Article
Chemistry, Analytical
Pilaipan Chaikhan, Yuthapong Udnan, Richmond J. Ampiah-Bonney, Wipharat Chuachuad Chaiyasith
Summary: A novel hybrid air-assisted solvent terminated dispersive liquid-liquid microextraction (AA-ST-DLLME) method using a domestic fish-tank pump as a bubble generator was developed for the determination of Pb in water and beverage samples by GFAAS. The method achieved a high enrichment factor, preconcentration factor, and extraction efficiency under optimized conditions, with low LOD and LOQ. The method was successfully applied for the determination of trace level of Pb in various samples, with satisfactory spiked recovery results and good agreement with standard reference materials.
MICROCHEMICAL JOURNAL
(2021)
Review
Chemistry, Analytical
Idaira Pacheco-Fernandez, Raul Gonzalez-Martin, Francisca A. e Silva, Mara G. Freire, Veronica Pino
Summary: The successful mode of liquid-phase microextraction (LPME) is dispersive liquid-liquid microextraction (DLLME), with advances focused on utilizing green, smart, and tunable materials as extraction solvents to enhance sustainability and efficiency. Hydrophilic media are considered a promising alternative for improving mass transfer and extraction efficiency.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Shizhong Chen, Chenghao Zhang, Juntao Yan, Chunlei Wang, Dengbo Lu
Summary: This study proposes an efficient method for the analysis of Te(IV) and Te(VI) using ultrasound-assisted dispersive liquid-liquid microextraction with deep eutectic solvent (DES) as an extractant. The method utilizes ammonium pyrroinedithiocarbamate (APDC) as a chelating reagent for Te(IV) and choline chloride and phenol to prepare DES for extraction of Te(IV)-APDC complexes. The results show that Te(IV) can be quantitatively extracted in the pH range of 5.0-8.0, while Te(VI) remains in the aqueous phase. The method demonstrates high sensitivity and accuracy, and has been successfully applied to the analysis of Te(IV) and Te(VI) in beverage samples.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Analytical
Valfredo Azevedo Lemos, Jeferson Alves Barreto, Luana Bastos Santos, Rosivan dos Santos de Assis, Cleber Galvao Novaes, Ricardo J. Cassella
Summary: Dispersive liquid-liquid microextraction (DLLME) is widely used for the separation and preconcentration of various chemical species, with some systems using a syringe as an extraction environment. This review discusses methods utilizing this approach, critical aspects like dispersion promotion, analytical characteristics, and the pros and cons of the methods, as well as future trends in in-syringe microextraction systems.
Article
Chemistry, Analytical
Ghada G. El-Gamal, Wael I. Mortada, Mohamed M. Hassanien, Amr A. Ibrahim, Yasmeen G. Abou El-Reash
Summary: This article presents a new method for the separation of thorium ions using Morin to form a stable complex in an acidic medium, combined with SFODME technology. Under optimized conditions, the method showed low detection limits, good reproducibility, and successful application in phosphate rock and ceramic tile samples.
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
(2021)
Article
Chemistry, Analytical
D. Sai Krishna, K. Madhavi, N. N. Meeravali, A. C. Sahayam
Summary: A rapid and highly sensitive vesicle mediated dispersive liquid-liquid microextraction procedure has been developed for the determination of parts per quadrillion level of beryllium in seawater and air filter samples. The method uses anionic vesicular surfactant and chelating agents to selectively extract beryllium, achieving excellent detection limits and recoveries across a range of sample types.
ANALYTICA CHIMICA ACTA
(2022)
Article
Environmental Sciences
Toraj Ahmadi Jouybari, Hadi Ahmadi Jouybari, Fatemeh Hosseini, Mohsen Nesari, Nazir Fattahi
Summary: Drug dealers add lead compounds to drugs for higher profit, leading to lead poisoning in drug users. Therefore, it is crucial to check their blood lead levels. This study developed an efficient and eco-friendly method using deep eutectic solvent for pretreatment and graphite furnace atomic absorption spectrometry for analysis, showing promising results for lead analysis in biological samples.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Biochemistry & Molecular Biology
Quan Han, Yaqi Liu, Yanyan Huo, Dan Li, Xiaohui Yang
Summary: A novel method based on DLLME and GFAAS has been developed for the determination of ultra-trace cobalt. The method utilizes the color reaction between Co2+ and 5-Br-PADMA in a buffer solution to achieve cobalt enrichment and separation through DLLME. Under optimal conditions, the method shows good linearity, low detection limit, and high extraction efficiency, and has been successfully applied to the determination of cobalt in water samples.
Article
Chemistry, Analytical
Dan Tie, Xuan Chen, Run-qin Wang, Shuang Hu, Li Yang, Yuan Zheng
Summary: A new PCSS-DLPME method combined with HPLC was developed for simultaneous preconcentration and determination of flavonoids in Ginkgobiloba, Platycladus orientalis, and Scutellaria. The method has advantages of simple preparation, high enrichment, good sensitivity, and selectivity for flavonoids.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Lingjun Hou, Yinghe Ji, Jing Zhao, Longshan Zhao
Summary: A vortex assisted-liquid-liquid microextraction (VA-LLME) pretreatment method using superparamagnetic nanofluid and deep eutectic solvents was developed for the isolation and preconcentration of quinolones in milk sample. The method proved to be simple, quick, and efficient, with high sensitivity and good recovery rates.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Analytical
Bereket Tesfaye, Abera Gure, Tsegaye Girma Asere, Guyo Jilo Molole
Summary: A deep eutectic solvent-based dispersive liquid-liquid microextraction method was developed for the extraction and preconcentration of organochlorine pesticides from water and apple juice samples. The method showed good linearity, low detection limits, and high recovery values, indicating it to be a rapid, simple, and environmentally-friendly alternative for determining OCPs in various matrices.
MICROCHEMICAL JOURNAL
(2023)
Article
Biochemistry & Molecular Biology
Chiara Dal Bosco, Francesca Mariani, Alessandra Gentili
Summary: A green solvent-based DLLME/HPLC-MS method has been developed for the determination of 19 pesticides in wine samples. The method shows high recovery, good precision, and low detection limits, making it a quick and cost-effective analysis.
Article
Chemistry, Analytical
Ruiting Niu, Honglin Qin, Yuan Tao, Lingdong Li, Lizhen Qiao
Summary: In this work, several new in situ deep eutectic solvents (DESs) were prepared using low toxic phenols and biodegradable esters, and the DESs were formed at room temperature. The DES-based DLLME approach exhibited good linearity, low limits of detection, high enrichment factors, and extraction recoveries. The proposed method was successfully applied for the determination of phthalate esters in water and beverage samples, showing good practical applicability.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Analytical
Xiaoyi Pu, Xin Wang, Youping Liu, Xin Di
Summary: In this study, a novel deep eutectic solvent was synthesized and used for the extraction of quinolones in environmental water. The method was found to be fast, sensitive, and environmentally friendly.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Applied
Xu Jing, Haoyue Xue, Xiaoyan Sang, Xiaowen Wang, Liyan Jia
Summary: A simple and efficient pretreatment method was established for the detection of mefentrifluconazole enantiomers in cereal samples. The method utilized dispersive liquid-liquid microextraction coupled with ultra-high-performance liquid chromatography-diode array detector. The use of magnetic deep eutectic solvent as the extractant allowed for simplification and acceleration of the process.
Article
Environmental Sciences
Mahdi Ghorbani, Alireza Shams, Orkideh Seyedin, Nahid Afshar Lahoori
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2018)
Article
Biochemical Research Methods
Mahdi Ghorbani, Mahmoud Chamsaz, Mohsen Aghamohammadhasan, Alireza Shams
ANALYTICAL BIOCHEMISTRY
(2018)
Article
Chemistry, Analytical
Mandi Ghorbani, Mohsen Aghamohammadhasan, Alireza Shams, Farzaneh Tajfirooz, Reza Pourhassan, Seyyede Raziye Bana Khosravi, Elahe Karimi, Ali Jampour
MICROCHEMICAL JOURNAL
(2019)
Article
Chemistry, Analytical
M. Ghorbani, M. Esmaelnia, M. Aghamohammadhasan, H. Akhlaghi, O. Seyedin, Z. Ahmadi Azari
JOURNAL OF ANALYTICAL CHEMISTRY
(2019)
Article
Chemistry, Analytical
Mahdi Ghorbani, Toktam Pedramrad, Mohsen Aghamohammadhasan, Orkideh Seyedin, Klossien Akhlaghi, Nahid Afshar Lahoori
MICROCHEMICAL JOURNAL
(2019)
Review
Chemistry, Analytical
Mahdi Ghorbani, Mohsen Aghamohammadhassan, Mahmoud Chamsaz, Hossien Akhlaghi, Toktam Pedramrad
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2019)
Review
Environmental Sciences
Mahdi Ghorbani, Orkideh Seyedin, Mohsen Aghamohammadhassan
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2020)
Article
Engineering, Environmental
Zinat Gordi, Mahdi Ghorbani, Maryam Ahmadian Khakhiyani
WATER ENVIRONMENT RESEARCH
(2020)
Article
Chemistry, Multidisciplinary
Mahdi Ghorbani, Shiva Ariavand, Mohsen Aghamohammadhasan, Orkideh Seyedin
Summary: A novel, green, and stable sorbent was synthesized and effectively removed heavy metal ions from wastewater samples. The sorbent showed high efficiency, environmental-friendliness, low cost, and short absorption time, making it suitable for the removal of Cr(VI), Pb(II), and Cd(II) ions. The experimental results confirmed the favorable adsorption performance of the sorbent.
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Analytical
Parisa Mohammadi, Mahdi Ghorbani, Parinaz Mohammadi, Majid Keshavarzi, Ayoob Rastegar, Mohsen Aghamohammadhassan, Ava Saghafi
Summary: A new method was developed for the extraction and simultaneous measurement of two organophosphorus pesticides residues in rice, cucumber, tomato, and mice liver samples. The magnetic NH2-MIL-53(Al)@ Chitosan sorbent prepared in this study showed high extraction efficiency and precision under optimized conditions.
MICROCHEMICAL JOURNAL
(2021)
Article
Chemistry, Analytical
Mahdi Ghorbani, Parisa Mohammadi, Majid Keshavarzi, Mohammad Hossien Saghi, Morteza Mohammadi, Alireza Shams, Mohsen Aghamohammadhasan
Summary: A dispersive micro solid-phase extraction procedure utilizing a novel and selective sorbent was developed for extracting organophosphorus pesticides in various samples. By optimizing the sorbent composite and parameters, efficient extraction of the pesticides was achieved, enabling residue detection in different types of samples.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Analytical
Parisa Mohammadi, Mahdi Ghorbani, Majid Keshavarzi, Ayoob Rastegar, Maryam Pakseresht, Morteza Mohammadi
Summary: A straightforward and efficient dispersive micro solid-phase extraction method was developed for extracting bicalutamide and flutamide as anti-cancer drugs in water and biological samples. The method showed good linearity, low detection limits, and good reproducibility for both drugs. The analysis of real samples demonstrated the high efficacy of the method for analyzing water and biological samples.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
(2022)
Review
Chemistry, Analytical
Mahdi Ghorbani, Parisa Mohammadi, Majid Keshavarzi, Aliakbar Ziroohi, Morteza Mohammadi, Mohsen Aghamohammadhasan, Maryam Pakseresht
Summary: Antidepressants are a crucial class of drugs for treating depression, and determining their presence in biological samples is important for controlling adverse effects and studying their pharmacokinetics. However, the low concentration and high matrix effects of these drugs in samples present a challenge for direct measurement. Sample preparation techniques, such as extraction and microextraction, are used to overcome these difficulties. This review investigates various extraction and microextraction methods for antidepressants in biological, water, and wastewater samples, and discusses their advantages, disadvantages, and recent developments.
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY
(2023)
Review
Chemistry, Analytical
Mahdi Ghorbani, Mohsen Aghamohammadhassan, Haniyeh Ghorbani, Ali Zabihi
MICROCHEMICAL JOURNAL
(2020)
Article
Biochemical Research Methods
Samaneh Akbarzade, Mahmoud Chamsaz, Gholam Hossein Rounaghi, Mahdi Ghorbani
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
(2018)
Article
Chemistry, Analytical
Gang Qu, Yuxin Zhao, Qiaoli Zhang, Jina Wu, Xiaosen Li, Yang Yang, Shilei Liu
Summary: In this study, magnetic mesoporous materials combined with real-time in situ mass spectrometry were used for the high-throughput detection of hydrolyzed products of organophosphorus nerve agents. The method showed good linearity, low limits of detection and quantification, and high extraction recoveries. The magnetic preparation method used was quick, cost-effective, rugged, and safe. The results demonstrated the potential of this method for rapid and efficient determination of the target analytes in environmental samples.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Anna Hildebrand, Mariam Merchant, Danny O'Hare
Summary: Substandard and falsified artemisinin derivatives in antimalarials have caused significant deaths and economic losses. This study evaluates the feasibility of voltammetric methods for identifying and quantifying artemether. The findings suggest that electrochemical analysis shows promise as a method for artemether identification and quantification.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Marx Osorio Araujo Pereira, Alvaro Ferreira Junior, Edson Silvio Batista Rodrigues, Helena Mulser, Giovanna Nascimento de Mello e Silva, Wallans Torres Pio dos Santos, Eric de Souza Gil
Summary: Brazilian spotted fever (BSF) is a serious and rapidly evolving disease. A new impedimetric immunosensor was developed for rapid diagnosis by measuring specific antibodies in plasma. The sensor demonstrated selectivity and accuracy, and has potential for important applications in diagnostic testing.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Kathrin Schilling, Ronald A. Glabonjat, Olgica Balac, Marta Galvez-Fernandez, Arce Domingo-Relloso, Vesna Slavkovich, Jeff Goldsmith, Miranda R. Jones, Tiffany R. Sanchez, Ana Navas-Acien
Summary: Analysis of trace elements in urine is an important tool for assessing exposures, diagnosing nutritional status, and guiding public health and healthcare intervention. This study provides a sensitive method for analyzing 18 elements in urine samples, using only 100 μL. The results show good accuracy and sensitivity of the method.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Mengya Li, Shijie Liu, Shiliang Guo, Dong Liang, Miaoyun Li, Yaodi Zhu, Lijun Zhao, Jong-Hoon Lee, Gaiming Zhao, Yangyang Ma, Yanxia Liu
Summary: In this study, a magnetic flow device was developed to purify spores in a culture medium system. The device used magnetic nanoparticles to absorb vegetative cells, separating them from the spores. The achieved purity of the collected spores was over 95%. The study also demonstrated a rapid quantitative detection method using Raman spectroscopy.
ANALYTICAL METHODS
(2024)
Article
Chemistry, Analytical
Wanqiong Liu, Zixuan Wu, Jianwei Peng, Zebin Xu, Yong Liang
Summary: Metal-organic frameworks (MOFs) are effective carriers for molecular imprinting, but their poor dispersibility in aqueous solution is a significant drawback. In this study, we have applied amphiphilic block copolymers and molecularly imprinted technology on MOFs to improve the hydrophilicity of molecularly imprinted fluorescent materials.
ANALYTICAL METHODS
(2024)