Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 4, Issue 11, Pages 2184-2190Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7qo00556c
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Funding
- National Natural Science Foundation of China (NSFC) [81373259, 81573286, 81602954]
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A procedure for the [Cp*CoIII]-catalyzed, 1,2,3-triazole directed C-H amidation of arenes, using dioxazolone as an efficient amidating reagent, has been developed. This reaction provides a step-and atomeconomical protocol for C-N bond formation, releasing carbon dioxide as a single byproduct. Yet a variety of functional groups are well tolerated, obtaining the desired products in moderate to excellent yields.
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