Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 10, Issue 6, Pages 6031-6038Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b18620
Keywords
iron-based metal-organic framework; chemical stability; hydrophobic character; hexane isomers; adsorptive separation
Funding
- National Natural Science Foundation of China [21576092, 21436005, U1662136]
- China Scholarship Council [201406155018]
- Guangdong Province Science and Technology Project [2016A020221006]
- Office of Basic Research, Energy Sciences of the U.S. Department of Energy [DE-FG02-08ER-46491]
- Office of Science, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-AC02-05CH11231]
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A novel iron-based microporous metalorganic framework built of trinuclear iron clusters [Fe-3(mu(3)-O)(COO)(6)] and 2,2-bis(4-carboxyphenyl)-hexafluoropropane (6FDCA) has been prepared by solvothermal synthesis. It exhibits excellent chemical stability and strong hydrophobic character. More importantly, this material is capable of separating hexane isomers with good separation performance on the basis of a kinetically controlled process, making it a promising candidate for improving the research octane number of gasoline.
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