3.8 Article

Highly Conductive PEDOT:PSS Transparent Hole Transporting Layer with Solvent Treatment for High Performance Silicon/Organic Hybrid Solar Cells

Journal

NANOSCALE RESEARCH LETTERS
Volume 12, Issue -, Pages -

Publisher

SPRINGEROPEN
DOI: 10.1186/s11671-017-2276-5

Keywords

Si/organic; Hybrid solar cells; PEDOT:PSS; Treatment; Conductivity

Funding

  1. National Natural Science Foundation of China [11574119, 51202150, 51272161]
  2. Science and Technology RAMP
  3. D Program of Shenzhen [JCYJ20160520175916066, JCYJ20150324141711593]
  4. China Postdoctoral Science Foundation [2016M590809]
  5. State Key Laboratory of Solidification Processing in NWPU [SKLSP201110]
  6. Program of Introducing Innovative Research Team in Dongguan [2014607109]

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Efficient Si/organic hybrid solar cells were fabricated with dimethyl sulfoxide (DMSO) and surfactant-doped poly(3,4-ethylenedioxythiophene): polystyrene (PEDOT:PSS). A post-treatment on PEDOT: PSS films with polar solvent was performed to increase the device performance. We found that the performance of hybrid solar cells increase with the polarity of solvent. A high conductivity of 1105 S cm(-1) of PEDOT: PSS was achieved by adopting methanol treatment, and the best efficiency of corresponding hybrid solar cells reaches 12.22%. X-ray photoelectron spectroscopy (XPS) and RAMAN spectroscopy were utilized to conform to component changes of PEDOT: PSS films after solvent treatment. It was found that the removal of the insulator PSS from the film and the conformational changes are the determinants for the device performance enhancement. Electrochemical impedance spectroscopy (EIS) was used to investigate the recombination resistance and capacitance of methanol-treated and untreated hybrid solar cells, indicating that methanol-treated devices had a larger recombination resistance and capacitance. Our findings bring a simple and efficient way for improving the performance of hybrid solar cell.

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