Article
Chemistry, Multidisciplinary
Pritha Biswas, Tamara D. Koledin, Skylar N. Farmer, Melissa K. Santala, Janet Tate
Summary: The transformation from amorphous to crystalline in TiO2 films in air leads to different polymorphs, which can be manipulated by introducing Sn into the system. Sn stabilizes the rutile structure at the Sn/TiO2 interfaces by scavenging oxygen, resulting in rutile formation.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Materials Science, Multidisciplinary
Rene Castro, Aleksei Kononov, Nadezhda Anisimova
Summary: The results of a study on charge transfer processes in thin amorphous and crystalline Sb2Te3 films in a wide range of frequencies and temperatures are presented. The authors used dielectric spectroscopy to obtain the frequency spectra of conductivity and analyzed the frequency and temperature dependences. They observed a transition from classical correlated barrier hopping (CBH) to quantum mechanical tunneling (QMT) at a certain temperature. The study also identified the activation energies and different types of conductivities for amorphous and crystalline films.
Article
Chemistry, Multidisciplinary
Paloma Martinez, Valerie Blanchet, Dominique Descamps, Jean-Baptiste Dory, Claude Fourment, Irene Papagiannouli, Stephane Petit, Jean-Yves Raty, Pierre Noe, Jerome Gaudin
Summary: This study investigates the sub-picosecond response of amorphous germanium telluride thin film to a femtosecond laser excitation using frequency-domain interferometry and ab initio molecular dynamics. The results reveal a shrinkage of the film with dielectric properties' response faster than 300 fs, and evidence a transition toward a new amorphous electronic excited state close in bonding/structure to the liquid state. Through in-depth analysis of the local order of structures, this study sheds new light on the optically highly excited states in chalcogenide materials involved in important processes.
ADVANCED MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Wanting Lan, Linhong Cao, Yajun Fu, Jinjing Fang, Jingsong Zhang, Jin Wang
Summary: This study prepared amorphous GeTe films by pulsed laser deposition and then transformed them into crystalline GeTe films through annealing, revealing that crystalline GeTe films have higher absorbance and are more favorable for photon transition compared to amorphous GeTe films.
Article
Chemistry, Physical
Ritesh Singh Maurya, Swetha Jayanthi, Ch Gupta Chandaluri, T. P. Radhakrishnan
Summary: The impact of the mode of assembly of molecules on the properties and functions of molecular materials is a fundamental problem that was investigated through a novel diaminodicyanoquinodimethane derivative in this study. The compound exhibited enhanced fluorescence in the crystalline state, with a noticeable weak and red-shifted fluorescence in the amorphous state. The transformation from amorphous to crystalline state was monitored through imaging techniques and confirmed by diffraction methods.
CHEMISTRY OF MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Shuang Guo, Yunfeng Wang, Xiaolong Zhang, Bao Wang, Jinzhong Zhang
Summary: The nitrogen doping effect on crystal structure, optical band gap, and localized states for amorphous/crystalline GeTe films has been investigated. The results show that nitrogen doping improves the crystallization temperature and sheet resistance of the films. Raman spectra analysis reveals the impact of nitrogen doping on the local bonding structure of amorphous and crystalline GeTe films. Transmittance spectra indicate significant changes in the optical band gap and localized states density of the films, with the band gap broadening after nitrogen doping being crucial for reducing the threshold current in phase change memory.
Article
Materials Science, Coatings & Films
Lauri Aarik, Hugo Mandar, Aivar Tarre, Helle-Mai Piirsoo, Jaan Aarik
Summary: The mechanical properties of atomic-layer deposited alumina thin films with different phases were characterized, showing that the hardness and elastic modulus of the films were positively correlated with their crystallinity and density.
SURFACE & COATINGS TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
David J. Hynek, Raivat M. Singhania, Shiyu Xu, Benjamin Davis, Leizhi Wang, Milad Yarali, Joshua Pondick, John M. Woods, Nicholas C. Strandwitz, Judy J. Cha
Summary: MoTe2 can access various electronic states due to small energy differences between its polymorphs, making it suitable for phase transformation studies and quantum phenomena. Large-area thin films with high crystallinity are crucial for careful applications of MoTe2.
Article
Chemistry, Multidisciplinary
Minseong Kim, Jihyung Seo, Jihyun Kim, Jong Sung Moon, Junghyun Lee, Je-Hyung Kim, Joohoon Kang, Hyesung Park
Summary: Chemical vapor deposition (CVD) using liquid-phase precursors has limitations in synthesizing large-area transition metal dichalcogenide (TMD) thin films. However, a promoter-assisted liquid-phase CVD process with transition metal-containing precursor homogeneously modified with an alkali metal halide can successfully synthesize high-quality large-area monolayer molybdenum diselenide (MoSe2) with superior electrical transport characteristics.
Article
Materials Science, Ceramics
Doan T. Tran, Hien T. Vu, Hung N. Vu, Minh D. Nguyen
Summary: Lead-free BaZr0.25Ti0.75O3 thin films were fabricated using the sol-gel spin-coating method, and the phase evolution from amorphous to pyrochlore to perovskite crystalline was confirmed. The annealed thin films at 600 degrees C exhibited a high recoverable energy storage density of 67.6 J/cm3 and an excellent energy efficiency of 94.5%, attributed to the existence of nano-scale polar regions (2-5 nm) within a non-polar amorphous matrix. Furthermore, the thin films showed excellent stability of energy-storage properties over a wide temperature range and strong fatigue-endurance even at elevated temperatures, making them promising for applications in harsh environments.
CERAMICS INTERNATIONAL
(2023)
Article
Materials Science, Multidisciplinary
Ying Zeng, Junqin Wang, Xiaosheng Yang, Jianquan Yao, Peining Li, Qiang He, Ming Xu, Xiangshui Miao
Summary: Chalcogenide phase change materials (PCMs) are being studied for their nonvolatile phase transition capability and high dielectric tunability for optoelectronic applications. In this study, the terahertz modulation of germanium telluride (GeTe) thin films was experimentally demonstrated through THz time-domain spectroscopy (THz-TDS) and ultrafast time-resolved optical pump-THz probe experiments. The GeTe film showed high optical contrast and the transmission could be tuned from 95% to 35% in the range of 0.1-1.2 THz.
Article
Physics, Applied
M. Baloi, D. Wamwangi, B. A. Mathe, R. M. Erasmus, D. G. Billing, M. Madhuku, P. Sechogela
Summary: This study investigated the elastic properties and lattice thermal conductivity of amorphous Ge2Sb2Te5 and GeTe thin films using surface Brillouin scattering. It was found that GeTe exhibited acoustic hardening compared to Ge2Sb2Te5, leading to lower lattice thermal conductivities for both chalcogenides alloys. This could have practical applications in thermal management for phase-change memory devices and thermoelectric applications.
JOURNAL OF APPLIED PHYSICS
(2021)
Article
Multidisciplinary Sciences
Jin Yue, Yilikal Ayino, Tristan K. Truttmann, Maria N. Gastiasoro, Eylon Persky, Alex Khanukov, Dooyong Lee, Laxman R. Thoutam, Beena Kalisky, Rafael M. Fernandes, Vlad S. Pribiag, Bharat Jalan
Summary: Using hybrid MBE, high-quality SrTiO₃ films with low defect density were obtained, and their transport properties were studied. The dominant influence of intraband scattering at the second Lifshitz transition was observed, along with the anomalous temperature dependence of the Hall scattering factor and carrier density due to the antiferrodistortive transition.
Article
Engineering, Electrical & Electronic
A. A. Kononov, R. A. Castro, Y. Saito, P. Fons, G. A. Bordovsky, N. I. Anisimova, A. V. Kolobov
Summary: Sb2Te3 is a key material in phase-change memory devices and also exhibits topological insulator properties. By studying relaxation processes in thin Sb2Te3 films, it was found that both amorphous and crystalline phases contain two types of relaxators, with one type showing lower relaxation temperature in the amorphous phase. The differences in relaxation mechanisms between the two phases provide insights into the 3D-2D transformation during crystallization of van der Waals solids.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Physical
Yukang Yuan, Zhehao Xu, Sannian Song, Zhitang Song, Ruirui Liu, Jiwei Zhai
Summary: In this study, we propose a MnTe/GeTe stacked thin film structure suitable for multi-level phase change memories and systematically study the correlation between structure and performance. The results show that the stacked thin films exhibit improved amorphous thermal stability and enhanced reliability, enabling multi-level storage capability with a 50 ns electrical pulse.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Emanuele Longo, Matteo Belli, Mario Alia, Martino Rimoldi, Raimondo Cecchini, Massimo Longo, Claudia Wiemer, Lorenzo Locatelli, Polychronis Tsipas, Athanasios Dimoulas, Gianluca Gubbiotti, Marco Fanciulli, Roberto Mantovan
Summary: Research on spin-charge interconversion at the interface between magnetic materials and topological insulators has shown an enhanced charge current in Sb2Te3 TIs structures. The results indicate a potential for future technology development with a 250% increase in spin pumping efficiency in this structure.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Physics, Condensed Matter
Iraultza Unzueta, Haraldur Pall Gunnlaugsson, Torben Esmann Molholt, Hilary Masenda, Adeleh Mokhles Gerami, Petko Krastev, Dmitry Zyabkin, Krish Bharuth-Ram, Deena Naidoo, Sveinn Olafsson, Fernando Plazaola, Juliana Schell, Bingcui Qi, Xupeng Zhao, Jiaxing Xiao, Jianhua Zhao, Roberto Mantovan
Summary: The magnetic properties of Mn x Ga alloys depend on the composition x. By using molecular beam epitaxy technique, Mn x Ga samples with strong perpendicular magnetic anisotropy and controllable saturation magnetization and coercive field were produced. Mn and Ga site-specific chemical, structural, and magnetic properties were investigated using emission Mössbauer spectroscopy, and correlated with the magnetic properties measured by superconducting quantum interference device magnetometry. The results revealed the atomic-scale mechanisms driving the compositional dependence of magnetism in Mn x Ga.
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
(2022)
Article
Crystallography
Torben E. Molholt, Sveinn Olafsson, Haraldur P. Gunnlaugsson, Bingcui Qi, Karl Johnston, Roberto Mantovan, Hilary Masenda, Krish Bharuth-Ram, Haflioi P. Gislason, Guido Langouche, Deena Naidoo
Summary: In this study, the magnetic properties of Fe/V superlattices were investigated using conventional Conversion Electron Mossbauer Spectroscopy and online Fe-57(+) emission Mossbauer Spectroscopy. The results revealed that the magnetic spectra of the superlattices depended on the local lattice environment and the strain state of the Fe-lattices. The effects of the strain state of the superlattice on the magnetic properties of the Fe-layer in Fe/V multilayer structures were successfully detected using the online eMS technique.
Article
Physics, Applied
P. Carrara, M. Brioschi, E. Longo, D. Dagur, V. Polewczyk, G. Vinai, R. Mantovan, M. Fanciulli, G. Rossi, G. Panaccione, R. Cucini
Summary: This article presents a method for generating and controlling surface acoustic waves in magnetic materials, which leads to coherent spin waves in ferromagnetic media. The study finds that this method accurately extracts the values of effective magnetization and Gilbert damping, and also observes higher-order effects due to parametric modulation of magnetization dynamics.
PHYSICAL REVIEW APPLIED
(2022)
Article
Physics, Applied
Gabriele Clemente, Massimo Moret, Andres Granados del Aguila, Muhammad Hussain, Zdenek Sofer, Jiayuan Zhou, Xue Liu, Marco Fanciulli, Fabrizio Moro
Summary: In this study, the electron spin resonance (ESR) properties of a van der Waals bulk CrBr3 single crystal were investigated. Angular- and temperature-dependent experiments were conducted in the range of the critical temperature for ferromagnetic order. The results revealed a strong uniaxial magnetic anisotropy constant and the occurrence of long wavelength spin fluctuations. The findings have implications for the potential application of CrBr3 in perpendicular magnetic tunneling junctions.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
E. Georgopoulou-Kotsaki, P. Pappas, A. Lintzeris, P. Tsipas, S. Fragkos, A. Markou, C. Felser, E. Longo, M. Fanciulli, R. Mantovan, F. Mahfouzi, N. Kioussis, A. Dimoulas
Summary: The 2D van der Waals ferromagnetic metals FexGeTe2 with x = 3-5 have attracted significant attention. In this study, epitaxial Fe5-dGeTe2 (FGT) heterostructures were grown on insulating crystalline substrates using Molecular Beam Epitaxy (MBE). The addition of Bi2Te3 topological insulator (TI) to FGT films significantly enhanced the saturation magnetization and Curie temperature (Tc), with record values of 570 K obtained.
Article
Physics, Applied
Clement Chassain, Andrzej Kusiak, Cecile Gaborieau, Yannick Anguy, Nguyet-Phuong Tran, Chiara Sabbione, Marie-Claire Cyrille, Claudia Wiemer, Alessio Lamperti, Jean-Luc Battaglia
Summary: Intensive research is being conducted in the domain of phase change memories (PCMs) to reduce the programming cycle cost. The RESET operation is achieved by melting the PCM and quenching it back to the amorphous state. In this study, the thermal contact between TiN and PCM in multilayer systems has been characterized, and the influence of compressive stress exerted by TiN layers on GeGST crystallization has been highlighted.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Valerio Di Palma, Andrea Pianalto, Michele Perego, Graziella Tallarida, Davide Codegoni, Marco Fanciulli
Summary: In vitro and in vivo stimulation and recording of neuron action potential can be achieved using microelectrode arrays made of IrO2, a conductive oxide known for its biocompatibility and charge injection capabilities. This study presents the growth of nanocrystalline rutile IrO2 using a new plasma-assisted ALD process, and provides a comprehensive characterization of its morphological, structural, physical, chemical, and electrochemical properties. The results demonstrate that IrO2 grown by PA-ALD is an excellent material for neuroelectronic applications, with high charge injection capacity and double-layer capacitance.
Article
Crystallography
Juliana Heiniger-Schell, Krish Bharuth-Ram, Kimara Naicker, Vusumuzi Masondo, Thien Thanh Dang, Marianela Escobar, Carlos Diaz-Guerra, Georg Marschick, Hilary Masenda, Haraldur P. Gunnlaugsson, Bingcui Qi, Iraultza Unzueta, Sveinn Olafsson, Rajdeep Adhikari, Gerrard Peters, Deena Naidoo, Peter Schaaf, Dmitry Zyabkin, Karl Johnston, Sven Becker, Gerhard Jakob
Summary: Emission Fe-57 Mossbauer spectroscopy was used to study the temperature dependence of the hyperfine magnetic field in Ba-doped BiFeO3 thin films. The measurements were performed on two samples, 88 nm and 300 nm thick, and doped to 15% with Ba ions. The results showed a variation of the hyperfine field with temperature following the Brillouin curve for S = 5/2.
Editorial Material
Materials Science, Multidisciplinary
Massimo Longo
Article
Nanoscience & Nanotechnology
Emanuele Longo, Lorenzo Locatelli, Polychronis Tsipas, Akylas Lintzeris, Athanasios Dimoulas, Marco Fanciulli, Massimo Longo, Roberto Mantovan
Summary: Properly tuning the Fermi level position in topological insulators is crucial for tailoring their spin-polarized electronic transport and improving device efficiency. In this study, a highly crystalline Bi2Te3/Sb2Te3 heterostructure was successfully grown on large area Si(111) substrates using in situ metal organic chemical vapor deposition. The surface Fermi level of Bi2Te3 was effectively tuned by growing it on top of Sb2Te3. A spin-charge converter based on this heterostructure was fabricated and its performance was verified through spin pumping ferromagnetic resonance. The results demonstrate the successful tuning of the surface Fermi level and have potential implications for future technology transfer.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Mohammed Adel Aly, Emmanuel Oghenevo Enakerakpor, Martin Koch, Hilary Masenda
Summary: Semiconductor heterostructures play a key role in the development of electronic and optoelectronic devices. The unique properties of two-dimensional transition metal dichalcogenides and the ability to engineer van der Waals heterostructures make them potential candidates for future high-tech devices. In this study, the emission of interlayer exciton energies in the binary-ternary heterobilayer of Mo0.5W0.5Se2 with MoSe2 and WSe2 was explicitly tuned. The results showed that these heterostructures offer a wider energy range and tailored emission energies compared to their binary counterparts. Additionally, the study confirmed that transition metal dichalcogenide alloys can be used to tune the band offsets, providing another design parameter for application-specific optoelectronic devices.
Article
Materials Science, Multidisciplinary
H. P. Gunnlaugsson, A. Mokhles Gerami, H. Masenda, S. Olafsson, R. Adhikari, K. Johnston, K. Naicker, G. Peters, J. Schell, D. Zyabkin, K. Bharuth-Ram, P. Krastev, R. Mantovan, D. Naidoo, I. Unzueta
Summary: There is a discrepancy between electron paramagnetic resonance and Mossbauer spectroscopy results on the charge and spin states of dilute Fe impurities in NaCl. In this study, Mn-57 -> Fe-57 emission Mossbauer spectroscopy was used to investigate the charge and spin states of dilute substitutional Fe impurities in NaCl and LiF. A proposed scheme can differentiate between high/low-spin Fe1+ and high-spin Fe2+ in Mossbauer spectroscopy by considering the effects of nearest-neighbor distances and electronegativity difference of the host atoms.