Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 6, Issue 12, Pages 1818-1822Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.201700390
Keywords
carboranes; conjugation; luminescence; solid-state emission; thermochromism
Categories
Funding
- Mitsubishi Foundation
- Scientific Research on Innovative
- Grants-in-Aid for Scientific Research [17H03067] Funding Source: KAKEN
Ask authors/readers for more resources
The pyrene-tethered carborane CBEP, which exhibited rapid and dramatic luminochromism, was synthesized. Based on optical measurements, we found that CBEP exhibited orange emission at room temperature, which was caused by intramolecular charge transfer in the solid state, and green excimer emission at 77K. We proposed that excimer formation could be encouraged by introducing a small amount of steric hindrance with an ethynyl spacer group. We found that o-carborane could suppress aggregation-caused quenching without the inhibition of excimer formation because of this steric hindrance.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available