Journal
ANAIS DA ACADEMIA BRASILEIRA DE CIENCIAS
Volume 90, Issue 1, Pages 859-893Publisher
ACAD BRASILEIRA DE CIENCIAS
DOI: 10.1590/0001-3765201820170768
Keywords
acylation; diazocarbonyl; diazocompounds; diazo transfer; synthetic methodology
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Funding
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2013/25504-1, 2013/18009-4, 2015/22003-7]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [303437/2015-4, 130528/2017-0]
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For many years diazocarbonyl compounds have been studied due to their versatility and usability in many chemical transformations. In this review, we summarize the traditional methods to prepare these compounds as well as the new methods and recent improvements in experimental procedures. Moreover, emergence of continuous flow techniques has allowed safer and environmentally friendly procedures for the handling of diazomethane and diazo compounds and will also be a topic in this review.
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