4.8 Article

A solar rechargeable battery based on hydrogen storage mechanism in dual-phase electrolyte

Journal

NANO ENERGY
Volume 38, Issue -, Pages 257-262

Publisher

ELSEVIER
DOI: 10.1016/j.nanoen.2017.06.001

Keywords

Solar rechargeable battery; Dye-sensitized solar cell; Solar water splitting; Hydrogen storage; Dual-phase electrolyte

Funding

  1. 973 Program [2015CB251100]
  2. NSFC of China [21421001]

Ask authors/readers for more resources

Solar water splitting is an effective approach to hydrogen production and application of solar energy. However, the photo-generated hydrogen should be initially stored in high pressure cylinder and subsequently applied in hydrogen-oxygen fuel cells. Herein, a solar rechargeable battery is proposed based mainly on hydrogen storage mechanism in dual-phase electrolyte. Specifically, the hydrogen production, storage and utilization are integrated into a hybrid system of the dye-sensitized solar cell and electrochemical cell with the dye-sensitized TiO2 as photo-anode, LiI as the cathode active material in organic electrolyte, AB(5)-type hydrogen storage alloy as anode in alkaline solution, and PEDOT-modified Nafion membrane as separator. Here, the photo-generated electrons in organic electrolyte pass to the AB(5)-type hydrogen storage alloy to split water in alkaline aqueous electrolyte for generating hydrogen, which is in situ stored into AB(5)-type hydrogen storage alloy. Subsequently, the hydrogen stored in the AB5-type hydrogen storage alloy can be oxidized by electrochemical way to generate electricity, coupled with LiI cathode in organic electrolyte. The solar rechargeable battery demonstrates a new solution of the solar energy conversion, hydrogen production, storage, and utilization, achieving the new energy conversion and storage from solar energy to chemical energy, and further to electrical energy.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Electrochemistry

La2NiO4 nanoparticles as a core host of sulfur to enhance cathode volumetric capacity for lithium-sulfur battery

Hai-Lun Ge, Zhen-Yu Wang, Guo-Ran Li, Sheng Liu, Xue-Ping Gao

Summary: This study introduces La2NiO4 nanoparticles coated uniformly around carbon nanotubes as the host of sulfur cathode for lithium-sulfur battery, providing improved cycling stability and high-volumetric capacity due to the polarity of LNO and the synergistic effect of LNO nanoparticles and CNTs.

ELECTROCHIMICA ACTA (2022)

Article Chemistry, Physical

A Sustainable Multipurpose Separator Directed Against the Shuttle Effect of Polysulfides for High-Performance Lithium-Sulfur Batteries

Wei Wang, Kai Xi, Bowen Li, Haojie Li, Sheng Liu, Jianan Wang, Hongyang Zhao, Huanglong Li, Amor M. Abdelkader, Xueping Gao, Guoran Li

Summary: The use of a multipurpose separator can address the aggregation of polysulfides in lithium-sulfur batteries, preventing the formation of dead sulfur and improving capacity. It shows promising performance in stability, flexibility, and sustainability.

ADVANCED ENERGY MATERIALS (2022)

Article Chemistry, Physical

Quantitatively regulating defects of 2D tungsten selenide to enhance catalytic ability for polysulfide conversion in a lithium sulfur battery

Hao-Jie Li, Kai Xi, Wei Wang, Sheng Liu, Guo-Ran Li, Xue-Ping Gao

Summary: This study investigates the influence of defects on enhancing the cathodic process in lithium sulfur batteries using 2D WSe2 as the host material. The results show that a moderate level of defects can significantly improve the catalytic ability, leading to high-performance Li-S batteries with excellent cycle stability and energy density.

ENERGY STORAGE MATERIALS (2022)

Article Energy & Fuels

Reversible Degradation in Hole Transport Layer-Free Carbon-Based Perovskite Solar Cells

Yuan-Bo Yang, Peng Chen, Hong-Shi Li, Qian Zhao, Tian-Tian Li, Yue Wu, Yu Zhang, Xue-Ping Gao, Guo-Ran Li

Summary: This study investigates the long-term stability of HTL-free carbon-based perovskite solar cells in the ambient air environment and discovers a reversible degradation phenomenon. The study also finds that the short-circuit current density and open-circuit voltage are minimally affected, while only the fill factor is reduced. Furthermore, a minute-heating treatment can eliminate the reversible degradation.

SOLAR RRL (2022)

Article Materials Science, Multidisciplinary

High-Entropy Alloys to Activate the Sulfur Cathode for Lithium-Sulfur Batteries

Zhenyu Wang, Hailun Ge, Sheng Liu, Guoran Li, Xueping Gao

Summary: This study introduces a high-entropy alloy as a catalytic host to activate the electrochemical performance of the sulfur cathode in lithium-sulfur batteries, enhancing the utilization of sulfur. The high-entropy alloy nanocrystallites on nitrogen-doped carbon exhibit high electrocatalytic activity, promoting the conversion of solid sulfur to soluble intermediate products and increasing the reversible capacity of the battery when the whole cathode is used as the active material.

ENERGY & ENVIRONMENTAL MATERIALS (2023)

Article Electrochemistry

Eu2O3-doped Li4SiO4 coating layer with a high ionic conductivity improving performance of LiNi0.8Co0.1Mn0.1O2 cathode materials

Shao-Lun Cui, Dan Feng, Zhen-Xue Xiao, Sheng Liu, Xue-Ping Gao, Guo-Ran Li

Summary: This study proposes a method of improving the cycle stability and structural stability of Ni-rich layered cathode materials by using Eu2O3-doped Li4SiO4 as a coating layer. The doping of Eu2O3 increases the ion conductivity and stability of the coating layer. The optimal cycle and rate performance are achieved when the doping amount of Eu2O3 is 10 mol% of Li4SiO4.

ELECTROCHIMICA ACTA (2022)

Article Engineering, Environmental

Photo-rechargeable all-solid-state lithium-sulfur batteries based on perovskite indoor photovoltaic modules

Tian-Tian Li, Yuan-Bo Yang, Bo-Sheng Zhao, Yue Wu, Xiao-Wen Wu, Peng Chen, Xue-Ping Gao

Summary: Photovoltaic technologies for indoor energy harvesting face barriers such as intermittent power supplies and low light intensities. In this study, an all-solid-state photo-rechargeable battery system based on an all-inorganic CsPbI2Br perovskite solar cell module and an all-solid-state lithium-sulfur battery was developed for indoor energy harvesting and storage. The system exhibited a high energy conversion and storage efficiency of 11.2% under LED illumination, as well as a high electrochemical storage capacity of 1585.3 mAh g(-1). It also demonstrated good safety and stability after 200 hours of photo-charge and galvanostatic discharge cycles.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Materials Science, Multidisciplinary

A gel polymer electrolyte with Al2O3 nanofibers skeleton for lithium-sulfur batteries

Hui-Min Wang, Zhen-Yu Wang, Chang Zhou, Guo-Ran Li, Sheng Liu, Xue-Ping Gao

Summary: In this study, researchers developed a functional gel polymer electrolyte for lithium-sulfur batteries. The electrolyte consists of a PVDF-HFP polymer matrix and a gamma-Al2O3 three-dimensional skeleton, providing structural and thermal stability. PVDF-HFP facilitates lithium-ion transport, while gamma-Al2O3 suppresses the shuttling of LiPs through strong interactions. Furthermore, gamma-Al2O3 improves ionic conductivity. This research offers a promising strategy for fabricating multifunctional gel electrolytes for high-energy lithium-sulfur batteries.

SCIENCE CHINA-MATERIALS (2023)

Article Nanoscience & Nanotechnology

Fast Charge-Transport Interface on Primary Particles Boosts High- Rate Performance of Li-Rich Mn-Based Cathode Materials

Shao-Lun Cui, Zhen-Xue Xiao, Bai-Chuan Cui, Sheng Liu, Xue-Ping Gao, Guo-Ran Li

Summary: A Li-rich Mn-based layered oxide cathode (LLO) is a promising cathode material for high-energy lithium-ion batteries. However, it faces challenges such as sluggish kinetics, oxygen evolution, and structural degradation. In this study, an interfacial optimization of primary particles is proposed to improve ion and electron transport simultaneously. The modified interface containing AlPO4 and carbon enhances Li+ diffusion and reduces charge-transfer resistance, leading to improved charge-transport kinetics. The optimized LLO cathode exhibits a high initial Coulombic efficiency of 87.3% and superior high-rate stability with 88.2% capacity retention after 300 cycles at a 5C high rate.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Multidisciplinary Sciences

Thermal tolerance of perovskite quantum dots dependent on A-site cation and surface ligand

Shuo Wang, Qian Zhao, Abhijit Hazarika, Simiao Li, Yue Wu, Yaxin Zhai, Xihan Chen, Joseph M. Luther, Guoran Li

Summary: A detailed picture of temperature dependent behavior of Cs(x)FA(1-x)PbI(3) perovskite quantum dots is constructed by in situ optical spectroscopic and structural measurements. The thermal degradation mechanism depends on both the exact chemical composition and the ligand binding energy. Cs-rich quantum dots undergo a phase transition from black gamma-phase to yellow delta-phase, while FA-rich quantum dots directly decompose into PbI2. Quantum dot growth is observed at elevated temperatures. FA-rich quantum dots exhibit stronger electron-longitudinal optical phonon coupling, leading to a higher probability of exciton dissociation compared to Cs-rich quantum dots. Surface ligand-induced strain enables full-range A-site tuning.

NATURE COMMUNICATIONS (2023)

Article Nanoscience & Nanotechnology

Lithiated Phosphoryl Cellulose Nanocrystals Enhance Cycling Stability and Safety of Quasi-Solid-State Lithium Metal Batteries

Baichuan Cui, Zhenxue Xiao, Shaolun Cui, Shuai Hao, Sheng Liu, Xueping Gao, Guoran Li

Summary: This study focuses on improving the cycling stability and safety of quasi-solid-state lithium metal batteries by synthesizing lithiated phosphoryl cellulose nanocrystals (PCNC-Li) and incorporating them into poly(vinylidene fluoride) (PVDF) gel polymer electrolyte. The PCNC-Li forms a uniform network structure on the surface of PVDF membranes, regulating the transport of lithium ions and enhancing the stability of the lithium anode interface. Additionally, the PCNC-Li coating layer improves the thermal stability and mechanical strength of PVDF membranes, thus enhancing the safety of lithium metal batteries. This work provides a new option for fabricating a better composite gel polymer electrolyte for lithium metal batteries.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Chemistry, Multidisciplinary

Morphology Control of Li2S Deposition via Geometrical Effect of Cobalt-Edged Nickel Alloy to Improve Performance of Lithium-Sulfur Batteries

Yicheng Jiang, Sheng Liu, Xueping Gao, Guoran Li

Summary: In this work, cobalt-edged nickel alloy is designed as a host material for sulfur cathodes in lithium-sulfur batteries to manipulate the behavior and morphology of Li2S deposition. The difference in catalytic kinetic characteristics of Co and Ni and the geometrical effect of Co-edged Ni alloy result in a well-spaced morphology, preventing premature surface passivation and improving sulfur utilization and rate capability of the cathodes. This study provides insights for developing new host materials and understanding the existing works in lithium-sulfur batteries.

ADVANCED FUNCTIONAL MATERIALS (2023)

Article Chemistry, Physical

An in situ fabricated multifunctional gel electrolyte for lithium-sulfur batteries

Hui-Min Wang, En-De Fu, Guo-Ran Li, Sheng Liu, Xue-Ping Gao

Summary: A multifunctional gel polymer electrolyte (ANPD-GPE) composed of Nafion-coated Al2O3 nanofibers and in-situ polymerized 1,3-dioxolane (DOL) was fabricated to improve the performance of high-energy lithium-sulfur (Li-S) batteries. The ANPD-GPE effectively solves the issues of polysulfide shuttle, unstable lithium anode, and safety hazards in traditional liquid electrolytes. The ANPD-GPE demonstrates improved electrochemical performance in terms of cathode cyclability and lithium anode stability.

JOURNAL OF POWER SOURCES (2023)

Article Chemistry, Physical

High-Entropy Oxide Nanofibers as Catalytic Host Promising High Volumetric Capacity of Sulfur-Based Composites for Lithium-Sulfur Batteries

Ya-Qi Wang, Hui-Min Wang, Yi-Cheng Jiang, Guo-Ran Li, Sheng Liu, Xue-Ping Gao

Summary: In this study, high-entropy oxide (HEO) nanofibers were used as sulfur hosts for the first time, showing good rate capacity and cycling stability due to strong chemical interaction with lithium polysulfides. The tap density of the sulfur/HEO composite was also significantly higher than that of the sulfur/CNT composite, leading to a higher volumetric capacity. This research provides a promising strategy for improving the volumetric energy density and electrochemical performance of lithium-sulfur batteries.

ACS APPLIED ENERGY MATERIALS (2023)

Article Chemistry, Physical

Inverse-opal structured TiO2 regulating electrodeposition behavior to enable stable lithium metal electrodes

Xuewen Wu, Shaolun Cui, Minfei Fei, Sheng Liu, Xueping Gao, Guoran Li

Summary: In this work, an inverse-opal structured TiO2 membrane is designed to regulate the electrodeposition behavior of lithium metal, providing a fundamental solution to the poor cycle stability and lithium dendrite safety problems. Through homogenizing the mass transfer process, reducing the desolvation barrier, and confining the migration of lithium atoms, the electrodeposition process of lithium metal is essentially changed, eliminating the possibility of lithium dendrite formation.

GREEN ENERGY & ENVIRONMENT (2023)

Article Chemistry, Physical

Gamma glycine enhances efficiency of organic hybrid piezoelectric-triboelectric nanogenerators

Sirinya Ukasi, Paritta Jutapukti, Chiranicha Ninthub, Nattapong Pinpru, Phakkhananan Pakawanit, Wanwilai Vittayakorn, Satana Pongampai, Naratip Vittayakorn, Thitirat Charoonsuk

Summary: This study explores the enhancement of electrical output of flexible hybrid piezoelectric-triboelectric nanogenerators by incorporating gamma-glycine into fully organic composites. The research demonstrates the importance of optimized concentrations of gamma-glycine and chitosan in achieving superior performance. The study identifies the critical content of gamma-glycine that leads to the highest output signal, and provides theoretical explanations for this observation.

NANO ENERGY (2024)

Article Chemistry, Physical

Portable triboelectric-electromagnetic hybrid biomechanical energy harvester for driving various functional light-emitting diodes with a wide range of wavelengths

Yoonsang Ra, Yu-seop Kim, Seonmo Yang, Namgyu Kang, Gyuwon Oh, Chungyeon Cho, Sangmin Lee, Dongwhi Choi

Summary: In this study, a portable energy harvester (STEP) was proposed to drive various functional LEDs using biomechanical energy. The roles and functionalities of a triboelectric nanogenerator (TENG) and electromagnetic generator (EMG) in the hybrid energy harvester were experimentally demonstrated, and the necessity of hybridization for LED-involved devices was described. The STEP showed promising potential as an effective energy supply strategy for various functional LEDs in related industries.

NANO ENERGY (2024)

Article Chemistry, Physical

Flexoelectrically augmented triboelectrification enabled self-power wireless smart home control system

Dae Sol Kong, Kyung Hoon Kim, Ying Chieh Hu, Jong Hun Kim, Inseo Kim, Jeongwan Lee, Joonhyuk Lee, Won Hyuk Shon, Hanjin Yoo, Chul-Un Ro, Seungsu Lee, Hyoungjeen Jeen, Minbaek Lee, Minseok Choi, Jong Hoon Jung

Summary: With the rapid development of the Internet of Things and artificial intelligence, smart home has emerged to fulfill the security, convenience, and energy-saving issues of modern life. A flexoelectric mica crystal is used to augment the finger touch-driven triboelectric output for operating a wireless and multichannel smart home controller. This work provides important ingredients for enhancing triboelectric output and realizing a convenient, multifunctional, cost-effective, and adaptable smart home control system without batteries.

NANO ENERGY (2024)

Article Chemistry, Physical

Enhance vortices vibration with Y-type bluff body to decrease arousing wind speed and extend range for flag triboelectric energy harvester

Yi Han, Fang Wu, Xiaozhen Du, Zihao Li, Haixiang Chen, Dongxing Guo, Junlei Wang, Hong Yu

Summary: This paper presents a novel type of triboelectric nanogenerator that utilizes wind energy, with a Y-type bluff body to enhance vibration and output power. The application of this generator successfully provides power for a wireless temperature and humidity sensor.

NANO ENERGY (2024)

Article Chemistry, Physical

Surface-interspersed nanoparticles induced cathode-electrolyte interphase enabling stable cycling of high-voltage LiCoO2

Wen Zhang, Fangyuan Cheng, Miao Chang, Yue Xu, Yuyu Li, Shixiong Sun, Liang Wang, Leimin Xu, Qing Li, Chun Fang, Meng Wang, Yuhao Lu, Jiantao Han, Yunhui Huang

Summary: This study successfully induced the formation of a uniform and robust CEI by constructing ZrO2 nano-rivets on the surface of LCO, stabilizing the surface of high-voltage LCO and facilitating lithium-ion diffusion.

NANO ENERGY (2024)

Article Chemistry, Physical

Asperity shape in flexoelectric/triboelectric contacts

Karl P. Olson, Laurence D. Marks

Summary: This paper investigates the role of contacting shapes in triboelectricity and provides scaling rules for designing energy harvesting devices.

NANO ENERGY (2024)

Article Chemistry, Physical

Externally motionless triboelectric nanogenerator based on vortex-induced rolling for omnidirectional wind energy harvesting

Jong-An Choi, Jingu Jeong, Mingyu Kang, Hee-Jin Ko, Taehoon Kim, Keun Park, Jongbaeg Kim, Soonjae Pyo

Summary: Wind-driven triboelectric nanogenerators (WTENGs) are a promising emerging technology for sustainable wind energy harvesting, offering high output performance, lightweight design, and compact dimensions. This study introduces an innovative WTENG design that leverages a rolling-based mechanism to achieve efficient omnidirectional wind energy harvesting.

NANO ENERGY (2024)

Article Chemistry, Physical

Flag-type hybrid nanogenerator utilizing flapping wakes for consistent high performance over an ultra-broad wind speed range

Liwei Dong, Qian Tang, Chaoyang Zhao, Guobiao Hu, Shuai Qu, Zicheng Liu, Yaowen Yang

Summary: This paper proposes a novel hybrid scheme for flag-type nanogenerators (FNGs) that enhances their performance and broadens their operational wind speed ranges by harnessing the synergistic potential of two aerodynamic behaviors. The proposed flag-type triboelectric-piezoelectric hybrid nanogenerator (FTPNG) integrates flapping piezoelectric flags (PEFs) and a fluttering triboelectric flag (TEF). The FTPNG achieves significant power generation and a broad wind speed range, surpassing other FNGs, making it suitable for various self-powered systems and Internet of Things applications.

NANO ENERGY (2024)

Review Chemistry, Physical

Marine biomaterial-based triboelectric nanogenerators: Insights and applications

Yunmeng Li, Xin Liu, Zewei Ren, Jianjun Luo, Chi Zhang, Changyong (Chase) Cao, Hua Yuan, Yaokun Pang

Summary: The demand for green and eco-friendly materials is growing due to increasing environmental concerns related to traditional petroleum-based products. Marine biomaterials have emerged as a promising alternative, thanks to their abundant availability, biocompatibility, biodegradability, and low toxicity. In this review, we discuss the development and applications of triboelectric nanogenerators (TENGs) based on marine biomaterials. The operational modes, foundational principles, intrinsic qualities, and advantages of marine biomaterials commonly used in TENG designs are highlighted. Approaches to enhance the efficacy of TENGs derived from marine biomaterials are also discussed, along with documented applications from existing literature. Furthermore, the existing challenges and future directions in marine biomaterial-inspired TENGs are explored.

NANO ENERGY (2024)

Article Chemistry, Physical

Pathway to high performance, low temperature thin-film solid oxide cells grown on porous anodised aluminium oxide

Matthew P. Wells, Adam J. Lovett, Yizhi Zhang, Zhongxia Shang, Kosova Kreka, Babak Bakhit, Haiyan Wang, Albert Tarancon, Judith L. MacManus-Driscoll

Summary: Reversible solid oxide cells (rSOCs) offer a promising solution to efficient energy conversion, but have been limited in portable power and electrolysis applications due to excessive polarisation resistance of the oxygen electrode at low temperatures. This study demonstrates the growth of symmetric and complete rSOC structures with reduced polarisation resistance by tuning oxygen vacancy through annealing, providing a promising route towards high-performance rSOC devices for portable power applications.

NANO ENERGY (2024)

Article Chemistry, Physical

Construction of low dielectric aqueous electrolyte with ethanol for highly stable Zn anode

Kangkang Bao, Minghui Wang, Yue Zheng, Panpan Wang, Liwen Yang, Yang Jin, Hui Wu, Bin Sun

Summary: This study utilizes ethanol as an electrolyte additive to modulate the migration of zinc ions and the surface structure of zinc anodes, resulting in improved capacity retention and cycle life of zinc-based aqueous batteries.

NANO ENERGY (2024)

Article Chemistry, Physical

Ultrathin nanolayer constituted by a natural polysaccharide achieves egg-box structured SnO2 nanoparticles toward efficient and stable perovskite solar cells

Haichao Yang, Wensi Cai, Ming Wang, Saif M. H. Qaid, Zhiyuan Xu, Huaxin Wang

Summary: The introduction of sodium alginate (SA) into perovskite solar cells improves the carrier dynamics, stability, and performance by inhibiting nonradiative recombination and retarded charge dynamics.

NANO ENERGY (2024)

Article Chemistry, Physical

All-in-one multifunctional and deformation-insensitive carbon nanotube nerve patches enabling on-demand interactions

Cuirong Zhang, Mingyuan Wei, Zihan Chen, Wansheng Lin, Shifan Yu, Yijing Xu, Chao Wei, Jinwei Zhang, Ziquan Guo, Yuanjin Zheng, Qingliang Liao, Xinqin Liao, Zhong Chen

Summary: Artificial Intelligence of Things (AIoT) aims to establish smart and informative interactions between humans and devices. However, common pixelated sensing arrays in AIoT applications present problems such as hard and brittle devices, complex structures, and low precision. This article introduces an innovative solution called the all-in-one intelligent semitransparent interactive nerve patch (AISI nerve patch), which integrates sensing, recognition, and transmission functionalities into a thin and flexible patch. The AISI nerve patch is semitransparent, allowing for accurate identification without affecting aesthetics, and it can be attached to any curved surface for intelligent and interactive applications. With rapid response time and high precision recognition, it enables the integration of artificial intelligence and achieves high recognition accuracy for further development of AIoT.

NANO ENERGY (2024)

Article Chemistry, Physical

Engineering anion defects of ternary V-S-Se layered cathodes for ultrafast zinc ion storage

Youcun Bai, Heng Zhang, Huijun Song, Chong Zhu, Lijin Yan, Qin Hu, Chang Ming Li

Summary: A novel stainless-steel supported lattice-mismatched V-S-Se layered compound with high selenium vacancy was synthesized by adjusting the molar ratio of sulfur to selenium. The introduction of selenium vacancies created additional redox peaks of sulfur, providing more mass transport channels and active sites for zinc ions. The specific capacity and cycle stability of the electrode were significantly improved, demonstrating great potential for practical applications and providing insights into the effects of defects on battery performance.

NANO ENERGY (2024)

Article Chemistry, Physical

Defect-management-induced multi-stimulus-responsive mechanoluminescence in Mn2+doped gallate compound

Yao Xiao, Puxian Xiong, Yakun Le, Zhenjie Lun, Kang Chen, Zhiduo Wang, Peishan Shao, Zhicong Chen, Dongdan Chen, Zhongmin Yang

Summary: This study successfully synthesized a material with multi-stimulus-responsive luminescence and confirmed the internal relationship between luminescence and defects by regulating the distribution and depth of defects. The dynamic process of multi-stimulus-responsive luminescence was validated by experimental and calculation results.

NANO ENERGY (2024)