Journal
NANO ENERGY
Volume 33, Issue -, Pages 387-392Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.nanoen.2017.01.054
Keywords
Supercapacitor; Flexible electronics; All-solid-state; Cobalt oxide; LiPON
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Relying on the combination of lithium phosphorous oxynitride (LiPON) as electrolyte and cobalt oxide (Co3O4) as electrode material it is possible to fabricate symmetric all-solid-state micro-supercapacitors (ASTSCaps) on rigid and flexible substrates. Due to the nanoscale active layer dimensions, the excellent performance of the component materials and the high nominal voltage of 2 V, an exceptionally high volumetric energy and power densities of up to 8 ( +/- 2) mW h/cm(3) and 16 ( +/- 2) W/cm(3), respectively, are obtained. These results are going far beyond the current state-of-the-art performance limits. The ASTSCaps are temperature stable up to 215 C-omicron ( for 1 V nominal voltage) and experience an endurance of more than 30,000 cycles. These ultra-thin all-solid-state micro-supercapacitors bring strong benefits for on-chip energy storage and open up interesting new avenues for autonomous and flexible electronic microsystems.
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