Base Catalysis by Mono- and Polyoxometalates

Decatungstate Anion for Photocatalyzed “Window Ledge” Reactions

(2016) Davide Ravelli et al.   ACCOUNTS OF CHEMICAL RESEARCH

Heteropolycompounds as catalysts for biomass product transformations

(2016) Laura M. Sanchez et al.   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Research progress on polyoxometalate-based transition-metal–rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications

(2016) Jun-Wei Zhao et al.   CHEMICAL COMMUNICATIONS

A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO2 Conversion

(2016) Pei-Zhou Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fully-occupied Keggin type polyoxometalate as solid base for catalyzing CO2 cycloaddition and Knoevenagel condensation

(2016) Weilin Ge et al.   Catalysis Science & Technology

Application of group V polyoxometalate as an efficient base catalyst: a case study of decaniobate clusters

(2016) Shun Hayashi et al.   RSC Advances

Solid base catalysts: fundamentals and their applications in organic reactions

(2015) Hideshi Hattori   APPLIED CATALYSIS A-GENERAL

Design of Highly Functionalized Polyoxometalate-Based Catalysts

(2015) Keigo Kamata   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Recent Advances in Polyoxometalate-Catalyzed Reactions

(2015) Sa-Sa Wang et al.   CHEMICAL REVIEWS

Temperature-induced racemic compounds and chiral conglomerates based on polyoxometalates and lanthanides: syntheses, structures and catalytic properties

(2015) Haiyan An et al.   CRYSTENGCOMM

Niobate salts of organic base catalyzed chemical fixation of carbon dioxide with epoxides to form cyclic carbonates

(2015) Angjun Chen et al.   GREEN CHEMISTRY

Recent progress on supported polyoxometalates for biodiesel synthesis via esterification and transesterification

(2015) Nilesh Narkhede et al.   GREEN CHEMISTRY

Silver tungstate: a single-component bifunctional catalyst for carboxylation of terminal alkynes with CO2 in ambient conditions

(2015) Chun-Xiang Guo et al.   GREEN CHEMISTRY

Polyoxometalate-based phase transfer catalysis for liquid–solid organic reactions: a review

(2015) Yu Zhou et al.   Catalysis Science & Technology

Lanthanide-supported molybdenum–vanadium oxide clusters: syntheses, structures and catalytic properties

(2015) Fei Fei et al.   RSC Advances

A Basic Germanodecatungstate with a −7 Charge: Efficient Chemoselective Acylation of Primary Alcohols

(2014) Kosei Sugahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tri-lacunary polyoxometalates of Na8H[PW9O34] as heterogeneous Lewis base catalysts for Knoevenagel condensation, cyanosilylation and the synthesis of benzoxazole derivatives

(2014) Shen Zhao et al.   APPLIED CATALYSIS A-GENERAL

Polyoxometalate based open-frameworks (POM-OFs)

(2014) Haralampos N. Miras et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of α-Dawson-Type Silicotungstate [α-Si2W18O62]8−and Protonation and Deprotonation Inside the Aperture through Intramolecular Hydrogen Bonds

(2014) Takuo Minato et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amphiprotic Properties of a Bis(μ-hydroxo)divanadium(IV)-Substituted γ-Keggin-Type Silicodecatungstate Containing Two Different Kinds of Hydroxyl Moieties

(2014) Kazuhiro Uehara et al.   INORGANIC CHEMISTRY

A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation

(2014) M. Hassan Beyzavi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Intermolecular Hydroamination of Unactivated Alkenes with Indoles

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Uptake of one and two molecules of CO2 by the molybdate dianion: a soluble, molecular oxide model system for carbon dioxide fixation

(2014) Ioana Knopf et al.   Chemical Science

Addition of carbon nucleophiles to hemiaminals promoted by a Lewis acidic polyoxotungstate

(2014) Wen-Jing Xuan et al.   Organic Chemistry Frontiers

Scope of chemical fixation of carbon dioxide catalyzed by a bifunctional monomeric tungstate

(2013) Keigo Kamata et al.   CATALYSIS TODAY

A Monovacant Lacunary Silicotungstate as an Efficient Heterogeneous Catalyst for Dehydration of Primary Amides to Nitriles

(2013) Shintaro Itagaki et al.   ChemCatChem

Catalytic Oxidation of Light Alkanes (C1–C4) by Heteropoly Compounds

(2013) Miao Sun et al.   CHEMICAL REVIEWS

Hydrosilylation of Various Multiple Bonds by a Simple Combined Catalyst of a Tungstate Monomer and Rhodium Acetate

(2013) Shintaro Itagaki et al.   CHEMISTRY LETTERS

Regioselective Double Organic Functionalization of Polyoxotungstates through Electrophilic Addition of Aromatic Isocyanates to [P2W17O61(SnR)]7-

(2013) Kévin Micoine et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Efficient chemical fixation of CO2 promoted by a bifunctional Ag2WO4/Ph3P system

(2013) Qing-Wen Song et al.   GREEN CHEMISTRY

An Efficient Method for Knoevenagel Condensation Catalyzed by Tetrabutylammonium hexatungstate [TBA]2[W6O19] as Novel and Reusable Heterogeneous Catalyst

(2013) Abolghasem Davoodnia   Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry

A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2at Atmospheric Pressure

(2012) Toshihiro Kimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effective Fixation of CO2by Iridium-Catalyzed Hydrosilylation

(2012) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyanosilylation of Carbonyl Compounds with Trimethylsilyl Cyanide Catalyzed by an Yttrium-Pillared Silicotungstate Dimer

(2012) Yuji Kikukawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemo- and Regioselective Direct Hydroxylation of Arenes with Hydrogen Peroxide Catalyzed by a Divanadium-Substituted Phosphotungstate

(2012) Keigo Kamata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes

(2012) Shintaro Itagaki et al.   CHEMICAL COMMUNICATIONS

Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties

(2012) Anne Dolbecq et al.   CHEMICAL COMMUNICATIONS

A highly negatively charged γ-Keggin germanodecatungstate efficient for Knoevenagel condensation

(2012) Kosei Sugahara et al.   CHEMICAL COMMUNICATIONS

Functionalization and post-functionalization: a step towards polyoxometalate-based materials

(2012) Anna Proust et al.   CHEMICAL SOCIETY REVIEWS

Polyoxometalate water oxidation catalysts and the production of green fuel

(2012) Hongjin Lv et al.   CHEMICAL SOCIETY REVIEWS

Zinc-Catalyzed Dehydrogenative N-Silylation of Indoles with Hydrosilanes

(2012) Teruhisa Tsuchimoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible Deprotonation and Protonation Behaviors of a Tetra-Protonated γ-Keggin Silicodecatungstate

(2012) Kosei Sugahara et al.   INORGANIC CHEMISTRY

Efficient [WO4]2–-Catalyzed Chemical Fixation of Carbon Dioxide with 2-Aminobenzonitriles to Quinazoline-2,4(1H,3H)-diones

(2012) Toshihiro Kimura et al.   INORGANIC CHEMISTRY

Strategic Design and Refinement of Lewis Acid–Base Catalysis by Rare-Earth-Metal-Containing Polyoxometalates

(2012) Kosuke Suzuki et al.   INORGANIC CHEMISTRY

Synthesis and binding assays of novel 3,3-dimethylpiperidine derivatives with various lipophilicities as σ1 receptor ligands

(2011) Savina Ferorelli et al.   BIOORGANIC & MEDICINAL CHEMISTRY

An efficient H2O2-based oxidative bromination of alkenes, alkynes, and aromatics by a divanadium-substituted phosphotungstate

(2011) Kazuhiro Yonehara et al.   CHEMICAL COMMUNICATIONS

Lanthanide Polyoxocationic Complexes: Experimental and Theoretical Stability Studies and Lewis Acid Catalysis

(2011) Hani El Moll et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Epoxidation of Electron-Deficient Alkenes with Hydrogen Peroxide Catalyzed by [γ-PW10O38V2(μ-OH)2]3−

(2011) Keigo Kamata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic oxidation of hydrocarbons with hydrogen peroxide by vanadium-based polyoxometalates

(2011) Noritaka Mizuno et al.   COORDINATION CHEMISTRY REVIEWS

Divacant polyoxotungstates: Reactivity of the gamma-decatungstates [γ-XW10O36]8−(X = Si, Ge)

(2011) Bassem S. Bassil et al.   DALTON TRANSACTIONS

Cross-Linking Organic and Polyoxometalate Chemistries

(2011) Serge Thorimbert et al.   ISRAEL JOURNAL OF CHEMISTRY

Protonation of Phosphovanadomolybdates H3+xPVxMo12–xO40: Computational Insight Into Reactivity

(2011) Irena Efremenko et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Polyoxometalates: Building Blocks for Functional Nanoscale Systems

(2010) De-Liang Long et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Catalysis with Organosoluble Lewis Acidic Polyoxotungstates

(2010) Nathalie Dupré et al.   CHEMISTRY-A EUROPEAN JOURNAL

Effect of the Central Oxoanion Size on the Voltammetric Properties of Keggin-Type [XW12O40]n−(n= 2−6) Complexes

(2010) Kiyomi Nakajima et al.   INORGANIC CHEMISTRY

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

(2010) Keigo Kamata et al.   Nature Chemistry

N-Heterocyclic Carbenes as Efficient Organocatalysts for CO2Fixation Reactions

(2009) Yoshihito Kayaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solid heterogeneous catalysts for transesterification of triglycerides with methanol: A review

(2009) Z. Helwani et al.   APPLIED CATALYSIS A-GENERAL

Syntheses, molecular structures and pH-dependent monomer–dimer equilibria of Dawson α2-monotitanium(iv)-substituted polyoxometalates

(2008) Shoko Yoshida et al.   DALTON TRANSACTIONS

Guest driven rearrangements of protonation and hydrogen bonding in decavanadate anions as their tetraalkylammonium salts

(2008) Setsuko Nakamura et al.   DALTON TRANSACTIONS

Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst

(2008) Tao Jiang et al.   GREEN CHEMISTRY

N-Pyridinyl(methyl)-indole-1- or 3-propanamides and propenamides acting as topical and systemic inflammation inhibitors

(2008) Alexandra Dassonville et al.   JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY

H2O2activation by heteropolyacids with defect structures: the case ofγ-[(XO4)W10O32]n−(X = Si, Ge, n = 8; X = P,n = 7)

(2008) Andrea Sartorel et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Regioselective Activation of Oxo Ligands in Functionalized Dawson Polyoxotungstates

(2008) Cécile Boglio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY