Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 5, Pages 859-863Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201403037
Keywords
Copper; Cyanides; Structure elucidation; Luminescence; N ligands
Categories
Funding
- National Natural Science Foundation of China [21071156]
- Natural Science Foundation of Chongqing [CSTC2010BB8325]
- Program for Innovation Team Building at Institutions of Higher Education in Chongqing [KJTD201309]
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The solvothermal reaction of a mixture of copper nitrate and 3,5-bis(4-pyridyl)-1H-1,2,4-triazole (4,4-Hbpt) in a mixed acetonitrile/water solvent leads to a special copper(I) cyanide complex Cu-3(CN)(3)(4,4-Hbpt)(2) (1) with a fivefold interpenetrating dmd topological framework. The cyanide ligands in the structure are generated in situ from the C-C cleavage of acetonitrile under solvothermal conditions. Solid-state luminescence experiments show that 1 can emit efficient violet luminescence, and the possible emission mechanism was investigated in detail through theoretical calculations. The results may be helpful for the design and synthesis of efficient luminescent materials.
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