4.5 Review

A Critical Review of Mg-Based Hydrogen Storage Materials Processed by Equal Channel Angular Pressing

Journal

METALS
Volume 7, Issue 9, Pages -

Publisher

MDPI
DOI: 10.3390/met7090324

Keywords

Mg alloy; hydrogen storage behavior; equal-channel angular pressing (ECAP)

Funding

  1. National Natural Science Foundation of China [51774109]
  2. Key Research and Development Project of Jiangsu Province of China [BE2017148]
  3. Fundamental Research Funds for the Central Universities [HHU2016B10314]
  4. Six Major Talent Peaks Project of Jiangsu Province of China [2014-XCL-023]
  5. Public Service Platform and Science & Technology Support Program in the industrial field of Suqian City of China [M201614, H201615]

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As a kind of cost-efficient hydrogen storage materials with high hydrogen capacity and light weight, Mg-based alloys have attracted much attention. This review introduces an effective technique in producing bulk ultrafine-grained (UFG) Mg alloys and promoting its hydrogen storage property, namely, equal-channel angular pressing (ECAP). This paper briefly describes the technical principle of ECAP and reviews the research progress on hydrogen storage properties of ECAP-processed Mg alloys. Special attention is given to their hydrogen storage behaviors including hydrogen storage dynamics, capacity, and cycling stability. Finally, it analyzes the factors that affect the hydrogen storage properties of ECAP-processed Mg alloys, such as the grain sizes, lattice defects, catalysts, and textures introduced by ECAP process.

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