4.7 Article

High rate performance of the carbon encapsulated Li4Ti5O12 for lithium ion battery

Journal

RESULTS IN PHYSICS
Volume 7, Issue -, Pages 810-812

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.rinp.2017.01.040

Keywords

Li-ion batteries; Rate performance; Carbon materials; Li4Ti5O12 anode

Funding

  1. Scientific Research Initial funding for the advanced talent of Janghan University [08010001, 06750001]
  2. Basic Research Project of Wuhan City [2015011701011593]
  3. 4th Yellow Crane Talent Programme of Wuhan City [08010004]
  4. Hubei Province Innovative Young Research Team in Universities [T201318]
  5. Key Project of Natural Science Foundation of Hubei Province [2014CFA098]
  6. National High Technology Research and Development Program of China (863 Program) [2015AA033406]
  7. National Science and Technology Major Project [2016YFB0401500]

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Li4Ti5O12 (LTO) is attractive alternative anode material with excellent cyclic performance and high rate after coating modifications of the conductive materials. Anatase TiO2 and glucose were applied of the synthesis of the carbon coated LTO (C@LTO). XRD results showed that all the major diffractions from the spinel structure of LTO can be found in the C@LTO such as (111), (311), (400) but there are no observations of the Carbon diffraction peaks. Electrochemical Impedance Spectroscopy (EIS) data shows C@LTO resistance was nearly half of the LTO value. Rate performance showed that capacity of C@LTO was higher than that of the pure LTO from 0.1 C, 0.2 C, 1 C, 2 C, 5 C and 10 C, which indicates that this is a promising approach to prepare the high performance LTO anode. (C) 2017 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license.

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