Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts

Infrared spectroscopy of the nitrogenase MoFe protein under electrochemical control: potential-triggered CO binding

(2017) P. Paengnakorn et al.   Chemical Science

Simultaneous UV–Visible Absorption and Raman Spectroelectrochemistry

(2016) David Ibañez et al.   ANALYTICAL CHEMISTRY

Foot of the Wave Analysis for Mechanistic Elucidation and Benchmarking Applications in Molecular Water Oxidation Catalysis

(2016) Roc Matheu et al.   ChemSusChem

Qualitative extension of the EC′ Zone Diagram to a molecular catalyst for a multi-electron, multi-substrate electrochemical reaction

(2016) Daniel J. Martin et al.   DALTON TRANSACTIONS

Electrocatalytic reduction of carbon dioxide with Mn(terpyridine) carbonyl complexes

(2016) Charles W. Machan et al.   DALTON TRANSACTIONS

Quantitative measurements in electrochemical electron paramagnetic resonance

(2016) Mika A. Tamski et al.   ELECTROCHIMICA ACTA

Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3

(2016) Po Ling Cheung et al.   INORGANIC CHEMISTRY

Iron Polypyridyl Complexes for Photocatalytic Hydrogen Generation

(2016) Carolyn L. Hartley et al.   INORGANIC CHEMISTRY

Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes

(2016) Douglas W. Agnew et al.   INORGANIC CHEMISTRY

Reactivity of Proton Sources with a Nickel Hydride Complex in Acetonitrile: Implications for the Study of Fuel-Forming Catalysts

(2016) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Re(I) NHC Complexes for Electrocatalytic Conversion of CO2

(2016) Charles J. Stanton et al.   INORGANIC CHEMISTRY

Kinetic Analysis of Competitive Electrocatalytic Pathways: New Insights into Hydrogen Production with Nickel Electrocatalysts

(2016) Eric S. Wiedner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tracking the Structural and Electronic Configurations of a Cobalt Proton Reduction Catalyst in Water

(2016) Dooshaye Moonshiram et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts

(2016) Noémie Elgrishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production

(2016) Eric S. Wiedner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids To Promote Carbon Dioxide Reduction at Low Overpotentials

(2016) Matthew D. Sampson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR and UV–vis spectroelectrochemical studies of diketopyrrolopyrroles disubstituted with alkylated thiophenes

(2016) Monika Gora et al.   SYNTHETIC METALS

A fascinating multifaceted redox-active chelating ligand: introducing the N,N′-dimethyl-3,3′-biquinoxalinium “methylbiquinoxen” platform

(2016) Nicolas Leblanc et al.   Chemical Science

Reaction Pathways of Hydrogen-Evolving Electrocatalysts: Electrochemical and Spectroscopic Studies of Proton-Coupled Electron Transfer Processes

(2016) Noémie Elgrishi et al.   ACS Catalysis

Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst

(2016) Eric S. Rountree et al.   ACS Catalysis

Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions

(2016) Michael L. Pegis et al.   ACS Central Science

Reaction Dynamics of Proton-Coupled Electron Transfer from Reduced ZnO Nanocrystals

(2015) Miles N. Braten et al.   ACS Nano

Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2′-bipyridine)(CO)3: CN Coordination Alters Mechanism

(2015) Charles W. Machan et al.   INORGANIC CHEMISTRY

Mechanistic Studies of Hydrogen Evolution in Aqueous Solution Catalyzed by a Tertpyridine–Amine Cobalt Complex

(2015) Anna Lewandowska-Andralojc et al.   INORGANIC CHEMISTRY

Bioinspired Tungsten Dithiolene Catalysts for Hydrogen Evolution: A Combined Electrochemical, Photochemical, and Computational Study

(2015) Maria Gomez-Mingot et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Concerted Electron–Proton Transfer (EPT) in the Oxidation of Cysteine

(2015) Christopher J. Gagliardi et al.   Journal of Physical Chemistry C

Cyclic Voltammetry Analysis of Electrocatalytic Films

(2015) Cyrille Costentin et al.   Journal of Physical Chemistry C

Potential-Dependent Electrocatalytic Pathways: Controlling Reactivity with pKa for Mechanistic Investigation of a Nickel-Based Hydrogen Evolution Catalyst

(2015) Eric S. Rountree et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton-Coupled Electron Transfer Dynamics in the Catalytic Mechanism of a [NiFe]-Hydrogenase

(2015) Brandon L. Greene et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate

(2015) Charles W. Machan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Homogeneous Reduction of CO2 by [Ni(cyclam)]+: Increased Catalytic Rates with the Addition of a CO Scavenger

(2015) Jesse D. Froehlich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concerted proton-coupled electron transfer from a metal-hydride complex

(2015) Marc Bourrez et al.   Nature Chemistry

Nickel phlorin intermediate formed by proton-coupled electron transfer in hydrogen evolution mechanism

(2015) Brian H. Solis et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Efficient and selective molecular catalyst for the CO2-to-CO electrochemical conversion in water

(2015) Cyrille Costentin et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Review of advances in coupling electrochemistry and liquid state NMR

(2015) Ugo Bussy et al.   TALANTA

Solution-phase electrochemistry-nuclear magnetic resonance of small organic molecules

(2015) D. Falck et al.   TRAC-TRENDS IN ANALYTICAL CHEMISTRY

Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex

(2015) Brian D. McCarthy et al.   Chemical Science

Turning it off! Disfavouring hydrogen evolution to enhance selectivity for CO production during homogeneous CO2 reduction by cobalt–terpyridine complexes

(2015) Noémie Elgrishi et al.   Chemical Science

Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts

(2015) Ming-Hsun Ho et al.   ACS Catalysis

UV-vis and EPR spectroelectrochemical investigations of triarylamine functionalized arylene bisimides

(2015) Sandra Pluczyk et al.   RSC Advances

Cyclic Voltammetry of Electrocatalytic Films: Fast Catalysis Regimes

(2015) Cyrille Costentin et al.   ChemElectroChem

In Situ Ultrafast 2D NMR Spectroelectrochemistry for Real-Time Monitoring of Redox Reactions

(2014) Renaud Boisseau et al.   ANALYTICAL CHEMISTRY

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

(2014) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

Toward the rational benchmarking of homogeneous H2-evolving catalysts

(2014) Vincent Artero et al.   Energy & Environmental Science

Mechanism of Photocatalytic Hydrogen Generation by a Polypyridyl-Based Cobalt Catalyst in Aqueous Solution

(2014) Alexander Rodenberg et al.   INORGANIC CHEMISTRY

Hydrogen Evolution Catalyzed by an Iron Polypyridyl Complex in Aqueous Solutions

(2014) G. P. Connor et al.   INORGANIC CHEMISTRY

Electrocatalytic Proton Reduction by a Dicobalt Tetrakis-Schiff Base Macrocycle in Nonaqueous Electrolyte

(2014) Subhadeep Kal et al.   INORGANIC CHEMISTRY

Reactivity of a Series of Isostructural Cobalt Pincer Complexes with CO2, CO, and H+

(2014) David W. Shaffer et al.   INORGANIC CHEMISTRY

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry

(2014) Eric S. Rountree et al.   INORGANIC CHEMISTRY

Electrocatalytic CO2 Reduction with a Homogeneous Catalyst in Ionic Liquid: High Catalytic Activity at Low Overpotential

(2014) David C. Grills et al.   Journal of Physical Chemistry Letters

Direct Comparison of Electrochemical and Spectrochemical Kinetics for Catalytic Oxygen Reduction

(2014) Derek J. Wasylenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of Key Catalytic Intermediates in a Photoinduced Proton Reduction Cycle with a Diiron Carbonyl Complex

(2014) Mohammad Mirmohades et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecular Catalysis of H2 Evolution: Diagnosing Heterolytic versus Homolytic Pathways

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comparison of [Ni(PPh2NPh2)2(CH3CN)]2+ and [Pd(PPh2NPh2)2]2+ as Electrocatalysts for H2 Production

(2014) Eric S. Wiedner et al.   ORGANOMETALLICS

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry

(2014) Charles W. Machan et al.   ORGANOMETALLICS

Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction

(2014) Matthew V. Vollmer et al.   ORGANOMETALLICS

Electrocatalytic H2 Evolution by Proton-Gated Hangman Iron Porphyrins

(2014) Daniel J. Graham et al.   ORGANOMETALLICS

Role of pendant proton relays and proton-coupled electron transfer on the hydrogen evolution reaction by nickel hangman porphyrins

(2014) D. Kwabena Bediako et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Redox-controlled fluorescence modulation (electrofluorochromism) in triphenylamine derivatives

(2014) Cassandre Quinton et al.   RSC Advances

Multielectron, Multistep Molecular Catalysis of Electrochemical Reactions: Benchmarking of Homogeneous Catalysts

(2014) Cyrille Costentin et al.   ChemElectroChem

Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides

(2013) R. Morris Bullock et al.   CHEMICAL COMMUNICATIONS

Carbon monoxide release catalysed by electron transfer: electrochemical and spectroscopic investigations of [Re(bpy-R)(CO)4](OTf) complexes relevant to CO2 reduction

(2013) Kyle A. Grice et al.   DALTON TRANSACTIONS

Manganese as a Substitute for Rhenium in CO2 Reduction Catalysts: The Importance of Acids

(2013) Jonathan M. Smieja et al.   INORGANIC CHEMISTRY

Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO2

(2013) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen

(2013) Tianbiao Liu et al.   Nature Chemistry

Earth-abundant hydrogen evolution electrocatalysts

(2013) James R. McKone et al.   Chemical Science

Catalysis of the electrochemical reduction of carbon dioxide

(2012) Cyrille Costentin et al.   CHEMICAL SOCIETY REVIEWS

Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell

(2012) F. Miomandre et al.   ELECTROCHEMISTRY COMMUNICATIONS

Electrochemical generation of hydrogen from acetic acid using a molecular molybdenum–oxo catalyst

(2012) V. Sara Thoi et al.   Energy & Environmental Science

Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins

(2012) Manolis M. Roubelakis et al.   Energy & Environmental Science

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

(2012) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Local Proton Source Enhances CO2 Electroreduction to CO by a Molecular Fe Catalyst

(2012) C. Costentin et al.   SCIENCE

Concertedness in proton-coupled electron transfer cleavages of carbon–metal bonds illustrated by the reduction of an alkyl cobalt porphyrin

(2012) Cyrille Costentin et al.   Chemical Science

Electrofluorochromism: from molecular systems to set-up and display

(2012) P. Audebert et al.   Chemical Science

[Ni(PMe2NPh2)2](BF4)2 as an Electrocatalyst for H2 Production

(2012) Stefan Wiese et al.   ACS Catalysis

Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime

(2011) James T. Muckerman et al.   CHEMICAL COMMUNICATIONS

Coupling thin layer electrochemistry with epifluorescence microscopy: An expedient way of investigating electrofluorochromism of organic dyes

(2011) Fabien Miomandre et al.   ELECTROCHEMISTRY COMMUNICATIONS

Studies of a Series of [Ni(PR2NPh2)2(CH3CN)]2+Complexes as Electrocatalysts for H2Production: Substituent Variation at the Phosphorus Atom of the P2N2Ligand

(2011) Uriah J. Kilgore et al.   INORGANIC CHEMISTRY

Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes

(2011) Brian H. Solis et al.   INORGANIC CHEMISTRY

An in situ electrochemical cell for Q- and W-band EPR spectroscopy

(2011) Paul R. Murray et al.   JOURNAL OF MAGNETIC RESONANCE

Bidirectional and Unidirectional PCET in a Molecular Model of a Cobalt-Based Oxygen-Evolving Catalyst

(2011) Mark D. Symes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

Re(bipy-tBu)(CO)3Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies

(2010) Jonathan M. Smieja et al.   INORGANIC CHEMISTRY

Design and applications of an in situ electrochemical NMR cell

(2010) Xiaocan Zhang et al.   JOURNAL OF MAGNETIC RESONANCE

Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts

(2010) Jillian L. Dempsey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of H2Evolution from a Photogenerated Hydridocobaloxime

(2010) Jillian L. Dempsey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Easily Constructed Microscale Spectroelectrochemical Cell

(2010) Paul A. Flowers et al.   SPECTROSCOPY LETTERS

Hydrogen Evolution Catalyzed by Cobaloximes

(2009) Jillian L. Dempsey et al.   ACCOUNTS OF CHEMICAL RESEARCH

In Situ NMR Spectroelectrochemistry of Higher Sensitivity by Large Scale Electrodes

(2009) Sabrina Klod et al.   ANALYTICAL CHEMISTRY

Electrocatalytic reduction of protons to hydrogen by a water-compatible cobalt polypyridyl platform

(2009) Julian P. Bigi et al.   CHEMICAL COMMUNICATIONS

Spectroelectrochemistry: the best of two worlds

(2009) Wolfgang Kaim et al.   CHEMICAL SOCIETY REVIEWS

Channel-Flow Cell for X-ray Absorption Spectroelectrochemistry

(2009) R. J. K. Wiltshire et al.   Journal of Physical Chemistry C

From Hydrogenases to Noble Metal-Free Catalytic Nanomaterials for H2 Production and Uptake

(2009) A. Le Goff et al.   SCIENCE

Single-molecule fluorescence spectroelectrochemistry of cresyl violet

(2008) Chenghong Lei et al.   CHEMICAL COMMUNICATIONS

Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects

(2008) Jean-Michel Savéant   CHEMICAL REVIEWS

The roles of the first and second coordination spheres in the design of molecular catalysts for H2production and oxidation

(2008) M. Rakowski DuBois et al.   CHEMICAL SOCIETY REVIEWS

Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

(2008) Eric E. Benson et al.   CHEMICAL SOCIETY REVIEWS

EQCM and in situ FTIR spectroelectrochemistry study on the electrochemical oxidation of TMB and the effect of large-sized anions

(2008) Meiling Liu et al.   JOURNAL OF ELECTROANALYTICAL CHEMISTRY