4.7 Article

Integration of c-axis oriented Bi3.15Nd0.85Ti2.95Hf0.05O12/La0.67Sr0.33MnO3 ferromagnetic-ferroelectric composite film on Si substrate

Journal

SCIENTIFIC REPORTS
Volume 7, Issue -, Pages -

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-017-11931-5

Keywords

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Funding

  1. project of the National Natural Science Foundation [61404107, 51372198, 51332007]
  2. National Basic Research Program of China [2016YFA0300103]
  3. China Postdoctoral Fund [2013M542368]
  4. Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry
  5. International Cooperation Project [2013KW14-01]
  6. Key Laboratory Project of Shaanxi Province [14JS066]
  7. Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan province [2016CL09]

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A La0.67Sr0.33MnO3 (LSMO) ferromagnetic layer and a Nd3+/Hf4+ co-substituted Bi4Ti3O12 (Bi3.15Nd0.85Ti3-x HfxO12 (BNTHx, x = 0, 0.025, 0.05, 0.1 and 0.15)) ferroelectric layer were successively deposited onto the (00 l)-oriented LaNiO3 (LNO) layer buffered (001) Si substrate via all chemical solution deposition (CSD) method. As a result, the BNTHx/LSMO ferromagnetic-ferroelectric composite films integrated on Si substrate exhibit high c-axis orientation. The Nd3+/Hf4+ co-substituted BNTHx films have the lower leakage current and the better ferroelectric properties than the mono-substituted Bi4Ti3O12 (Bi3.15Nd0.85Ti3O12 and Bi4Ti2.95Hf0.05O12) films. In particular, the BNTH0.05/LSMO/LNO film has the lowest leakage current density of 2.5 x 10(-7) A/cm(2) at 200 kV/cm, and the highest remnant polarization (Pr) of 27.3 mu C/cm(2). The BNTH0.05/LSMO/LNO composite film also exhibits the soft ferromagnetism characteristics with a high saturated magnetization of 258 emu/cm(3) at 300 K, and the excellent magnetoelectric (ME) effect. The variations of ME voltage coefficient alpha(E) values with DC bias magnetic field H-bias shows that the BNTH0.05/LSMO/LNO film has the high alpha(E) value at near zero H-bias. Moreover, at H-bias = 0 Oe, the alpha(E) value gradually increases from zero with the increasing of the AC magnetic field frequency, and eventually reaches about 18.9 V/cm.Oe at 100 kHz, suggesting the existence of self-biased ME effect.

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