Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 5, Pages 607-615Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201500990
Keywords
Phosphorus; Diphosphenes; Steric hindrance; Transition-metal complexes; Ab initio calculations; Density functional calculations
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Funding
- Tohoku University, Japan
- University of Tokyo, Japan
- Technical University of Braunschweig, Germany
- University of Bonn, Germany
- University of Alabama, USA
- Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT)
- Japan Society for the Promotion Science
- Alexander von Humboldt Foundation
- Germany and the National Science Foundation, USA
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Diphosphenes with various kinds of sterically protecting groups are described and discussed with regard to P-31 NMR spectroscopic data, X-ray results, preparative methods, and some reactions including end-on coordination complex formations. New results of theoretical calculations on the particular diphosphene (E)-Mes*P=PMes* are also described.
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