation, Characterization, and Multifaceted Frustrated Lewis Pair Type Catalysis

(2015) Jiawei Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

(2015) Martin Oestreich et al.   CHEMICAL SOCIETY REVIEWS

Molecular complexes of group 13 element trihalides, pentafluorophenyl derivatives and Lewis superacids

(2015) E.I. Davydova et al.   COORDINATION CHEMISTRY REVIEWS

From unsuccessful H2-activation with FLPs containing B(Ohfip)3 to a systematic evaluation of the Lewis acidity of 33 Lewis acids based on fluoride, chloride, hydride and methyl ion affinities

(2015) Hannes Böhrer et al.   DALTON TRANSACTIONS

Review of recent advances in CF bond activation of aliphatic fluorides

(2015) Qian Shen et al.   JOURNAL OF FLUORINE CHEMISTRY

Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound

(2015) Allegra L. Liberman-Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal SiH4 chemistry using stable and easy-to-handle surrogates

(2015) Antoine Simonneau et al.   Nature Chemistry

Synthesis of Chlorosilicates

(2014) Simon Steinhauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Squeezing Fluoride out of Water with a Neutral Bidentate Antimony(V) Lewis Acid

(2014) Masato Hirai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An efficient and near linear scaling pair natural orbital based local coupled cluster method

(2013) Christoph Riplinger et al.   JOURNAL OF CHEMICAL PHYSICS

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

Separating Electrophilicity and Lewis Acidity: The Synthesis, Characterization, and Electrochemistry of the Electron DeficientTris(aryl)boranes B(C6F5)3–n(C6Cl5)n(n= 1–3)

(2011) Andrew E. Ashley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Triflimidates: Better than Metal Triflates as Catalysts in Organic Synthesis-The Effect of a Highly Delocalized Counteranion

(2010) Sylvain Antoniotti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and accurate approximations to the local coupled cluster singles doubles method using a truncated pair natural orbital basis

(2009) Frank Neese et al.   JOURNAL OF CHEMICAL PHYSICS

Simple Access to the Non-Oxidizing Lewis Superacid PhF→Al(ORF)3(RF=C(CF3)3)

(2008) Lutz O. Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Triethylsilane

(2008) Jian Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY