Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2015, Issue 19, Pages 4053-4069Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201500080
Keywords
Palladium; Quinones; Reaction mechanisms; C-H activation; Oxidative coupling
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Palladium(II)-catalyzed procedures often use benzoquinone (BQ) to regenerate the catalyst. Besides its oxidation role, BQ can also promote various steps of the catalytic cycle. This review highlights the multifaceted properties of BQ and its analogues when involved in Pd-II-catalyzed oxidative reactions and presents mechanisms proposed in the literature, in some cases with personal observations.
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