Article
Materials Science, Ceramics
Phylis Makurunje, Simon C. Middleburgh, William E. Lee
Summary: This review discusses various approaches to address the high processing temperatures required in reactive melt infiltration (RMI) processing of modern multiphase ceramic matrix composites (CMCs). It focuses on using immiscible phases, miscible phases, silicide phases, and/or silicide eutectics to lower the temperature requirement for RMI, optimizing the composition of incorporated phases, minimizing damage to reinforcing phases, utilizing rapid heating techniques, and developing in situ real-time monitoring systems. Future opportunities include integrating additive manufacturing with RMI, utilizing process modeling, and applying in situ and in operando characterization techniques.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
Konstantin Bolgaru, Anton Reger, Vladimir Vereshchagin, Alexander Akulinkin
Summary: A method for manufacturing silicon nitride-based composites with a desired porosity using self-propagating high-temperature synthesis has been developed. The effects of starting specimen composition, pressure, and diameter on combustion parameters were studied, with the addition of aqueous-alkali solution. The phase composition of the composites was determined, showing porosities of 25.11%-55.08% predominantly with open pores in the range of 21-305 μm.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Chun-Liang Yeh, Kuan-Ting Chen, Tzong-Hann Shieh
Summary: Aluminothermic combustion synthesis was used to investigate the formation of Fe3Si/FeSi-Al2O3 composites in Fe2O3-Al-Fe-Si reaction systems under different Fe/Si stoichiometry. The study found that the formation of iron silicide phases was dependent on the Fe/Si ratio, with the Si percentage affecting combustion exothermicity and flame-front velocity. The increase in Si content led to the formation of both Fe3Si and FeSi in the final products, with FeSi content increasing with Si percentage.
Review
Materials Science, Ceramics
Dewei Ni, Yuan Cheng, Jiaping Zhang, Ji-Xuan Liu, Ji Zou, Bowen Chen, Haoyang Wu, Hejun Li, Shaoming Dong, Jiecai Han, Xinghong Zhang, Qiangang Fu, Guo-Jun Zhang
Summary: Ultra-high temperature ceramics (UHTCs) have ultra-high melting points, outstanding mechanical properties, and ablation resistance at elevated temperatures, making them promising materials for structural applications in extreme environments such as rockets and hypersonic vehicles. The development of high-entropy UHTCs is an emerging direction for ultra-high temperature materials.
JOURNAL OF ADVANCED CERAMICS
(2022)
Article
Materials Science, Multidisciplinary
Kan Bian, Xiuxiu Li, Yiping Wang, Xiongjie Li, Sheng Sun, Shuo Feng, Ying Yang
Summary: PZT-based piezoelectric ceramics and Al2O3-based structural ceramics were cast and co-fired to prepare a layered piezoelectric ceramic/structural ceramic composite. Control of sintering temperature and adjustment of solid content were systematically conducted to achieve sintering density matching. Al2O3 structural ceramic exhibited excellent mechanical properties, while PZT functional ceramic showed high electrical performance in the layered composites.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Materials Science, Ceramics
Mohammadreza Faraji, Mandana Adeli, Mansour Soltanieh
Summary: The efficient synthesis of magnesium silicide was achieved by implementing combustion reactions in compressed mixtures of magnesium and silicon. The induction-activated method allowed rapid synthesis and characterization of the products using XRD and SEM techniques, showing that decreasing silicon particle size and increasing sample green density improved reaction kinetics and reduced the formation of undesirable phases. Activation energy for the self-propagating, high-temperature synthesis (SHS) of Mg2Si was calculated to be around 195 kJ mol(-1).
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Shile Chen, Liang Wang, Gang He, Jiangtao Li, Chang-An Wang
Summary: A novel approach was developed in this study to prepare porous Si3N4 ceramics with high porosity, high strength, high toughness, and low thermal conductivity by integrating the gelcasting-SHS process.
JOURNAL OF ADVANCED CERAMICS
(2022)
Article
Materials Science, Ceramics
Y. Arai, M. Saito, A. Samizo, R. Inoue, K. Nishio, Y. Kogo
Summary: A novel heat-resistant material, carbon fiber-containing refractory high-entropy ceramic matrix composites (C/RHECs), were successfully fabricated for components of hypersonic vehicles. Arc jet tests conducted showed the formation of complex oxides in the oxidized region, indicating the presence of a barrier to oxygen diffusion during oxidation.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Zheng Peng, Wei Sun, Xiang Xiong, Hongbo Zhang, Fangwei Guo, Jiaming Li
Summary: The study found that optimizing nitrogen substitution in the sublattice can significantly improve the ablation resistance of high-entropy ceramics, reducing the ablation rate.
Article
Nanoscience & Nanotechnology
Linchao Wang, Junwei Liu, Liying Shen, Chuyan Hu, Zhenhui Huang, Baihan Wang, Chao Xu, Qiang Liu
Summary: This study focused on the development of lightweight magnesium matrix composites (MMCs) capable of operating at high temperatures exceeding 300 degrees C. By infiltrating molten Mg alloy into porous ceramic scaffolds, a range of new lamellar ceramic/Mg composites were prepared, exhibiting excellent mechanical properties at temperatures above 300 degrees C. The mechanical properties of the composites were found to be proportional to the ceramic content, with a significant increase in flexural strength at 300 degrees C. The results of this research provide new design ideas and lay a foundation for further investigation of magnesium matrix composites capable of working at temperatures above 300 degrees C.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING
(2023)
Article
Materials Science, Multidisciplinary
Chun-Liang Yeh, Ann Lu, Wei-Che Liang
Summary: Fe-Si intermetallics-Al2O3 composites were prepared by thermite-assisted combustion synthesis, and the effects of Si content on the formation of silicide phases were investigated. It was found that the increase of Si content led to a decrease in combustion temperature and combustion wave velocity. Fe3Si, FeSi, and alpha-FeSi2 were identified as the silicide compounds in the final products.
Article
Chemistry, Physical
Mingyu Gu, Chunyan Wu, Xingyu Chen, Yu Wan, Yumeng Liu, Shan Zhou, Hongwei Cai, Bi Jia, Ruzhuan Wang, Weiguo Li
Summary: In this research, the temperature-dependent critical inclusion size for microcracking was estimated under residual stress and applied stress for particulate-reinforced ultra-high-temperature ceramic matrix composites. The study also estimated the critical flaw size and applied stress required for the stable growth of radial cracks under different temperatures. The results showed that the sensitivity of the critical inclusion size to temperature was influenced by the applied stress, with higher applied stresses leading to lower sensitivity. Additionally, the crack resistance of ceramic materials with pre-existing microcracks could be improved by increasing the service stress when the stress was low. A temperature-dependent fracture strength model for composites with a pre-existing critical flaw was proposed and showed good agreement with experimental data.
Article
Nanoscience & Nanotechnology
Jianning Zhang, Ke Chen, Xun Sun, Ming Liu, Xiao Hu, Liu He, Zhengren Huang, Zhifang Chai, Xueshan Xiao, Yujie Song, Qing Huang
Summary: Ceramics, including a variety of compounds, are widely used in different applications, but processing them into complex shapes has been a challenge. The use of polymer-derived ceramics can lower processing temperatures and allow for the manufacturing of objects with complex shapes and fine textures.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Materials Science, Multidisciplinary
Qin Zou, Peihang Dong, Yanguo Li, Di Wu, Yongan Luo
Summary: The influence of different formulations on the composition, microstructure, microhardness, fracture toughness and abrasive ratio of polycrystalline cubic boron nitride (PcBN) composites was investigated. Experimental results showed that aluminum can improve toughness and reduce hardness, WC/VC and cBN can generate a hard intermediate phase to improve hardness and reduce toughness, ZrC can achieve phase change toughening by generating ZrO2, and WC system, WC/VC system, and WC/ZrC system all have a high improvement on the hardness, denseness, and abrasive ratio of the sintered body.
DIAMOND AND RELATED MATERIALS
(2023)
Review
Materials Science, Ceramics
Xuefei Li, Zhiwei Guo, Qiren Huang, Chengqing Yuan
Summary: Ceramic materials are widely used due to their good physical and chemical properties, but their poor mechanical properties have limited their development. To overcome this limitation, researchers have turned to nature for inspiration and developed high toughness, lightweight, and functional ceramic materials through biomimetic design and preparation techniques.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2023)
Article
Materials Science, Ceramics
S. Vorotilo, A. Yu Potanin, P. A. Loginov, N. Shvindina, E. A. Levashov
CERAMICS INTERNATIONAL
(2020)
Article
Crystallography
Stepan Vorotilo, Philipp V. Kiryukhantsev-Korneev, Boris S. Seplyarskii, Roman A. Kochetkov, Nail I. Abzalov, Ivan D. Kovalev, Tatyana G. Lisina, Alexander A. Zaitsev
Article
Materials Science, Ceramics
D. O. Moskovskikh, S. Vorotilo, A. S. Sedegov, K. Kuskov, K. Bardasova, Ph Kiryukhantsev-korneev, M. Zhukovskyi, A. S. Mukasyan
CERAMICS INTERNATIONAL
(2020)
Article
Materials Science, Ceramics
AYu Potanin, A. N. Astapov, S. Rupasov, S. Vorotilo, N. A. Kochetov, D. Yu Kovalev, E. A. Levashov
CERAMICS INTERNATIONAL
(2020)
Article
Chemistry, Physical
Stepan Vorotilo, Evgeniy Patsera, Natalya Shvindina, Sergei Rupasov, Evgeniy Levashov
Article
Chemistry, Multidisciplinary
Stepan Vorotilo, Pavel Alexandrovich Loginov, Alexandr Yuryevich Churyumov, Alexey Sergeevich Prosviryakov, Marina Yakovlevna Bychkova, Sergey Ivanovich Rupasov, Anton Sergeevich Orekhov, Philipp Vladimirovich Kiryukhantsev-Korneev, Evgeny Alexandrovich Levashov
Article
Metallurgy & Metallurgical Engineering
P. A. Loginov, S. Vorotilo, D. A. Sidorenko, Yu. V. Lopatina, A. Okubayev, N. V. Shvyndina, E. A. Levashov
RUSSIAN JOURNAL OF NON-FERROUS METALS
(2020)
Article
Metallurgy & Metallurgical Engineering
S. Vorotilo, E. A. Levashov, A. Yu. Potanin, P. A. Loginov, N. V. Shvyndina
RUSSIAN JOURNAL OF NON-FERROUS METALS
(2020)
Article
Materials Science, Coatings & Films
Ph Kiryukhantsev-Korneev, A. D. Sytchenko, A. Yu Potanin, S. A. Vorotilo, E. A. Levashov
SURFACE & COATINGS TECHNOLOGY
(2020)
Article
Multidisciplinary Sciences
Dmitry Moskovskikh, Stepan Vorotilo, Veronika Buinevich, Alexey Sedegov, Kirill Kuskov, Alexander Khort, Christopher Shuck, Maksim Zhukovskyi, Alexander Mukasyan
SCIENTIFIC REPORTS
(2020)
Article
Chemistry, Physical
Philipp Kiryukhantsev-Korneev, Alina Sytchenko, Yuriy Pogozhev, Stepan Vorotilo, Anton Orekhov, Pavel Loginov, Evgeny Levashov
Summary: Coatings in a Zr-Mo-Si-B-N system were deposited using magnetron sputtering in argon, demonstrating superior properties such as high hardness, elastic recovery, low friction coefficient, and excellent oxidation resistance up to 1200 degrees C. The protective oxide layer inhibits oxygen diffusion into the coating, resulting in high oxidation resistance.
Article
Materials Science, Ceramics
S. Vorotilo, E. A. Levashov, V. V. Kurbatkina, E. Patsera, P. A. Loginov, V. Yu Lopatin, A. S. Orekhov
Summary: Investigations in the Zr-Ta-Si-B system reveal tendencies to form tantalum boride and tantalum silicide, and to release Si and Zr, based on macrokinetic features and phase and structure formation mechanisms.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Multidisciplinary
Philipp Kiryukhantsev-Korneev, Alina Sytchenko, Yuriy Kaplanskii, Alexander Sheveyko, Stepan Vorotilo, Evgeny Levashov
Summary: The study investigated the structure and properties of ZrB2 and Zr-B-N coatings deposited under different atmospheres. The nitrogen-containing coatings exhibited enhanced wear resistance and corrosion resistance compared to coatings without nitrogen.
Article
Thermodynamics
Tigran G. Akopdzhanyan, Sergey Rupasov, Stepan Vorotilo
Summary: This study explores the synthesis of aluminum oxynitride (AlON) under high-pressure nitrogen atmosphere, examining the effects of nitrogen pressure, Mg(ClO4)(2) addition, and excess Al on combustion process kinetics and product composition. The research reveals the relationship between AlON lattice parameter and nitrogen pressure, and demonstrates the fabrication of transparent Y2O3-doped AlON ceramics from combustion products.
COMBUSTION AND FLAME
(2021)
Article
Chemistry, Physical
S. Vorotilo, P. A. Loginov, D. Yu Kovalev, E. A. Levashov
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)