Curvature capillary repulsion

Directed assembly of colloids is an exciting field in materials science for forming structures with new symmetries and responses. We have been studying how interface curvature can be used in to guide colloidal structure formation. On a fluid interface, the area of the deformation field around adsorbed microparticles depends on interface curvature; particles move to minimize the excess area of the distortions that they make in the interface. For particles that are sufficiently small, this area decreases as particlesmove along principal axes to sites of high deviatoric curvature. We have studied this migration for microparticles on a curved host interface with zeromean curvature created by pinning an oil-water interface around a micropost. Here, on a similar interface, we demonstrate capillary curvature repulsion; that is, we identify conditions in which microparticles migrate away from high curvature sites. Using theory and experiment, we discuss the origin of these interactions and their relationship to the particle's undulated contact line. We discuss the implications of this type of interaction in various contexts from materials science to microrobotics.