4.6 Article

Porous asphalt/graphene composite for supercapacitors with high energy density at superior power density without added conducting materials

Journal

JOURNAL OF MATERIALS CHEMISTRY A
Volume 5, Issue 41, Pages 21757-21764

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ta05457b

Keywords

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Funding

  1. Ministry of Science and Technology of China (MoST) [2016YFA0200200]
  2. National Natural Science Foundation of China (NSFC) [51633002, 51472124]

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The promotion of electrode active materials with higher rate capabilities and lower cost has been a long-standing challenge in the field of supercapacitors. In this work, a novel composite of asphalt with graphene oxide is developed, and it is found that the introduction of a small amount of graphene oxide such as 1 wt% could increase conductivity up to similar to 400% and surface area up to similar to 114%. The composite materials without the addition of any conducting material demonstrate both high capacitance and cycling stability. In addition, their rate capability is well maintained from 0.5 A g(-1) to 100 A g(-1) with high capacitance retention (similar to 88%). Furthermore, the optimized material, which is made mainly from the cheap waste material asphalt, demonstrates an excellent energy density (22.0 Wh kg(-1)) at an ultra-high power density (55.4 kW kg(-1)), which indicates its promising potential for industrial applications in green energy.

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