Molecular electrocatalysts for the oxygen reduction reaction

Design of template-stabilized active and earth-abundant oxygen evolution catalysts in acid

(2017) Michael Huynh et al.   Chemical Science

Towards an intelligent design of molecular electrocatalysts

(2017) Cyrille Costentin et al.   Nature Reviews Chemistry

Electrocatalytic O2 Reduction at a Bio-inspired Mononuclear Copper Phenolato Complex Immobilized on a Carbon Nanotube Electrode

(2016) Solène Gentil et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water

(2016) Wolfgang Schöfberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

(2016) Tatsuya Kitagawa et al.   CHEMICAL COMMUNICATIONS

Energy-Related Small Molecule Activation Reactions: Oxygen Reduction and Hydrogen and Oxygen Evolution Reactions Catalyzed by Porphyrin- and Corrole-Based Systems

(2016) Wei Zhang et al.   CHEMICAL REVIEWS

Characterization and Subsequent Reactivity of an Fe-Peroxo Porphyrin Generated by Electrochemical Reductive Activation of O2

(2016) Raquel Oliveira et al.   INORGANIC CHEMISTRY

Metallocorroles as Electrocatalysts for the Oxygen Reduction Reaction (ORR)

(2016) Atif Mahammed et al.   ISRAEL JOURNAL OF CHEMISTRY

Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production

(2016) Eric S. Wiedner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxygen Reduction Catalysis at a Dicobalt Center: The Relationship of Faradaic Efficiency to Overpotential

(2016) Guillaume Passard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Noncovalent Immobilization of a Pyrene-Modified Cobalt Corrole on Carbon Supports for Enhanced Electrocatalytic Oxygen Reduction and Oxygen Evolution in Aqueous Solutions

(2016) Haitao Lei et al.   ACS Catalysis

Catalytic H2O2 Disproportionation and Electrocatalytic O2 Reduction by a Functional Mimic of Heme Catalase: Direct Observation of Compound 0 and Compound I in Situ

(2016) Kushal Sengupta et al.   ACS Catalysis

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays

(2015) R. Morris Bullock et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metallocorroles as Nonprecious-Metal Catalysts for Oxygen Reduction

(2015) Naomi Levy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron transfer and reaction mechanism of laccases

(2015) Stephen M. Jones et al.   CELLULAR AND MOLECULAR LIFE SCIENCES

Enhancement of 4-electron O2 reduction by a Cu(ii)–pyridylamine complex via protonation of a pendant pyridine in the second coordination sphere in water

(2015) Hiroaki Kotani et al.   CHEMICAL COMMUNICATIONS

Tuning the thermodynamic onset potential of electrocatalytic O2 reduction reaction by synthetic iron–porphyrin complexes

(2015) Sk Amanullah et al.   CHEMICAL COMMUNICATIONS

New Perspectives on Proton Pumping in Cellular Respiration

(2015) Mårten Wikström et al.   CHEMICAL REVIEWS

Molecular Catalysts for Water Oxidation

(2015) James D. Blakemore et al.   CHEMICAL REVIEWS

Noble metal-free hydrogen evolution catalysts for water splitting

(2015) Xiaoxin Zou et al.   CHEMICAL SOCIETY REVIEWS

Concerted Proton–Electron Transfer in Electrocatalytic O2 Reduction by Iron Porphyrin Complexes: Axial Ligands Tuning H/D Isotope Effect

(2015) Sudipta Chatterjee et al.   INORGANIC CHEMISTRY

Standard Reduction Potentials for Oxygen and Carbon Dioxide Couples in Acetonitrile and N,N-Dimethylformamide

(2015) Michael L. Pegis et al.   INORGANIC CHEMISTRY

Electrochemical dioxygen reduction catalyzed by a (nitro)cobalt(perfluorophthalocyanine) complex and the possibility of a peroxynitro complex intermediate

(2015) John A. Goodwin et al.   JOURNAL OF PORPHYRINS AND PHTHALOCYANINES

Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e–/4H+ O2-Reduction

(2015) Sudipta Chatterjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Catalysis of O2 Reduction by Iron Porphyrins in Water: Heterogeneous versus Homogeneous Pathways

(2015) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Medium Effects Are as Important as Catalyst Design for Selectivity in Electrocatalytic Oxygen Reduction by Iron–Porphyrin Complexes

(2015) Matthew L. Rigsby et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A biosynthetic model of cytochrome c oxidase as an electrocatalyst for oxygen reduction

(2015) Sohini Mukherjee et al.   Nature Communications

Electrocatalytic O2reduction by a monolayer of hemin: the role of pKaof distal and proximal oxygen of a FeIII–OOH species in determining reactivity

(2014) Sohini Mukherjee et al.   CHEMICAL COMMUNICATIONS

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

(2014) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

The use of copper and cobalt phthalocyanines as electrocatalysts for the oxygen reduction reaction in acid medium

(2014) Rafael M. Reis et al.   ELECTROCHIMICA ACTA

Multicopper Models for the Laccase Active Site: Effect of Nuclearity on Electrocatalytic Oxygen Reduction

(2014) Edmund C. M. Tse et al.   INORGANIC CHEMISTRY

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Cobalt triarylcorroles containing one, two or three nitro groups. Effect of NO2 substitution on electrochemical properties and catalytic activity for reduction of molecular oxygen in acid media

(2014) Bihong Li et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Direct Comparison of Electrochemical and Spectrochemical Kinetics for Catalytic Oxygen Reduction

(2014) Derek J. Wasylenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic O2 Reduction by [Fe-Fe]-Hydrogenase Active Site Models

(2014) Subal Dey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton switch for modulating oxygen reduction by a copper electrocatalyst embedded in a hybrid bilayer membrane

(2014) Christopher J. Barile et al.   NATURE MATERIALS

Spectroscopic characterization of a phenolate bound FeII–O2adduct: gauging the relative “push” effect of a phenolate axial ligand

(2013) Pradip Kumar Das et al.   CHEMICAL COMMUNICATIONS

Iron(II) phthalocyanine covalently functionalized graphene as a highly efficient non-precious-metal catalyst for the oxygen reduction reaction in alkaline media

(2013) Ying Liu et al.   ELECTROCHIMICA ACTA

Second Sphere Control of Redox Catalysis: Selective Reduction of O2 to O2– or H2O by an Iron Porphyrin Catalyst

(2013) Subhra Samanta et al.   INORGANIC CHEMISTRY

Density Functional Study for the Bridged Dinuclear Center Based on a High-Resolution X-ray Crystal Structure of ba3 Cytochrome c Oxidase from Thermus thermophilus

(2013) Wen-Ge Han Du et al.   INORGANIC CHEMISTRY

Selective 4e–/4H+ O2 Reduction by an Iron(tetraferrocenyl)Porphyrin Complex: From Proton Transfer Followed by Electron Transfer in Organic Solvent to Proton Coupled Electron Transfer in Aqueous Medium

(2013) Kaustuv Mittra et al.   INORGANIC CHEMISTRY

O2 Reduction Reaction by Biologically Relevant Anionic Ligand Bound Iron Porphyrin Complexes

(2013) Subhra Samanta et al.   INORGANIC CHEMISTRY

Electrocatalytic O2 Reduction Reaction by Synthetic Analogues of Cytochrome P450 and Myoglobin: In-Situ Resonance Raman and Dynamic Electrochemistry Investigations

(2013) Sudipta Chatterjee et al.   INORGANIC CHEMISTRY

Absorption and Electrochemical Properties of Cobalt and Iron Phthalocyanines and Their Quaternized Derivatives: Aggregation Equilibrium and Oxygen Reduction Electrocatalysis

(2013) Thiago Teixeira Tasso et al.   INORGANIC CHEMISTRY

Redox Mediator Effect on Water Oxidation in a Ruthenium-Based Chromophore–Catalyst Assembly

(2013) Michael R. Norris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of intermediates formed during steady-state electrocatalytic O2 reduction by iron porphyrins

(2013) K. Sengupta et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction

(2013) Yuanyuan Jiang et al.   ACS Catalysis

Selective four electron reduction of O2 by an iron porphyrin electrocatalyst under fast and slow electron fluxes

(2012) Subhra Samanta et al.   CHEMICAL COMMUNICATIONS

Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water

(2012) Benjamin D. Matson et al.   CHEMICAL COMMUNICATIONS

Complexes of earth-abundant metals for catalytic electrochemical hydrogen generation under aqueous conditions

(2012) V. Sara Thoi et al.   CHEMICAL SOCIETY REVIEWS

Cu complexes that catalyze the oxygen reduction reaction

(2012) Matthew A. Thorseth et al.   COORDINATION CHEMISTRY REVIEWS

Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges

(2012) Pingwu Du et al.   Energy & Environmental Science

Nonprecious Metal Catalysts for Fuel Cell Applications: Electrochemical Dioxygen Activation by a Series of First Row Transition Metal Tris(2-pyridylmethyl)amine Complexes

(2012) Ashleigh L. Ward et al.   INORGANIC CHEMISTRY

EPR, Resonance Raman, and DFT Calculations on Thiolate- and Imidazole-Bound Iron(III) Porphyrin Complexes: Role of the Axial Ligand in Tuning the Electronic Structure

(2012) Pradip Kumar Das et al.   INORGANIC CHEMISTRY

Molecular Oxygen Reduction Electrocatalyzed by meso-Substituted Cobalt Corroles Coated on Edge-Plane Pyrolytic Graphite Electrodes in Acidic Media

(2012) Zhongping Ou et al.   INORGANIC CHEMISTRY

Ligand Effects on the Overpotential for Dioxygen Reduction by Tris(2-pyridylmethyl)amine Derivatives

(2012) Matthew A. Thorseth et al.   INORGANIC CHEMISTRY

Molecular catalysis of the oxygen reduction reaction by iron porphyrin catalysts tethered into Nafion layers: An electrochemical study in solution and a membrane-electrode-assembly study in fuel cells

(2012) Qinggang He et al.   JOURNAL OF POWER SOURCES

Catalytic Four-Electron Reduction of O2 via Rate-Determining Proton-Coupled Electron Transfer to a Dinuclear Cobalt-μ-1,2-peroxo Complex

(2012) Shunichi Fukuzumi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biomimetic Oxygen Reduction by Cofacial Porphyrins at a Liquid–Liquid Interface

(2012) Pekka Peljo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A molecular ruthenium catalyst with water-oxidation activity comparable to that of photosystem II

(2012) Lele Duan et al.   Nature Chemistry

Developing the mechanism of dioxygen reduction catalyzed by multicopper oxidases using protein film electrochemistry

(2012) James A. Cracknell et al.   Chemical Science

Splitting Water with Cobalt

(2011) Vincent Artero et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dioxygen and Hydrogen Peroxide Reduction with Hemocyanin Model Complexes

(2011) Matthew A. Thorseth et al.   INORGANIC CHEMISTRY

Four-Electron Oxygen Reduction by Brominated Cobalt Corrole

(2011) Alex Schechter et al.   INORGANIC CHEMISTRY

Electrocatalytic O2Reduction by Covalently Immobilized Mononuclear Copper(I) Complexes: Evidence for a Binuclear Cu2O2Intermediate

(2011) Charles C. L. McCrory et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High electrocatalytic activity of tethered multicopper oxidase–carbon nanotube conjugates

(2010) Ramaraja P. Ramasamy et al.   CHEMICAL COMMUNICATIONS

Proton-Coupled Electron Transfer in Cytochrome Oxidase

(2010) Ville R. I. Kaila et al.   CHEMICAL REVIEWS

Solar Water Splitting Cells

(2010) Michael G. Walter et al.   CHEMICAL REVIEWS

Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines

(2010) Jenny Y. Yang et al.   DALTON TRANSACTIONS

H2Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation

(2010) Vincent Fourmond et al.   INORGANIC CHEMISTRY

Hangman Corroles: Efficient Synthesis and Oxygen Reaction Chemistry

(2010) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic studies of the ‘blue’ Cu enzyme, bilirubin oxidase, as a highly efficient electrocatalyst for the oxygen reduction reaction

(2010) Luciano dos Santos et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Oxygen reduction reactivity of cobalt(ii) hangman porphyrins

(2010) Robert McGuire Jr. et al.   Chemical Science

Powering the planet with solar fuel

(2009) Harry B. Gray   Nature Chemistry

Oxygen Reduction Activity of a Copper Complex of 3,5-Diamino-1,2,4-triazole Supported on Carbon Black

(2008) Matthew S. Thorum et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS

Clarification of the Oxidation State of Cobalt Corroles in Heterogeneous and Homogeneous Catalytic Reduction of Dioxygen

(2008) Karl M. Kadish et al.   INORGANIC CHEMISTRY

Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygenadsorption/desorption in aqueous media

(2007) Tomohiko Inomata et al.   CHEMICAL COMMUNICATIONS