4.8 Article

High-performance near-field thermophotovoltaics for waste heat recovery

Journal

NANO ENERGY
Volume 41, Issue -, Pages 344-350

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2017.09.054

Keywords

Waste heat recovery; Near-field thermophotovoltaics; Surface plasmon polaritons

Funding

  1. Advanced Research Projects Agency Energy (ARPA-E), IDEAS program [DE-AR0000731]
  2. Stanford University
  3. Department of Energy Light-Material Interactions in Energy Conversion Energy Frontier Research Center [DE-SC0001293]
  4. Stanford Graduate Fellowship

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The US industries reject nearly 20-50% of the consumed energy into the environment as waste heat. Harvesting this huge amount of heat can substantially improve the energy usage efficiency. For waste heat in the medium temperature range (similar to 500-900 K), traditional solid-state waste heat recovery techniques like thermoelectric generators and thermophotovoltaics (TPVs) are still suffering from relatively low efficiency or power density. In this work, we analyze a near-field TPV system consisting of a plasmonic emitter (indium tin oxide) and a narrow-bandgap photovoltaic cell (InAs) that are brought to deep sub-wavelength distances for high-efficiency and high-power-density waste heat recovery. We show that despite the inclusion of realistic nonradiative recombination rates and sub-bandgap heat transfer, such a near-field TPV system can convert heat to electricity with up to nearly 40% efficiency and 11 W/cm(2) power density at a 900 K emitter temperature, because of the spectral reshaping and enhancement by the thermally excited surface plasmons and waveguide modes. Thus, we show that for waste heat recovery, near-field TPV systems can have performances that significantly exceed typical thermoelectric systems. We propose a modified system to further enhance the power density by using a thin metal film on the cell, achieving a counterintuitively blocking-assisted heat transfer and power generation in the near-field regime.

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