Journal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
Volume 73, Issue -, Pages 669-674Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2052520617008447
Keywords
metal-organic framework; dynamic in situ X-ray diffraction; dehydration; time resolved; single-crystal to single-crystal
Categories
Funding
- National Science Foundation [DMR-1455039]
- National Science Foundation/Department of Energy [NSF/CHE-1346572]
- US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1346572] Funding Source: National Science Foundation
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Understanding the processes by which porous solid-state materials adsorb and release guest molecules would represent a significant step towards developing rational design principles for functional porous materials. To elucidate the process of liquid exchange in these materials, dynamic in situ X-ray diffraction techniques have been developed which utilize liquid-phase chemical stimuli. Using these time-resolved diffraction techniques, the ethanol solvation process in a flexible metal-organic framework [Co(AIP)(bpy)(0.5)(H2O)] center dot 2H(2)O was examined. The measurements provide important insight into the nature of the chemical transformation in this system including the presence of a previously unreported neat ethanol solvate structure.
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