Journal
AICHE JOURNAL
Volume 64, Issue 8, Pages 3177-3187Publisher
WILEY
DOI: 10.1002/aic.16112
Keywords
graphene; colloids; interfacial processes; Langmuir films; self-assembly
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Funding
- NSF MRI [CBET-153219]
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1532179] Funding Source: National Science Foundation
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We examine the dynamics and morphology of graphitic films at an air-water interface in a Langmuir trough by varying interfacial surface coverage, by observing in situ interfacial structure, and by characterizing interfacial structure of depositions on mica substrates. In situ interfacial structure is visualized with Brewster angle microscopy and depositions of the interface are characterized with atomic force microscopy and field-emission scanning electron microscopy. Compression/expansion curves exhibit a monotonically decreasing surface pressure between consecutive compressions, but demonstrate a rebound of hysteretic behavior when the interface is allowed to relax between consecutive compressions. This dynamic results from a competition between consolidation of the interface via agglomeration of particles or the stacking of graphene sheets, and a thermally-driven relaxation where nanometer-thick particles are able to overcome capillary interactions. These results are especially relevant to applications where functional films with controlled conductivity and transparency may be produced via liquid-phase deposition methods. (C) 2018 American Institute of Chemical Engineers
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