4.6 Article

Luminescence probe for temperature sensor based on fluorescence intensity ratio

Journal

OPTICAL MATERIALS EXPRESS
Volume 7, Issue 3, Pages 1077-1083

Publisher

OPTICAL SOC AMER
DOI: 10.1364/OME.7.001077

Keywords

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Funding

  1. National Key Laboratory of Tunable Laser Technology
  2. National Natural Science Foundation of China (NSFC) [61078006, 61275066]
  3. National Key Technology Research and Development Program of the Ministry of Science and Technology of China [2012BAF14B11]

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The beta-NaLuF4: Yb3+/Ho3+ nanocrystals have been synthesized via a solvothermal method, which were protected in a SiO2 capillary tube. Upon 980 nm continuous laser excitation, the micro-tube waveguide characteristic was studied. Additionally, the upconversion emissions from the F-5(4), S-5(2)-> I-5(7) (similar to 545 nm), F-5(5)-> I-5(8) (650 nm) and F-5(4), S-5(2)-> I-5(7) (similar to 750 nm) transitions of Ho3+ ions in the micro-tube were obtained and studied as a function of temperature in the range of 300-500 K. The maximum sensitivities derived from the fluorescence intensity ratio technique are 1.53% K-1 (I-750/I-650) and 0.09% K-1 (I-545/I-650) at 300 K. The result demonstrated that the near infrared-red absolute sensitivity is more sensitive as a thermometer than the green-red at the whole temperature range. The device is a promising candidate for high resolution luminescent thermometers operating under temperature of 300 similar to 500 K. (C) 2017 Optical Society of America.

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